Colored glass articles having improved mechanical durability

ABSTRACT

A colored glass article may include 50-80 mol % SiO2; 7-20 mol % Al2O3; 1-35 mol % R2O, wherein R2O comprises at least one of Li2O, Na2O, and K2O; 1×10−6-10 mol % of a colorant, wherein the colorant comprises at least one of Cr2O3, Au, Ag, CuO, NiO, Co3O4, TiO2, CeO2; and 12-24 mol % of Al2O3+MgO+CaO+ZnO. The colored glass article may have a transmittance color coordinate in the CIELAB color space with an L* value of 55 to 96.5. The colored glass article may have a compressive stress profile with a depth of compression ≥0.15t, a thickness t from 0.4 mm-5 mm, a compressive stress ≥200 MPa, and a central tension ≥60 MPa. The colored glass article may have a dielectric constant from 5.6 to 6.4 over the frequency range from 10 GHz to 60 GHz.

CROSS REFERENCE TO RELATED APPLICATIONS

The present application claims the benefit of U.S. Provisional Patent Application Ser. No. 63/212,191 filed Jun. 18, 2021 and entitled “Colored Glass Articles Having Improved Mechanical Durability,” U.S. Provisional Patent Application Ser. No. 63/212,179 filed Jun. 18, 2021 and entitled “Colored Glass Articles Having Improved Mechanical Durability,” U.S. Provisional Patent Application Ser. No. 63/251,785 filed Oct. 4, 2021 and entitled “Colored Glass Articles Having Improved Mechanical Durability,” U.S. Provisional Patent Application Ser. No. 63/286,316 filed Dec. 6, 2021 and entitled “Glass Compositions For Forming Colored Glass Articles And Glass Articles Formed Therefrom,” and U.S. Provisional Patent Application Ser. No. 63/304,807 filed Jan. 31, 2022 and entitled “Colored Glass Articles Having Improved Mechanical Durability,” each of which is incorporated by reference herein in their entireties.

FIELD

The present specification generally relates to glass compositions and glass articles and, in particular, to glass compositions and ion-exchangeable, colored glass articles formed therefrom.

TECHNICAL BACKGROUND

Aluminosilicate glass articles may exhibit superior ion-exchangeability and drop performance. Various industries, including the consumer electronics industry, desire colored materials with the same or similar strength and fracture toughness properties as existing, non-colored, ion-exchange strengthened glasses. However, simply including colorants in conventional aluminosilicate glass compositions may not produce the desired color.

Accordingly, a need exists for an alternative colored glass articles having high strength and fracture toughness.

SUMMARY

Aspect A1 includes a colored glass article comprising: greater than or equal to 50 mol % and less than or equal to 80 mol % SiO₂; greater than or equal to 7 mol % and less than or equal to 20 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 35 mol % R₂O, wherein R₂O comprises at least one of Li₂O, Na₂O, and K₂O; greater than 1×10⁻⁶ mol % and less than or equal to 10 mol % of a colorant, wherein the colorant comprises at least one of Cr₂O₃, Au, Ag, CuO, NiO, Co₃O₄, TiO₂, CeO₂; and greater than or equal to 12 mol % and less than or equal to 24 mol % of Al₂O₃+MgO+CaO+ZnO, wherein the colored glass article comprises: a transmittance color coordinate in the CIELAB color space comprising an L* value greater than or equal to 55 and less than or equal to 96.5 as measured under F2 illumination and a 10° standard observer angle; a compressive stress profile with a depth of compression greater than or equal to 0.15t where t is a thickness of the colored glass article, a compressive stress greater than or equal to 200 MPa, and a central tension greater than or equal to 60 MPa; a dielectric constant from 5.6 to 6.4 over a frequency range from 10 GHz to 60 GHz; and the thickness t is greater than or equal to 0.4 mm and less than or equal to 5 mm.

Aspect A2 includes the colored glass article of aspect A1, wherein the thickness t is greater than or equal to 0.5 mm and less than or equal to 5 mm.

Aspect A3 includes the colored glass article of any preceding aspect, wherein a colored glass article having the same composition and microstructure as a center of the colored glass article has a fracture toughness K_(IC) greater than or equal to 0.7 MPa·m^(1/2).

Aspect A4 includes the colored glass article of any preceding aspect comprising an average transmittance of greater than or equal to 10% and less than or equal to 92% over the wavelength range of 380 nm to 750 nm.

Aspect A5 includes the colored glass article of any preceding aspect further comprising at least one crystalline phase.

Aspect A6 includes the colored glass article of any preceding aspect comprising a crystallinity of less than 10 wt %.

Aspect A7 includes the colored glass article of any preceding aspect, wherein the depth of compression is less than or equal to 0.3t.

Aspect A8 includes the colored glass article of any preceding aspect, wherein the surface compressive stress is greater than or equal to 400 MPa.

Aspect A9 includes the colored glass article of any preceding aspect, wherein the central tension is greater than or equal to 70 MPa.

Aspect A10 includes the colored glass article of any preceding aspect, wherein the transmittance color coordinate in the CIELAB color space comprises an a* value and |a*| is ≥0.3.

Aspect A11 includes the colored glass article of any preceding aspect, wherein the transmittance color coordinate in the CIELAB color space comprises a b* value and |b*| is ≥0.5.

Aspect A12 includes the colored glass article of any preceding aspect, wherein the transmittance color coordinate in the CIELAB color space comprises an a* value and a b* value, wherein |a*| is ≥0.3 and |b*| is ≥0.5.

Aspect A13 includes the colored glass article of any preceding aspect, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=0.2879·a*+27.818; b*=7.0833·a*−94.5; b*=0.45·a*+104.5; and b*=15.3·a*+253.

Aspect A14 includes the colored glass article of aspect A13, wherein the colorant comprises Ag.

Aspect A15 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=7.0833·a*−94.5; b*=−0.9583·a*+146.75; b*=2.6957·a*−50.565; and b*=33.

Aspect A16 includes the colored glass article of aspect A15 wherein the colorant comprises Ag.

Aspect A17 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=2.6957·a*−50.565; a*=54; b*=1.0769·a*−17.154; and b*=6.6667·a*−173.67.

Aspect A18 includes the colored glass article of aspect A17 wherein the colorant comprises Ag.

Aspect A19 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=0.2879·a*+27.818; a*=0; b*=−1.375·a*+1; and b*=9.333·a*+86.667, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5.

Aspect A20 includes the colored glass article of aspect A19, wherein the colorant comprises Ag.

Aspect A21 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=0.0833·a*+20.833; b*=2.1182·a*−32.073; b*=−0.3; and b*=1.5929·a*−0.3, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5.

Aspect A22 includes the colored glass article of aspect A21, wherein the colorant comprises Ag.

Aspect A23 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −18 and less than or equal to 0.3 and b* values greater than or equal to 0.5 and less than or equal to 82.

Aspect A24 includes the colored glass article of claim A23, wherein the colorant comprises Cr₂O₃.

Aspect A25 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −18 and less than or equal to 18, exclusive of a* greater than −0.3 and less than 0.3, and b* greater than or equal to 0.5 and less than or equal to 82.

Aspect A26 includes the colored glass article of aspect A25, wherein the colorant comprises Cr₂O₃ and NiO.

Aspect A27 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −20 and less than or equal to 60, exclusive of a* greater than −0.3 and less than 0.3, and b* greater than or equal to −90 and less than or equal to 85, exclusive of b* values greater than −0.5 and less than 0.5.

Aspect A28 includes the colored glass article of aspect A27, wherein the colorant comprises Cr₂O₃ and Co₃O₄.

Aspect A29 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to −0.3, and b* values greater than or equal to 0.5 and less than or equal to 82.

Aspect A30 includes the colored glass article of aspect A29, wherein the colorant comprises Cr₂O₃ and CuO.

Aspect A31 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to 20, exclusive of a* greater than −0.3 and less than 0.3, and b* values greater than or equal to 0.5 and less than or equal to 75.

Aspect A32 includes the colored glass article of aspect A31, wherein the colorant comprises Cr₂O₃, NiO, and CuO.

Aspect A33 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −15 and less than or equal to 65, exclusive of a* greater than −0.3 and less than 0.3, and b* values greater than or equal to −90 and less than or equal to 80, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A34 includes the colored glass article of aspect A33, wherein the colorant comprises Cr₂O₃, NiO, and Co₃O₄.

Aspect A35 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to 60, exclusive of a* greater than −0.3 and less than 0.3, and b* values greater than or equal to −90 and less than or equal to 80, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A36 includes the colored glass article of aspect A35, wherein the colorant comprises Cr₂O₃, CuO, and Co₃O₄.

Aspect A37 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to 60, exclusive of a* greater than −0.3 and less than 0.3, and b* values greater than or equal to −90 and less than or equal to 80, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A38 includes the colored glass article of aspect A37, wherein the colorant comprises Cr₂O₃, NiO, CuO, and Co₃O₄.

Aspect A39 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −15 and less than or equal to −0.3 and b* values greater than or equal to −10 and less than or equal to 10, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A40 includes the colored glass article of aspect A39, wherein the colorant comprises at least one of NiO, CuO, TiO₂, Co₃O₄, Cr₂O₃, and CeO₂.

Aspect A41 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −5 and less than or equal to 25, exclusive of a* greater than −0.3 and less than 0.3, and b* greater than or equal to −20 and less than or equal to 5, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A42 includes the colored glass article of aspect A41, wherein the colorant comprises Au.

Aspect A43 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −10 and less than or equal to 25, exclusive of a* greater than −0.3 and less than 0.3, and b* values greater than or equal to −20 and less than or equal to 5, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A44 includes the colored glass article of aspect A43, wherein the colorant comprises Au.

Aspect A45 includes the colored glass article of any of aspects A1-A12, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −15 and less than or equal to −0.3, and b* values greater than or equal to −10 and less than or equal to 10, exclusive of b* greater than −0.5 and less than 0.5.

Aspect A46 includes the colored glass article of aspect A45, wherein the colorant comprises at least one of Cr₂O₃, Au, Ag, CuO, NiO, Co₃O₄, TiO₂, and CeO₂.

Aspect A47 includes an electronic device comprising a housing, the housing comprising a colored glass article according to any preceding aspect.

Additional features and advantages of the colored glass articles described herein will be set forth in the detailed description that follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the embodiments described herein, including the detailed description which follows, the claims, as well as the appended drawings.

It is to be understood that both the foregoing general description and the following detailed description describe various embodiments and are intended to provide an overview or framework for understanding the nature and character of the claimed subject matter. The accompanying drawings are included to provide a further understanding of the various embodiments, and are incorporated into and constitute a part of this specification. The drawings illustrate the various embodiments described herein, and together with the description serve to explain the principles and operations of the claimed subject matter.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a plan view of an electronic device incorporating any of the colored glass articles according to one or more embodiments described herein;

FIG. 2 is a perspective view of the electronic device of FIG. 1 ;

FIG. 3A is a plot of a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) as a function of a heat treatment temperature of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 3B is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 3A;

FIG. 3C is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 3A;

FIG. 4A is a plot of a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) as a function of a heat treatment temperature of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 4B is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 4A;

FIG. 4C is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 4A;

FIG. 5A is a plot of a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) as a function of a heat treatment temperature of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 5B is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 5A;

FIG. 5C is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 5A;

FIG. 6A is a plot of a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) as a function of a heat treatment temperature of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 6B is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 6A;

FIG. 6C is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 6A;

FIG. 7 is a plot of R₂O—Al₂O₃ vs. a* CIELAB space (x-axis: R₂O—Al₂O₃; y-axis: a*) of colored glass articles made from glass compositions and subjected to a heat treatment according to one or more embodiments described herein;

FIG. 8 is a plot of R₂O—Al₂O₃ vs. b* CIELAB space (x-axis: R₂O—Al₂O₃; y-axis: b*) of colored glass articles made from glass compositions and subjected to a heat treatment according to one or more embodiments described herein;

FIG. 9 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 10 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 9 ;

FIG. 11 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 9 ;

FIG. 12 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 13 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 12 ;

FIG. 14 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 12 ;

FIG. 15 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 16 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 15 ;

FIG. 17 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 15 ;

FIG. 18 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 19 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 18 ;

FIG. 20 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 18 ;

FIG. 21 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 22 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 21 ;

FIG. 23 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 21 ;

FIG. 24 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 25 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 24 ;

FIG. 26 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 24 ;

FIG. 27 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 28 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 27 ;

FIG. 29 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 27 ;

FIG. 30 is a plot of a projected a* vs. b* CIELAB space (x-axis: a*; y-axis: b*) of a colored glass article made from a glass composition according to one or more embodiments described herein;

FIG. 31 is a plot of a projected a* vs. L* CIELAB space (x-axis: a*; y-axis: L*) of the colored glass article of FIG. 30 ;

FIG. 32 is a plot of a projected b* vs. L* CIELAB space (x-axis: b*; y-axis: L*) of the colored glass article of FIG. 30 ;

FIG. 33A graphically depicts a plot of projected a* vs. L* CIELAB spaces (y-axis: a*; x-axis: L*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 33B graphically depicts a plot of projected b* vs. L* CIELAB spaces (y-axis: b*; x-axis: L*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 33C graphically depicts a plot of projected a* vs. b* CIELAB spaces (y-axis: b*; x-axis: a*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 34A graphically depicts a plot of projected a* vs. L* CIELAB spaces (y-axis: a*; x-axis: L*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 34B graphically depicts a plot of projected b* vs. L* CIELAB spaces (y-axis: b*; x-axis: L*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 34C graphically depicts a plot of projected a* vs. b* CIELAB spaces (y-axis: b*; x-axis: a*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 35 graphically depicts absorbance spectra (y-axis) as a function of wavelength (x-axis) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 36 graphically depicts absorbance spectra (y-axis) as a function of wavelength (x-axis) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 37 graphically depicts absorbance spectra (y-axis) as a function of wavelength (x-axis) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 38 graphically depicts absorbance spectra (y-axis) as a function of wavelength (x-axis) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 39 graphically depicts absorbance (y-axis) as a function of wavelength (x-axis) spectra of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 40A graphically depicts a plot of a projected a* vs. L* CIELAB space (y-axis: a*; x-axis: L*) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 40B graphically depicts a plot of a projected b* vs. L* CIELAB space (y-axis: b*; x-axis: L*) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 40C graphically depicts a plot of a projected a* vs. b* CIELAB space (y-axis: b*; x-axis: a*) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 41 graphically depicts an absorbance spectra (y-axis) as a function of wavelength (x-axis) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 42A graphically depicts a plot of a projected b* vs. L* CIELAB space (y-axis: b*; x-axis: L*) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 42B graphically depicts a plot of a projected a* vs. b* CIELAB space (y-axis: b*; x-axis: a*) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 42C graphically depicts a plot of a projected a* vs. L* CIELAB space (y-axis: a*; x-axis: L*) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 43 graphically depicts an absorbance spectra (y-axis) as a function of wavelength (x-axis) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 44A is a transmission electron microscopy (TEM) micrograph of anisotropic silver particles in a colored glass article according to one or more embodiments of the present disclosure;

FIG. 44B is a magnified view of a portion of the TEM micrograph of FIG. 44A showing an anisotropic silver particle in a colored glass article according to one or more embodiments of the present disclosure;

FIG. 44C is a magnified view of a portion of the TEM micrograph of FIG. 44B showing an anisotropic silver particle in a colored glass article according to one or more embodiments of the present disclosure;

FIG. 45 graphically depicts a transmittance spectra (y-axis) as a function of wavelength (x-axis) of a colored glass article heat treated at the same temperature for different heat treatment times, according to one or more embodiments of the present disclosure;

FIG. 46 graphically depicts a transmittance spectra (y-axis) as a function of wavelength (x-axis) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 47 graphically depicts a transmittance spectra (y-axis) as a function of wavelength (x-axis) of a colored glass article according to one or more embodiments of the present disclosure;

FIG. 48 is graphically depicts a plot of a projected a* vs. b* CIELAB space (y-axis: b*; x-axis: a*) of colored glass articles according to one or more embodiments of the present disclosure;

FIG. 49 is a schematic representation of a sample utilized in the double cantilever beam (DCB) procedure to determine the fracture toughness κ_(IC) and a cross-section thereof;

FIG. 50 graphically depicts the results of an incremental face drop on sandpaper (i.e., a “drop test”) for select inventive examples and a comparative example; and

FIG. 51 schematically depicts a drop test conducted on ion exchange strengthened colored glass articles.

DETAILED DESCRIPTION

Reference will now be made in detail to various embodiments of glass compositions and colored glass articles formed therefrom having a desired color. According to embodiments, a colored glass article includes: greater than or equal to 50 mol % and less than or equal to 80 mol % SiO₂; greater than or equal to 7 mol % and less than or equal to 20 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 35 mol % R₂O, wherein R₂O comprises at least one of Li₂O, Na₂O, and K₂O; greater than 1×10⁻⁶ mol % and less than or equal to 10 mol % of a colorant, wherein the colorant comprises at least one of Cr₂O₃, Au, Ag, CuO, NiO, Co₃O₄, TiO₂, CeO₂; and greater than or equal to 12 mol % and less than or equal to 24 mol % of Al₂O₃+MgO+CaO+ZnO. The colored glass article may further include a transmittance color coordinate in the CIELAB color space comprising an L* value greater than or equal to 55 and less than or equal to 96.5 as measured under F2 illumination and a 10° standard observer angle; a compressive stress profile with a depth of compression greater than or equal to 0.15t where t is a thickness of the colored glass article, a compressive stress greater than or equal to 200 MPa, and a central tension greater than or equal to 60 MPa; a dielectric constant from 5.6 to 6.4 over a frequency range from 10 GHz to 60 GHz; and the thickness t is greater than or equal to 0.4 mm and less than or equal to 5 mm. Various embodiments of colored glass articles will be described herein with specific reference to the appended drawings.

Ranges may be expressed herein as from “about” one particular value, and/or to “about” another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another embodiment. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint.

Directional terms as used herein—for example up, down, right, left, front, back, top, bottom—are made only with reference to the figures as drawn and are not intended to imply absolute orientation.

Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order, nor that with any apparatus specific orientations be required. Accordingly, where a method claim does not actually recite an order to be followed by its steps, or that any apparatus claim does not actually recite an order or orientation to individual components, or it is not otherwise specifically stated in the claims or description that the steps are to be limited to a specific order, or that a specific order or orientation to components of an apparatus is not recited, it is in no way intended that an order or orientation be inferred, in any respect. This holds for any possible non-express basis for interpretation, including: matters of logic with respect to arrangement of steps, operational flow, order of components, or orientation of components; plain meaning derived from grammatical organization or punctuation, and; the number or type of embodiments described in the specification.

As used herein, the singular forms “a,” “an” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to “a” component includes aspects having two or more such components, unless the context clearly indicates otherwise.

In the embodiments of the glass compositions and the resultant colored glass articles described herein, the concentrations of constituent components in oxide form (e.g., SiO₂, Al₂O₃, and the like) are specified in mole percent (mol %) on an oxide basis, unless otherwise specified.

In embodiments of the glass compositions and the resultant colored glass articles described herein, the concentrations of Au and Cl are specified in mole percent (mol %), unless otherwise specified.

In embodiments of the glass compositions and the resultant colored glass articles described herein, the concentration of a cation “M” is specified in mole percent (mol %), unless otherwise specified.

The term “substantially free,” when used to describe the concentration and/or absence of a particular constituent component in a glass composition and the resultant colored glass article, means that the constituent component is not intentionally added to the glass composition and the resultant colored glass article. However, the glass composition and the resultant colored glass article may contain traces of the constituent component as a contaminant or tramp in amounts of less than 200 ppm unless specified otherwise herein. It is noted that the definition of “substantially free” is exclusive of gold (Au) which may be intentionally added to the glass composition in relatively small amounts such as, for example and without limitation, amounts less than 200 ppm (or the equivalent in mol %) to achieve a desired color in the resultant colored glass article.

The terms “0 mol %” and “free,” when used to describe the concentration and/or absence of a particular constituent component in a glass composition, means that the constituent component is not present in the glass composition.

Fracture toughness (K_(IC)) represents the ability of a glass composition to resist fracture. Fracture toughness is measured on a non-strengthened glass article, such as measuring the K_(IC) value prior to ion exchange (IOX) treatment of the glass article, thereby representing a feature of a glass substrate prior to IOX. The fracture toughness test methods described herein are not suitable for glasses that have been exposed to IOX treatment. Accordingly, where the fracture toughness of an ion exchanged article is referred to, it means the fracture toughness of a non-ion exchanged article with the same composition and microstructure (when present) as the center (i.e., a point located at least 0.5t from every surface of the article or substrate where t is the thickness of the article or substrate) of the ion exchanged article (which corresponds to the portion of the ion exchanged article least affected by the ion exchange process and, hence, a composition and microstructure comparable to a non-ion exchanged glass). Fracture toughness is measured by the chevron notched short bar method. The chevron notched short bar (CNSB) method is disclosed in Reddy, K. P. R. et al, “Fracture Toughness Measurement of Glass and Ceramic Materials Using Chevron-Notched Specimens,” J. Am. Ceram. Soc., 71 [6], C-310-C-313 (1988) except that Y*_(m) is calculated using equation 5 of Bubsey, R. T. et al., “Closed-Form Expressions for Crack-Mouth Displacement and Stress Intensity Factors for Chevron-Notched Short Bar and Short Rod Specimens Based on Experimental Compliance Measurements,” NASA Technical Memorandum 83796, pp. 1-30 (October 1992). Unless otherwise specified, all fracture toughness values were measured by chevron notched short bar (CNSB) method.

Alternative K_(IC) fracture toughness measurements were performed on some samples with the double cantilever beam (DCB) procedure. The DCB specimen geometry is shown in FIG. 49 with parameters being the crack length a, applied load P, cross-sectional dimensions w and 2h, and the thickness of the crack-guiding groove b. The samples were cut into rectangles of width 2h=1.25 cm and a thickness ranging from, w=0.3 mm to 1 mm, with the overall length of the sample, which is not a critical dimension, varying from 5 cm to 10 cm. A hole was drilled on both ends with a diamond drill to provide a means of attaching the sample to a sample holder and to the load. A crack “guiding groove” was cut down the length of the sample on both flat faces using a wafer dicing saw with a diamond blade, leaving a “web” of material, approximately half the total plate thickness (dimension b in FIG. 49 ), with a height of 180 μm corresponding to the blade thickness. The high precision dimensional tolerances of the dicing saw allow for minimal sample-to-sample variation. The dicing saw was also used to cut an initial crack where a=15 mm. As a consequence of this final operation a very thin wedge of material was created near the crack tip (due to the blade curvature) allowing for easier crack initiation in the sample. The samples were mounted in a metal sample holder with a steel wire in the bottom hole of the sample. The samples were also supported on the opposite end to keep the samples level under low loading conditions. A spring in series with a load cell (FUTEK, LSB200) was hooked to the upper hole which was then extended, to gradually apply load, using rope and a high precision slide. The crack was monitored using a microscope having a 5 μm resolution attached to a digital camera and a computer. The applied stress intensity, K_(P), was calculated using the following equation:

$K_{P} = {\left\lbrack \frac{P \cdot a}{\left( {w \cdot b} \right)^{0.5}h^{1.5}} \right\rbrack\left\lbrack {{{3.4}7} + {{2.3}2\frac{h}{a}}} \right\rbrack}$ For each sample, a crack was first initiated at the tip of the web, and then the starter crack was carefully sub-critically grown until the ratio of dimensions a/h was greater than 1.5 to accurately calculate stress intensity. At this point the crack length, a, was measured and recorded using a traveling microscope with 5 μm resolution. A drop of toluene was then placed into the crack groove and wicked along the length of the groove by capillary forces, pinning the crack from moving until the fracture toughness is reached. The load was then increased until sample fracture occurred, and the critical stress intensity K_(IC) calculated from the failure load and sample dimensions, with K_(P) being equivalent to K_(IC) due to the measurement method.

The viscosity of the glass composition, as described herein, is measured according to ASTM C965-96.

The term “melting point,” as used herein, refers to the temperature at which the viscosity of the glass composition is 200 poise.

The term “softening point,” as used herein, refers to the temperature at which the viscosity of the glass composition is 1×10^(7.6) poise. The softening point is measured according to the parallel plate viscosity method which measures the viscosity of inorganic glass from 10⁷ to 10⁹ poise as a function of temperature, similar to ASTM C1351M.

The term “annealing point” as used herein, refer to the temperature at which the viscosity of the glass composition is 1×10^(13.18) poise.

The term “strain point,” as used herein, refers to the temperature at which the viscosity of the glass composition is 1×10^(14.68) poise.

The term “coefficient of thermal expansion” and “CTE,” as described herein, is measured in accordance with ASTM E228-85 over the temperature range of 25° C. to 300° C. and is expressed in terms of “×10⁻⁷/° C.” as an average over the temperature range.

The term “liquidus viscosity,” as used herein, refers to the viscosity of the glass composition at the onset of devitrification (i.e., at the liquidus temperature as determined with the gradient furnace method according to ASTM C829-81).

The term “liquidus temperature,” as used herein, refers to the temperature at which the glass composition begins to devitrify as determined with the gradient furnace method according to ASTM C829-81.

Surface compressive stress is measured with a surface stress meter (FSM) such as commercially available instruments such as the FSM-6000, manufactured by Orihara Industrial Co., Ltd. (Japan). Surface stress measurements rely upon the measurement of the stress optical coefficient (SOC), which is related to the birefringence of the glass article. SOC, in turn, is measured according to Procedure C (Glass Disc Method) described in ASTM standard C770-16, entitled “Standard Test Method for Measurement of Glass Stress-Optical Coefficient,” the contents of which are incorporated herein by reference in their entirety. Depth of compression (DOC) is also measured with the FSM. The maximum central tension (CT) values are measured using a scattered light polariscope (SCALP) technique known in the art.

The term “depth of compression” (DOC), as used herein, refers to the position in the article where compressive stress transitions to tensile stress.

Transmittance data (total transmittance and diffuse transmittance) in the visible spectrum is measured with a Lambda 950 UV/Vis/NIR Spectrophotometer manufactured by PerkinElmer Inc. (Waltham, Mass. USA). The Lambda 950 apparatus was fitted with a 150 mm integrating sphere. Data was collected using an open beam baseline and a Spectralon® reference reflectance disk. For total transmittance (Total Tx), the sample is fixed at the integrating sphere entry point.

The term “average transmittance,” as used herein with respect to the visible spectrum, refers to the average of transmittance measurements made within a given wavelength range with each whole numbered wavelength weighted equally. In embodiments described herein, the “average transmittance” with respect to the visible spectrum is reported over the wavelength range from 380 nm to 750 nm (inclusive of endpoints). Unless otherwise specified, the average transmittance is indicated for article thicknesses from 0.4 mm to 5 mm, inclusive of endpoints. Unless otherwise specified, when average transmittance is indicated, this means that each thickness within the range of thicknesses from 0.4 mm to 5 mm has an average transmittance as specified. For example, colored glass articles having average transmittances of 10% to 92% over the wavelength range from 380 nm to 750 nm means that each thickness within the range of 0.4 mm to 5 mm (e.g., 0.6 mm, 0.9 mm, 2 mm, etc.) has an average transmittance in the range of 10% to 92% for the wavelength range from 380 nm to 750 nm.

The term “CIELAB color space,” as used herein, refers to a color space defined by the International Commission on Illumination (CIE) in 1976. It expresses color as three values: L* for the lightness from black (0) to white (100), a* from green (−) to red (+), and b* from blue (−) to yellow (+). Unless otherwise specified, the L*, a*, and b* values are indicated for article thicknesses of 0.4 mm to 5 mm (inclusive of endpoints) in the thickness direction of the sample under F2 illumination and a 10° standard observer angle. Unless otherwise specified, this means that each thickness within the range of thicknesses has L*, a*, and b* coordinates falling within the specified range(s) for L*, a*, and b* coordinates. For example, a colored glass article having an L* value within the range from 55 to 96.5 means that each thickness within the range of 0.4 mm to 5 mm (e.g., 0.6 mm, 0.9 mm, 2 mm, etc.) has an L* in the range of 55 to 96.5.

The term “color gamut,” as used herein, refers to the pallet of colors that may be achieved by the colored glass articles within the CIELAB color space.

The “optical transmission spectra,” described herein, were obtained using an Agilent Cary 60 spectrophotometer with a scan range of 250 nm to 800 nm, a scan step of 2 nm, a signal average of 0.5 s, and a spot size of 2 mm. The optical transmission data obtained were used to plot coordinates in the CIELAB color space as described in R. S. Berns, Billmeyer and Saltzman's Principles of Color Technology, 3rd. Ed., John Wiley & Sons, New York (2000).

The term “projected color gamut,” as used herein, refers to the line, surface, volume, or overlapping volume occupied by the colored glass article within the three-dimensional CIELAB color space and represents the pallet of colors that may be achieved by the colored glass articles within the CIELAB color space based upon the concentration of colorant(s) present in the colored glass article. The projected color gamuts shown herein were produced using the plotting routine Gnuplot Version 5.4. Specifically, Gnuplot was used to display projections of the CIELAB color coordinates for the transmitted colors under F2 illumination for the CIE 1976 10° Standard Observer. The transmittance spectrum through a flat sheet of glass is given by the following expression:

${{T(\lambda)} = \frac{\left\lbrack {1 - {R(\lambda)}} \right\rbrack^{2} \times {\exp\left\lbrack {- {\sum_{i}{N_{i}{\sigma_{i}(\lambda)}t}}} \right\rbrack}}{1 - {{R(\lambda)}^{2} \times {\exp\left\lbrack {{- 2}{\sum_{i}{N_{i}{\sigma_{i}(\lambda)}t}}} \right\rbrack}}}},$

where R is the Fresnel intensity reflection coefficient of the glass, N_(i) and σ_(i) represent the number density and absorption cross section, respectively, for the individual dopants, λ is the optical wavelength, and t is the thickness of the glass. The color coordinates were calculated from the transmittance spectra through 1.5 mm of the colored glass article. The expression for the transmittance was evaluated by varying the dopant concentrations (N_(i)) for the combinations of the colorants from 0 to a maximum value. As described herein, the maximum values for Cr₂O₃, NiO, CuO, and Co₃O₄ were set to 2 mol %, 4 mol %, 20 mol %, and 2 mol %, respectively for purposes of determining the projected color gamut.

The dielectric constant of the colored glass articles may be measured using a split post dielectric resonator (SPDR), as is known in the art, at a frequency of 10 GHz. The dielectric constant was measured on samples of the colored glass article having a length of 3 inches (76.2 mm), a width of 3 inches (76.2 mm), and a thickness of less than 0.9 mm.

The dielectric constant of the colored glass articles may also be measured over a range of frequencies from 10 GHz to 60 GHz using a double concave reflecting mirror Fabry-Perot open resonator, as is known in the art. The dielectric constant can be measured at different frequencies by adjusting the mirror spacing in the open resonator. The dielectric constant may be measured on samples of the colored glass article having a length of 120 mm, a width of 120 mm, and a thickness of 2 mm or less. While not wishing to be bound by theory, it is believed that the dielectric constant of the colored glass articles measured at 10 GHz approximates the dielectric constant at each frequency in the range from 10 GHz to 60 GHz.

The dielectric constant Dk of the colored glass article may be calculated according to the equation: Dk=3.802946+0.01747*B₂O₃ (mol %)+0.058769*Al₂O₃ (mol %)+0.080876*Li₂O (mol %)+0.148433*Na₂O (mol %)+0.153264*K₂O (mol %)+0.045179*MgO (mol %)+0.080113*CaO (mol %).

Colorants have been added to conventional aluminosilicate glass compositions to achieve glass articles having a desired color. However, such glass articles may not have the desired mechanical or electrical properties suitable for some end user applications. For example, glasses used in the housings of consumer electronic devices may require robust mechanical properties to withstand the rigors of day-to-day use and/or dielectric properties to allow for reception of wireless signals by the device.

Moreover, it may be desirable to have colored glass articles having mechanical and dielectric properties such that the glass article is suitable for use with consumer electronic devices while also providing the same colored glass articles in a range of different colors. However, simply including colorants in aluminosilicate glass compositions may not produce the desired color. For example, some colorants may have relatively low vaporization temperatures and may vaporize and diffuse out of the glass during manufacturing. The relatively low retention of the colorant limits the color gamut that may be achieved.

Disclosed herein are glass compositions and colored glass articles formed therefrom having superior ion-exchange performance. The colored glass articles also have dielectric properties, such as dielectric constants, such that the glass articles are suitable for use as enclosures for consumer electronic devices such as smart phones, tablets, and computers. The use of various colorants and combinations of colorants expands the color gamut that may be achieved in the resultant colored glass articles

The glass compositions and colored glass articles described herein may be described as aluminoborosilicate glass compositions and colored glass articles and comprise SiO₂, Al₂O₃, and B₂O₃. In addition to SiO₂, Al₂O₃, and B₂O₃, the glass compositions and colored glass articles described herein include one or more colorants in a colorant package to impart a desired color to the resultant colored glass article. The glass compositions and colored glass articles described herein also include alkali oxides, such as Li₂O and Na₂O, to enable the ion-exchangeability of the colored glass articles. In embodiments, the glass compositions and colored glass articles described herein may further include other components to improve colorant retention and produce colored glass articles having the desired color. In embodiments, the difference between R₂O and Al₂O₃ (i.e. R₂O (mol %)−Al₂O₃ (mol %)) in the glass compositions and resultant colored glass articles described herein may be adjusted to produce a desired observable color (e.g., pink, purple, red, orange, or blue). In embodiments, the viscosity of the glass composition may be adjusted to prevent devitrification of the glass composition.

SiO₂ is the primary glass former in the glass compositions described herein and may function to stabilize the network structure of the colored glass articles. The concentration of SiO₂ in the glass compositions and resultant colored glass articles should be sufficiently high (e.g., greater than or equal to 40 mol %) to enhance the chemical durability of the glass composition and, in particular, the resistance of the glass composition to degradation upon exposure to acidic solutions, basic solutions, and in water. The amount of SiO₂ may be limited (e.g., to less than or equal to 80 mol %) to control the melting point of the glass composition, as the melting point of pure SiO₂ or high SiO₂ glasses is undesirably high. Thus, limiting the concentration of SiO₂ may aid in improving the meltability and the formability of the resultant colored glass article.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 40 mol % and less than or equal to 80 mol % SiO₂ or even 50 mol % and less than or equal to 80 mol % SiO₂. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 45 mol % and less than or equal to 67 mol % SiO₂ or even greater than or equal to 53 mol % and less than or equal to 67 mol % SiO₂. In embodiments, the concentration of SiO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 40 mol %, greater than or equal to 45 mol %, greater than or equal to 50 mol %, greater than or equal to 52 mol %, greater than or equal to 53 mol %, greater than or equal to 54 mol %, greater than or equal to 55 mol %, greater than or equal to 56 mol %, greater than or equal to 57 mol %, greater than or equal to 58 mol %, or even greater than or equal to 60 mol %. In embodiments, the concentration of SiO₂ in the glass composition and the colored resultant glass article may be less than or equal to 80 mol %, less than or equal to 75 mol %, less than or equal to 73 mol %, less than or equal to 71 mol %, less than or equal to 70 mol %, less than or equal to 68 mol %, less than or equal to 67 mol %, less than or equal to 66 mol %, less than or equal to 65 mol %, less than or equal to 64 mol %, less than or equal to 63 mol %, less than or equal to 62 mol %, less than or equal to 61 mol %, less than or equal to 60 mol %, or even less than or equal to 59 mol %. In embodiments, the concentration of SiO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 40 mol % and less than or equal to 70 mol %, greater than or equal to 40 mol % and less than or equal to 67 mol %, greater than or equal to 40 mol % and less than or equal to 65 mol % greater than or equal to 40 mol % and less than or equal to 63 mol %, greater than or equal to 40 mol % and less than or equal to 62 mol %, greater than or equal to 40 mol % and less than or equal to 61 mol %, greater than or equal to 40 mol % and less than or equal to 60 mol %, greater than or equal to 45 mol % and less than or equal to 70 mol %, greater than or equal to 45 mol % and less than or equal to 67 mol %, greater than or equal to 45 mol % and less than or equal to 65 mol % greater than or equal to 45 mol % and less than or equal to 63 mol %, greater than or equal to 45 mol % and less than or equal to 62 mol %, greater than or equal to 45 mol % and less than or equal to 61 mol %, greater than or equal to 45 mol % and less than or equal to 60 mol %, greater than or equal to 50 mol % and less than or equal to 70 mol %, greater than or equal to 50 mol % and less than or equal to 67 mol %, greater than or equal to 50 mol % and less than or equal to 65 mol %, greater than or equal to 50 mol % and less than or equal to 63 mol %, greater than or equal to 50 mol % and less than or equal to 62 mol %, greater than or equal to 50 mol % and less than or equal to 61 mol %, greater than or equal to 50 mol % and less than or equal to 60 mol %, greater than or equal to 50 mol % and less than or equal to 59 mol %, greater than or equal to 53 mol % and less than or equal to 70 mol %, greater than or equal to 53 mol % and less than or equal to 67 mol %, greater than or equal to 53 mol % and less than or equal to 65 mol % greater than or equal to 53 mol % and less than or equal to 63 mol %, greater than or equal to 53 mol % and less than or equal to 62 mol %, greater than or equal to 53 mol % and less than or equal to 61 mol %, greater than or equal to 53 mol % and less than or equal to 60 mol %, greater than or equal to 53 mol % and less than or equal to 59 mol %, greater than or equal to 55 mol % and less than or equal to 70 mol %, greater than or equal to 55 mol % and less than or equal to 67 mol %, greater than or equal to 55 mol % and less than or equal to 65 mol % greater than or equal to 55 mol % and less than or equal to 63 mol %, greater than or equal to 55 mol % and less than or equal to 62 mol %, greater than or equal to 55 mol % and less than or equal to 61 mol %, greater than or equal to 55 mol % and less than or equal to 60 mol %, greater than or equal to 55 mol % and less than or equal to 59 mol %, greater than or equal to 56 mol % and less than or equal to 70 mol %, greater than or equal to 56 mol % and less than or equal to 67 mol %, greater than or equal to 56 mol % and less than or equal to 65 mol % greater than or equal to 56 mol % and less than or equal to 63 mol %, greater than or equal to 56 mol % and less than or equal to 62 mol %, greater than or equal to 56 mol % and less than or equal to 61 mol %, greater than or equal to 56 mol % and less than or equal to 60 mol %, greater than or equal to 56 mol % and less than or equal to 59 mol %, greater than or equal to 57 mol % and less than or equal to 70 mol %, greater than or equal to 57 mol % and less than or equal to 67 mol %, greater than or equal to 57 mol % and less than or equal to 65 mol % greater than or equal to 57 mol % and less than or equal to 63 mol %, greater than or equal to 57 mol % and less than or equal to 62 mol %, greater than or equal to 57 mol % and less than or equal to 61 mol %, greater than or equal to 57 mol % and less than or equal to 60 mol %, or even greater than or equal to 57 mol % and less than or equal to 59 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of SiO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 50 mol % and less than or equal to 80 mol %, greater than or equal to 50 mol % and less than or equal to 75 mol %, greater than or equal to 50 mol % and less than or equal to 73 mol %, greater than or equal to 50 mol % and less than or equal to 71 mol %, greater than or equal to 50 mol % and less than or equal to 69 mol %, greater than or equal to 52 mol % and less than or equal to 80 mol %, greater than or equal to 52 mol % and less than or equal to 75 mol %, greater than or equal to 52 mol % and less than or equal to 73 mol %, greater than or equal to 52 mol % and less than or equal to 71 mol %, greater than or equal to 52 mol % and less than or equal to 69 mol %, greater than or equal to 54 mol % and less than or equal to 80 mol %, greater than or equal to 54 mol % and less than or equal to 75 mol %, greater than or equal to 54 mol % and less than or equal to 73 mol %, greater than or equal to 54 mol % and less than or equal to 71 mol %, greater than or equal to 54 mol % and less than or equal to 69 mol %, greater than or equal to 56 mol % and less than or equal to 80 mol %, greater than or equal to 56 mol % and less than or equal to 75 mol %, greater than or equal to 56 mol % and less than or equal to 73 mol %, greater than or equal to 56 mol % and less than or equal to 71 mol %, greater than or equal to 56 mol % and less than or equal to 69 mol %, greater than or equal to 58 mol % and less than or equal to 80 mol %, greater than or equal to 58 mol % and less than or equal to 75 mol %, greater than or equal to 58 mol % and less than or equal to 73 mol %, greater than or equal to 58 mol % and less than or equal to 71 mol %, greater than or equal to 58 mol % and less than or equal to 69 mol %, greater than or equal to 50 mol % and less than or equal to 80 mol %, greater than or equal to 60 mol % and less than or equal to 75 mol %, greater than or equal to 60 mol % and less than or equal to 73 mol %, greater than or equal to 60 mol % and less than or equal to 71 mol %, or even greater than or equal to 60 mol % and less than or equal to 69 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of SiO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 52 mol % and less than or equal to 70 mol %, greater than or equal to 52 mol % and less than or equal to 68 mol %, greater than or equal to 52 mol % and less than or equal to 66 mol %, greater than or equal to 52 mol % and less than or equal to 65 mol %, greater than or equal to 52 mol % and less than or equal to 64 mol %, greater than or equal to 53 mol % and less than or equal to 70 mol %, greater than or equal to 53 mol % and less than or equal to 68 mol %, greater than or equal to 53 mol % and less than or equal to 66 mol %, greater than or equal to 53 mol % and less than or equal to 65 mol %, or greater than or equal to 53 mol % and less than or equal to 64 mol %, greater than or equal to 54 mol % and less than or equal to 70 mol %, greater than or equal to 54 mol % and less than or equal to 68 mol %, greater than or equal to 54 mol % and less than or equal to 66 mol %, greater than or equal to 54 mol % and less than or equal to 65 mol %, or greater than or equal to 54 mol % and less than or equal to 64 mol %, or any and all sub-ranges formed from these endpoints.

Like SiO₂, Al₂O₃ may also stabilize the glass network and additionally provides improved mechanical properties and chemical durability to the glass composition and the resultant colored glass article. The amount of Al₂O₃ may also be tailored to control the viscosity of the glass composition. Al₂O₃ may be included such that the resultant glass composition has the desired fracture toughness (e.g., greater than or equal to 0.7 MPa·m^(1/2)). However, if the amount of Al₂O₃ is too high (e.g., greater than 25 mol %), the viscosity of the glass melt may increase, thereby diminishing the formability of the colored glass article. In embodiments, if the amount of Al₂O₃ is too high, the solubility of one or more colorants of the colorant package in the glass melt may decrease, resulting in the formation of undesirable crystal phases in the glass. For example and without limitation, when the colorant package includes Cr₂O₃, the solubility of Cr₂O₃ in the glass melt may decrease with increasing Al₂O₃ concentrations (e.g., concentrations greater than or equal to 17.5 mol %), leading to the precipitation of undesirable crystal phases. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Cr₂O₃.

Accordingly, in embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 7 mol % and less than or equal to 25 mol % Al₂O₃, greater than or equal to 7 mol % and less than or equal to 20 mol % Al₂O₃, or even greater than or equal to 8 mol % and less than or equal to 20 mol % Al₂O₃. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 10 mol % and less than or equal to 20 mol % Al₂O₃, greater than or equal to 10 mol % and less than or equal to 17.5 mol % Al₂O₃, or even greater than or equal to 12 mol % and less than or equal to 17.25 mol % Al₂O₃. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 11 mol % and less than or equal to 19 mol % Al₂O₃ or greater than or equal to 14 mol % and less than or equal to 17 mol % Al₂O₃. In embodiments, the concentration of Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 7 mol %, greater than or equal to 8 mol %, greater than or equal to 9 mol %, greater than or equal to 10 mol %, greater than or equal to 11 mol %, greater than or equal to 12 mol %, greater than or equal to 12.5 mol %, greater than or equal to 13 mol %, greater than or equal to 13.5 mol %, greater than or equal to 14 mol %, greater than or equal to 14.5 mol %, greater than or equal to 15 mol %, greater than or equal to 15.5 mol %, or even greater than or equal to 16 mol %. In embodiments, the concentration of Al₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 25 mol %, less than or equal to 23 mol %, less than or equal to 20 mol %, less than or equal to 19 mol %, less than or equal to 18 mol %, less than or equal to 17.5 mol %, less than or equal to 17.25 mol %, less than or equal to 17 mol %, less than or equal to 16.75 mol %, or even less than or equal to 16 mol %. In embodiments, the concentration of Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 8 mol % and less than or equal to 20 mol %, greater than or equal to 8 mol % and less than or equal to 18 mol % greater than or equal to 8 mol % and less than or equal to 17.5 mol %, greater than or equal to 8 mol % and less than or equal to 17 mol %, greater than or equal to 10 mol % and less than or equal to 20 mol %, greater than or equal to 10 mol % and less than or equal to 18 mol % greater than or equal to 10 mol % and less than or equal to 17.5 mol %, greater than or equal to 10 mol % and less than or equal to 17 mol %, greater than or equal to 12 mol % and less than or equal to 20 mol %, greater than or equal to 12 mol % and less than or equal to 18 mol % greater than or equal to 12 mol % and less than or equal to 17.5 mol %, greater than or equal to 12 mol % and less than or equal to 17 mol %, greater than or equal to 12.5 mol % and less than or equal to 20 mol %, greater than or equal to 12.5 mol % and less than or equal to 18 mol % greater than or equal to 12.5 mol % and less than or equal to 17.5 mol %, greater than or equal to 12.5 mol % and less than or equal to 17 mol %, greater than or equal to 13 mol % and less than or equal to 20 mol %, greater than or equal to 13 mol % and less than or equal to 18 mol % greater than or equal to 13 mol % and less than or equal to 17.5 mol %, greater than or equal to 13 mol % and less than or equal to 17 mol %, greater than or equal to 13.5 mol % and less than or equal to 20 mol %, greater than or equal to 13.5 mol % and less than or equal to 18 mol % greater than or equal to 13.5 mol % and less than or equal to 17.5 mol %, greater than or equal to 13.5 mol % and less than or equal to 17 mol %, greater than or equal to 14 mol % and less than or equal to 20 mol %, greater than or equal to 14 mol % and less than or equal to 18 mol % greater than or equal to 14 mol % and less than or equal to 17.5 mol %, or even greater than or equal to 14 mol % and less than or equal to 17 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 7 mol % and less than or equal to 25 mol %, greater than or equal to 7 mol % and less than or equal to 23 mol %, greater than or equal to 7 mol % and less than or equal to 20 mol %, greater than or equal to 7 mol % and less than or equal to 17 mol %, greater than or equal to 9 mol % and less than or equal to 25 mol %, greater than or equal to 9 mol % and less than or equal to 23 mol %, greater than or equal to 9 mol % and less than or equal to 20 mol %, greater than or equal to 9 mol % and less than or equal to 17 mol %, greater than or equal to 11 mol % and less than or equal to 25 mol %, greater than or equal to 11 mol % and less than or equal to 23 mol %, greater than or equal to 11 mol % and less than or equal to 20 mol %, greater than or equal to 11 mol % and less than or equal to 17 mol %, greater than or equal to 13 mol % and less than or equal to 25 mol %, greater than or equal to 13 mol % and less than or equal to 23 mol %, greater than or equal to 13 mol % and less than or equal to 20 mol %, greater than or equal to 13 mol % and less than or equal to 17 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 10 mol % and less than or equal to 17.5 mol %, greater than or equal to 10 mol % and less than or equal to 17.25 mol %, greater than or equal to 10 mol % and less than or equal to 17 mol %, greater than or equal to 10 mol % and less than or equal to 16.75 mol %, greater than or equal to 12 mol % and less than or equal to 17.5 mol %, greater than or equal to 12 mol % and less than or equal to 17.25 mol %, greater than or equal to 12 mol % and less than or equal to 17 mol %, greater than or equal to 12 mol % and less than or equal to 16.75 mol %, greater than or equal to 14 mol % and less than or equal to 17.5 mol %, greater than or equal to 14 mol % and less than or equal to 17.25 mol %, greater than or equal to 14 mol % and less than or equal to 17 mol %, greater than or equal to 14 mol % and less than or equal to 16.75 mol %, greater than or equal to 14.5 mol % and less than or equal to 17.5 mol %, greater than or equal to 14.5 mol % and less than or equal to 17.25 mol %, greater than or equal to 14.5 mol % and less than or equal to 17 mol %, greater than or equal to 14.5 mol % and less than or equal to 16.75 mol %, greater than or equal to 15 mol % and less than or equal to 17.5 mol %, greater than or equal to 15 mol % and less than or equal to 17.25 mol %, greater than or equal to 15 mol % and less than or equal to 17 mol %, greater than or equal to 15 mol % and less than or equal to 16.75 mol %, greater than or equal to 15.5 mol % and less than or equal to 17.5 mol %, greater than or equal to 15.5 mol % and less than or equal to 17.25 mol %, greater than or equal to 15.5 mol % and less than or equal to 17 mol %, greater than or equal to 15.5 mol % and less than or equal to 16.75 mol %, greater than or equal to 16 mol % and less than or equal to 17.5 mol %, greater than or equal to 16 mol % and less than or equal to 17.25 mol %, greater than or equal to 16 mol % and less than or equal to 17 mol %, or even greater than or equal to 16 mol % and less than or equal to 16.75 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 10 mol % and less than or equal to 20 mol %, greater than or equal to 10 mol % and less than or equal to 19 mol %, greater than or equal to 10 mol % and less than or equal to 18 mol %, greater than or equal to 10 mol % and less than or equal to 17 mol %, greater than or equal to 10 mol % and less than or equal to 16 mol %, greater than or equal to 11 mol % and less than or equal to 20 mol %, greater than or equal to 11 mol % and less than or equal to 19 mol %, greater than or equal to 11 mol % and less than or equal to 18 mol %, greater than or equal to 11 mol % and less than or equal to 17 mol %, greater than or equal to 11 mol % and less than or equal to 16 mol %, greater than or equal to 12 mol % and less than or equal to 20 mol %, greater than or equal to 12 mol % and less than or equal to 19 mol %, greater than or equal to 12 mol % and less than or equal to 18 mol %, greater than or equal to 12 mol % and less than or equal to 17 mol %, greater than or equal to 12 mol % and less than or equal to 16 mol %, greater than or equal to 13 mol % and less than or equal to 20 mol %, greater than or equal to 13 mol % and less than or equal to 19 mol %, greater than or equal to 13 mol % and less than or equal to 18 mol %, greater than or equal to 13 mol % and less than or equal to 17 mol %, greater than or equal to 13 mol % and less than or equal to 16 mol %, greater than or equal to 14 mol % and less than or equal to 20 mol %, greater than or equal to 14 mol % and less than or equal to 19 mol %, greater than or equal to 14 mol % and less than or equal to 18 mol %, greater than or equal to 14 mol % and less than or equal to 17 mol %, greater than or equal to 14 mol % and less than or equal to 16 mol %, or any and all sub-ranges formed from any of these endpoints.

B₂O₃ decreases the melting point of the glass composition, which may improve retention of certain colorants in the glass, such as, for example and without limitation, Au. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Au. B₂O₃ may also improve the damage resistance of the resultant colored glass article. In addition, B₂O₃ may be added to reduce the formation of non-bridging oxygen, the presence of which may reduce fracture toughness. The concentration of B₂O₃ should be sufficiently high (e.g., greater than or equal to 1 mol %) to reduce the melting point of the glass composition, improve the formability, and increase the fracture toughness of the colored glass article. However, if B₂O₃ is too high (e.g., greater than 15 mol %), the annealing point and strain point may decrease, which increases stress relaxation and reduces the overall strength of the colored glass article.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 1 mol % and less than or equal to 15 mol % B₂O₃, greater than or equal to 1 mol % and less than or equal to 10 mol % B₂O₃, greater than or equal to 3 mol % and less than or equal to 10 mol % B₂O₃, greater than or equal to 3.5 mol % and less than or equal to 9 mol % B₂O₃. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 2 mol % and less than or equal to 12 mol % B₂O₃ or even greater than or equal to 2 mol % and less than or equal to 8 mol % B₂O₃. In embodiments, the concentration of B₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol %, greater than or equal to 2 mol %, greater than or equal to 3 mol %, greater than or equal to 3.5 mol %, greater than or equal to 4 mol %, greater than or equal to 4.5 mol %, greater than or equal to 5 mol %, or even greater than or equal to 5.5 mol %. In embodiments, the concentration of B₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 15 mol %, less than or equal to 12 mol %, less than or equal to 10 mol %, less than or equal to 9 mol %, less than or equal to 8 mol %, less than or equal to 7.5 mol %, less than or equal to 7 mol %, less than or equal to 6.5 mol %, or even less than or equal to 6 mol %. In embodiments, the concentration of B₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol % and less than or equal to 15 mol %, greater than or equal to 1 mol % and less than or equal to 12 mol %, greater than or equal to 1 mol % and less than or equal to 10 mol %, greater than or equal to 1 mol % and less than or equal to 9 mol %, greater than or equal to 1 mol % and less than or equal to 8 mol %, greater than or equal to 1 mol % and less than or equal to 7.5 mol %, greater than or equal to 1 mol % and less than or equal to 7 mol %, greater than or equal to 1 mol % and less than or equal to 6.5 mol %, greater than or equal to 1 mol % and less than or equal to 6 mol %, greater than or equal to 2 mol % and less than or equal to 15 mol %, greater than or equal to 2 mol % and less than or equal to 12 mol %, greater than or equal to 2 mol % and less than or equal to 10 mol %, greater than or equal to 2 mol % and less than or equal to 9 mol %, greater than or equal to 2 mol % and less than or equal to 8 mol %, greater than or equal to 2 mol % and less than or equal to 7.5 mol %, greater than or equal to 2 mol % and less than or equal to 7 mol %, greater than or equal to 2 mol % and less than or equal to 6.5 mol %, greater than or equal to 2 mol % and less than or equal to 6 mol %, greater than or equal to 3 mol % and less than or equal to 15 mol %, greater than or equal to 3 mol % and less than or equal to 12 mol %, greater than or equal to 3 mol % and less than or equal to 10 mol %, greater than or equal to 3 mol % and less than or equal to 9 mol %, greater than or equal to 3 mol % and less than or equal to 8 mol %, greater than or equal to 3 mol % and less than or equal to 7.5 mol %, greater than or equal to 3 mol % and less than or equal to 7 mol %, greater than or equal to 3 mol % and less than or equal to 6.5 mol %, greater than or equal to 3 mol % and less than or equal to 6 mol %, greater than or equal to 3.5 mol % and less than or equal to 15 mol %, greater than or equal to 3.5 mol % and less than or equal to 12 mol %, greater than or equal to 3.5 mol % and less than or equal to 10 mol %, greater than or equal to 3.5 mol % and less than or equal to 9 mol %, greater than or equal to 3.5 mol % and less than or equal to 8 mol %, greater than or equal to 3.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 7 mol %, greater than or equal to 3.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 6 mol %, greater than or equal to 4 mol % and less than or equal to 15 mol %, greater than or equal to 4 mol % and less than or equal to 12 mol %, greater than or equal to 4 mol % and less than or equal to 10 mol %, greater than or equal to 4 mol % and less than or equal to 9 mol %, greater than or equal to 4 mol % and less than or equal to 8 mol %, greater than or equal to 4 mol % and less than or equal to 7.5 mol %, greater than or equal to 4 mol % and less than or equal to 7 mol %, greater than or equal to 4 mol % and less than or equal to 6.5 mol %, greater than or equal to 4 mol % and less than or equal to 6 mol %, greater than or equal to 4.5 mol % and less than or equal to 10 mol %, greater than or equal to 4.5 mol % and less than or equal to 9 mol %, greater than or equal to 4.5 mol % and less than or equal to 8 mol %, greater than or equal to 4.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 4.5 mol % and less than or equal to 7 mol %, greater than or equal to 4.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 5 mol % and less than or equal to 10 mol %, greater than or equal to 5 mol % and less than or equal to 9 mol %, greater than or equal to 5 mol % and less than or equal to 8 mol %, greater than or equal to 5 mol % and less than or equal to 7.5 mol %, greater than or equal to 5 mol % and less than or equal to 7 mol %, greater than or equal to 5 mol % and less than or equal to 6.5 mol %, greater than or equal to 5.5 mol % and less than or equal to 10 mol %, greater than or equal to 5.5 mol % and less than or equal to 9 mol %, greater than or equal to 5.5 mol % and less than or equal to 8 mol %, greater than or equal to 5.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 5.5 mol % and less than or equal to 7 mol %, or even greater than or equal to 5.5 mol % and less than or equal to 6.5 mol %, or any and all sub-ranges formed from any of these endpoints.

As described hereinabove, the glass compositions and the resultant colored glass articles may contain alkali oxides, such as Li₂O, Na₂O, and K₂O, to enable the ion-exchangeability of the colored glass articles.

Li₂O aids in the ion-exchangeability of the colored glass article and also reduces the softening point of the glass composition, thereby increasing the formability of the colored glass articles. The addition of Li₂O facilitates the exchange of both Na⁺ and K⁺ cations into the glass for strengthening the glass and also facilitates producing a relatively high surface compressive stress and relatively deep depth of compression, improving the mechanical characteristics of the resultant colored glass article. In addition, Li₂O decreases the melting point of the glass composition, which may improve retention of colorants in the glass, such as, for example and without limitation, Au. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Au. The concentration of Li₂O in the glass compositions and resultant colored glass articles should be sufficiently high (e.g., greater than or equal to 1 mol %) to reduce the melting point of the glass composition and achieve the desired maximum central tension (e.g., greater than or equal to 40 MPa) following ion exchange. However, if the amount of Li₂O is too high (e.g., greater than 20 mol %), the liquidus temperature may increase, thereby diminishing the manufacturability of the colored glass article.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 1 mol % and less than or equal to 20 mol % Li₂O or even greater than or equal to 1 mol % and less than or equal to 20 mol % Li₂O. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 3 mol % and less than or equal to 18 mol % Li₂O, greater than or equal to 7 mol % and less than or equal to 18 mol % Li₂O, greater than or equal to 8.8 mol % and less than or equal to 14 mol % Li₂O, or even greater than or equal to 9 mol % and less than or equal to 13.5 mol % Li₂O. In embodiments, the concentration of Li₂O in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol %, greater than or equal to 3 mol %, greater than or equal to 5 mol %, greater than or equal to 7 mol %, greater than or equal to 7.5 mol %, greater than or equal to 8 mol %, greater than or equal to 8.5 mol %, greater than or equal to 8.8 mol %, greater than or equal to 9 mol %, greater than or equal to 9.2 mol %, greater than or equal to 9.4 mol %, greater than or equal to 9.6 mol %, greater than or equal to 9.8 mol %, greater than or equal to 10 mol %, greater than or equal to 11 mol %, greater than or equal to 11.5 mol %, or even greater than or equal to 12 mol %. In embodiments, the concentration of Li₂O in the glass composition and the resultant colored glass article may be less than or equal to 20 mol %, less than or equal to 18 mol %, less than or equal to 17 mol %, less than or equal to 16 mol %, less than or equal to 15 mol %, less than or equal to 14 mol %, less than or equal to 13.5 mol %, less than or equal to 13 mol %, less than or equal to 12.5 mol %, less than or equal to 12 mol %, less than or equal to 11.5 mol %, or even less than or equal to 11 mol %. In embodiments, the concentration of Li₂O in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol % and less than or equal to 20 mol %, greater than or equal to 1 mol % and less than or equal to 18 mol %, greater than or equal to 1 mol % and less than or equal to 16 mol %, greater than or equal to 1 mol % and less than or equal to 14 mol %, greater than or equal to 1 mol % and less than or equal to 12.5 mol %, greater than or equal to 1 mol % and less than or equal to 12 mol %, greater than or equal to 1 mol % and less than or equal 11.5 mol %, greater than or equal to 1 mol % and less than or equal to 11 mol %, greater than or equal to 3 mol % and less than or equal to 20 mol %, greater than or equal to 3 mol % and less than or equal to 18 mol %, greater than or equal to 3 mol % and less than or equal to 16 mol %, greater than or equal to 3 mol % and less than or equal to 14 mol %, greater than or equal to 3 mol % and less than or equal to 12.5 mol %, greater than or equal to 3 mol % and less than or equal to 12 mol %, greater than or equal to 3 mol % and less than or equal 11.5 mol %, greater than or equal to 3 mol % and less than or equal to 11 mol %, greater than or equal to 5 mol % and less than or equal to 20 mol %, greater than or equal to 5 mol % and less than or equal to 18 mol %, greater than or equal to 5 mol % and less than or equal to 16 mol %, greater than or equal to 5 mol % and less than or equal to 14 mol %, greater than or equal to 5 mol % and less than or equal to 12.5 mol %, greater than or equal to 5 mol % and less than or equal to 12 mol %, greater than or equal to 5 mol % and less than or equal 11.5 mol %, greater than or equal to 5 mol % and less than or equal to 11 mol %, greater than or equal to 7 mol % and less than or equal to 20 mol %, greater than or equal to 7 mol % and less than or equal to 18 mol %, greater than or equal to 7 mol % and less than or equal to 16 mol %, greater than or equal to 7 mol % and less than or equal to 15 mol %, greater than or equal to 7 mol % and less than or equal to 14 mol %, greater than or equal to 7 mol % and less than or equal to 13 mol %, greater than or equal to 7 mol % and less than or equal to 12.5 mol %, greater than or equal to 7 mol % and less than or equal to 12 mol %, greater than or equal to 7 mol % and less than or equal 11.5 mol %, greater than or equal to 7 mol % and less than or equal to 11 mol %, greater than or equal to 7.5 mol % and less than or equal to 20 mol %, greater than or equal to 7.5 mol % and less than or equal to 18 mol %, greater than or equal to 7.5 mol % and less than or equal to 16 mol %, greater than or equal to 7.5 mol % and less than or equal to 14 mol %, greater than or equal to 7.5 mol % and less than or equal to 12.5 mol %, greater than or equal to 7.5 mol % and less than or equal to 12 mol %, greater than or equal to 7.5 mol % and less than or equal 11.5 mol %, greater than or equal to 7.5 mol % and less than or equal to 11 mol %, greater than or equal to 8 mol % and less than or equal to 20 mol %, greater than or equal to 8 mol % and less than or equal to 18 mol %, greater than or equal to 8 mol % and less than or equal to 16 mol %, greater than or equal to 8 mol % and less than or equal to 15 mol %, greater than or equal to 8 mol % and less than or equal to 14 mol %, greater than or equal to 8 mol % and less than or equal to 13 mol %, greater than or equal to 8 mol % and less than or equal to 12.5 mol %, greater than or equal to 8 mol % and less than or equal to 12 mol %, greater than or equal to 8 mol % and less than or equal 11.5 mol %, greater than or equal to 8 mol % and less than or equal to 11 mol %, greater than or equal to 8.5 mol % and less than or equal to 20 mol %, greater than or equal to 8.5 mol % and less than or equal to 18 mol %, greater than or equal to 8.5 mol % and less than or equal to 16 mol %, greater than or equal to 8.5 mol % and less than or equal to 14 mol %, greater than or equal to 8.5 mol % and less than or equal to 12.5 mol %, greater than or equal to 8.5 mol % and less than or equal to 12 mol %, greater than or equal to 8.5 mol % and less than or equal 11.5 mol %, greater than or equal to 8.5 mol % and less than or equal to 11 mol %, greater than or equal to 9 mol % and less than or equal to 20 mol %, greater than or equal to 9 mol % and less than or equal to 18 mol %, greater than or equal to 9 mol % and less than or equal to 16 mol %, greater than or equal to 9 mol % and less than or equal to 15 mol %, greater than or equal to 9 mol % and less than or equal to 14 mol %, greater than or equal to 9 mol % and less than or equal to 13 mol %, greater than or equal to 9 mol % and less than or equal to 12.5 mol %, greater than or equal to 9 mol % and less than or equal to 12 mol %, greater than or equal to 9 mol % and less than or equal 11.5 mol %, or even greater than or equal to 9 mol % and less than or equal to 11 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of Li₂O in the glass composition and the resultant colored glass article may be greater than or equal to 8.8 mol % and less than or equal to 14 mol %, greater than or equal to 8.8 mol % and less than or equal to 13.5 mol %, greater than or equal to 8.8 mol % and less than or equal to 13 mol %, greater than or equal to 8.8 mol % and less than or equal to 12.5 mol %, greater than or equal to 8.8 mol % and less than or equal to 12 mol %, greater than or equal to 8.8 mol % and less than or equal to 11.5 mol %, greater than or equal to 9 mol % and less than or equal to 14 mol %, greater than or equal to 9 mol % and less than or equal to 13.5 mol %, greater than or equal to 9 mol % and less than or equal to 13 mol %, greater than or equal to 9 mol % and less than or equal to 12.5 mol %, greater than or equal to 9 mol % and less than or equal to 12 mol %, greater than or equal to 9 mol % and less than or equal to 11.5 mol %, greater than or equal to 9.2 mol % and less than or equal to 14 mol %, greater than or equal to 9.2 mol % and less than or equal to 13.5 mol %, greater than or equal to 9.2 mol % and less than or equal to 13 mol %, greater than or equal to 9.2 mol % and less than or equal to 12.5 mol %, greater than or equal to 9.2 mol % and less than or equal to 12 mol %, greater than or equal to 9.2 mol % and less than or equal to 11.5 mol %, greater than or equal to 9.4 mol % and less than or equal to 14 mol %, greater than or equal to 9.4 mol % and less than or equal to 13.5 mol %, greater than or equal to 9.4 mol % and less than or equal to 13 mol %, greater than or equal to 9.4 mol % and less than or equal to 12.5 mol %, greater than or equal to 9.4 mol % and less than or equal to 12 mol %, greater than or equal to 9.4 mol % and less than or equal to 11.5 mol %, greater than or equal to 9.6 mol % and less than or equal to 14 mol %, greater than or equal to 9.6 mol % and less than or equal to 13.5 mol %, greater than or equal to 9.6 mol % and less than or equal to 13 mol %, greater than or equal to 9.6 mol % and less than or equal to 12.5 mol %, greater than or equal to 9.6 mol % and less than or equal to 12 mol %, greater than or equal to 9.6 mol % and less than or equal to 11.5 mol %, greater than or equal to 9.8 mol % and less than or equal to 14 mol %, greater than or equal to 9.8 mol % and less than or equal to 13.5 mol %, greater than or equal to 9.8 mol % and less than or equal to 13 mol %, greater than or equal to 9.8 mol % and less than or equal to 12.5 mol %, greater than or equal to 9.8 mol % and less than or equal to 12 mol %, greater than or equal to 9.8 mol % and less than or equal to 11.5 mol %, greater than or equal to 10 mol % and less than or equal to 14 mol %, greater than or equal to 10 mol % and less than or equal to 13.5 mol %, greater than or equal to 10 mol % and less than or equal to 13 mol %, greater than or equal to 10 mol % and less than or equal to 12.5 mol %, greater than or equal to 10 mol % and less than or equal to 12 mol %, or even greater than or equal to 10 mol % and less than or equal to 11.5 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the concentration of Li₂O in the glass composition and the resultant colored glass article may be greater than or equal to 10 mol % and less than or equal to 17 mol %, greater than or equal to 10 mol % and less than or equal to 16 mol %, greater than or equal to 10 mol % and less than or equal to 15 mol %, greater than or equal to 10 mol % and less than or equal to 14 mol %, greater than or equal to 10 mol % and less than or equal to 13 mol %, greater than or equal to 10 mol % and less than or equal to 12 mol %, greater than or equal to 11 mol % and less than or equal to 17 mol %, greater than or equal to 11 mol % and less than or equal to 16 mol %, greater than or equal to 11 mol % and less than or equal to 15 mol %, greater than or equal to 11 mol % and less than or equal to 14 mol %, greater than or equal to 11 mol % and less than or equal to 13 mol %, greater than or equal to 11 mol % and less than or equal to 12 mol %, greater than or equal to 11.1 mol % and less than or equal to 17 mol %, greater than or equal to 11.1 mol % and less than or equal to 16 mol %, greater than or equal to 11.1 mol % and less than or equal to 15 mol %, greater than or equal to 11.1 mol % and less than or equal to 14 mol %, greater than or equal to 11.1 mol % and less than or equal to 13 mol %, greater than or equal to 11.1 mol % and less than or equal to 12 mol %, greater than or equal to 11.5 mol % and less than or equal to 17 mol %, greater than or equal to 11.5 mol % and less than or equal to 16 mol %, greater than or equal to 11.5 mol % and less than or equal to 15 mol %, greater than or equal to 11.5 mol % and less than or equal to 14 mol %, greater than or equal to 11.5 mol % and less than or equal to 13 mol %, greater than or equal to 11.5 mol % and less than or equal to 12 mol %, greater than or equal to 12 mol % and less than or equal to 17 mol %, greater than or equal to 12 mol % and less than or equal to 16 mol %, greater than or equal to 12 mol % and less than or equal to 15 mol %, greater than or equal to 12 mol % and less than or equal to 14 mol %, greater than or equal to 12 mol % and less than or equal to 13 mol %, greater than or equal to 13 mol % and less than or equal to 17 mol %, greater than or equal to 13 mol % and less than or equal to 16 mol %, greater than or equal to 13 mol % and less than or equal to 15 mol %, greater than or equal to 13 mol % and less than or equal to 14 mol %, or any and all sub-ranges formed from any of these endpoints.

Na₂O improves diffusivity of alkali ions in the glass and thereby reduces ion-exchange time and helps achieve the desired surface compressive stress (e.g., greater than or equal to 300 MPa). The addition of Na₂O also facilitates the exchange of K⁺ cations into the glass for strengthening and improving the mechanical characteristics of the resultant colored glass article. Na₂O also improves the formability of the colored glass article. In addition, Na₂O decreases the melting point of the glass composition, which may improve retention of certain colorants in the glass, such as, for example, Au. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Au. However, if too much Na₂O is added to the glass composition, the melting point may be too low. In embodiments, the concentration of Li₂O present in the glass composition and the resultant colored glass article may be greater than the concentration of Na₂O present in the glass composition and the resultant colored glass article.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than 0 mol. % or greater than or equal to 0.01 mol % and less than or equal to 15 mol % Na₂O, greater than or equal to 0.5 mol % and less than or equal to 15 mol % Na₂O or even greater than or equal to 1 mol % and less than or equal to 15 mol % Na₂O. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 1 mol % and less than or equal to 12 mol % Na₂O or even greater than or equal to 2 mol % and less than or equal to 10 mol % Na₂O. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.01 mol % and less than or equal to 4 mol % Na₂O. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 1.5 mol % and less than or equal to 8 mol % Na₂O or even greater than or equal to 2 mol % and less than or equal to 7.5 mol % Na₂O. In embodiments, the concentration of Na₂O in the glass composition and the resultant colored glass article may be greater than 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.5 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, greater than or equal to 2 mol %, greater than or equal to 2.5 mol %, greater than or equal to 3 mol %, greater than or equal to 3.5 mol %, greater than or equal to 4 mol %, or even greater than or equal to 4.5 mol %. In embodiments, the concentration of Na₂O in the glass composition and the resultant colored glass article may be less than or equal to 15 mol %, less than or equal to 12 mol %, less than or equal to 10 mol %, less than or equal to 9 mol %, less than or equal to 8.5 mol %, less than or equal to 8 mol %, less than or equal to 7.5 mol %, less than or equal to less than or equal to 7 mol %, less than or equal to 6.5 mol %, less than or equal to 6 mol %, less than or equal to less than or equal to 5.5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, or even less than or equal to 4 mol %. In embodiments, the concentration of Na₂O in the glass composition and the resultant colored glass article may be greater than 0 mol % and less than or equal to 15 mol %, greater than 0 mol % and less than or equal to 12 mol %, greater than 0 mol % and less than or equal to 10 mol %, greater than 0 mol % and less than or equal to 8 mol %, greater than 0 mol % and less than or equal to 6 mol %, greater than 0 mol % and less than or equal to 5.5 mol %, greater than 0 mol % and less than or equal to 5 mol %, greater than 0 mol % and less than or equal to 4.5 mol %, greater than 0 mol % and less than or equal to 4 mol %, greater than or equal to 0.01 mol % and less than or equal to 15 mol %, greater than or equal to 0.01 mol % and less than or equal to 12 mol %, greater than or equal to 0.01 mol % and less than or equal to 10 mol %, greater than or equal to 0.01 mol % and less than or equal to 8 mol %, greater than or equal to 0.01 mol % and less than or equal to 6 mol %, greater than or equal to 0.01 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 5 mol %, greater than or equal to 0.01 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 15 mol %, greater than or equal to 0.5 mol % and less than or equal to 12 mol %, greater than or equal to 0.5 mol % and less than or equal to 10 mol %, greater than or equal to 0.5 mol % and less than or equal to 8 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 1 mol % and less than or equal to 15 mol %, greater than or equal to 1 mol % and less than or equal to 12 mol %, greater than or equal to 1 and less than or equal to 10 mol %, greater than or equal to 1 and less than or equal to 9 mol %, greater than or equal to 1 mol % and less than or equal to 8 mol %, greater than or equal to 1 mol % and less than or equal to 7.5 mol %, greater than or equal to 1 mol % and less than or equal to 7 mol %, greater than or equal to 1 mol % and less than or equal to 6.5 mol %, greater than or equal to 1 mol % and less than or equal to 6 mol %, greater than or equal to 1 mol % and less than or equal to 5.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 15 mol %, greater than or equal to 1.5 mol % and less than or equal to 12 mol %, greater than or equal to 1.5 and less than or equal to 10 mol %, greater than or equal to 1.5 and less than or equal to 9 mol %, greater than or equal to 1.5 mol % and less than or equal to 8 mol %, greater than or equal to 1.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 7 mol %, greater than or equal to 1.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 6 mol %, greater than or equal to 1.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 2 mol % and less than or equal to 15 mol %, greater than or equal to 2 mol % and less than or equal to 12 mol %, greater than or equal to 2 and less than or equal to 10 mol %, greater than or equal to 2 and less than or equal to 9 mol %, greater than or equal to 2 mol % and less than or equal to 8 mol %, greater than or equal to 2 mol % and less than or equal to 7.5 mol %, greater than or equal to 2 mol % and less than or equal to 7 mol %, greater than or equal to 2 mol % and less than or equal to 6.5 mol %, greater than or equal to 2 mol % and less than or equal to 6 mol %, greater than or equal to 2 mol % and less than or equal to 5.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 15 mol %, greater than or equal to 2.5 mol % and less than or equal to 12 mol %, greater than or equal to 2.5 and less than or equal to 10 mol %, greater than or equal to 2.5 and less than or equal to 9 mol %, greater than or equal to 2.5 mol % and less than or equal to 8 mol %, greater than or equal to 2.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 7 mol %, greater than or equal to 2.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 6 mol %, greater than or equal to 2.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 3 mol % and less than or equal to 15 mol %, greater than or equal to 3 mol % and less than or equal to 12 mol %, greater than or equal to 3 and less than or equal to 10 mol %, greater than or equal to 3 and less than or equal to 9 mol %, greater than or equal to 3 and less than or equal to 8.5 mol %, greater than or equal to 3 mol % and less than or equal to 8 mol %, greater than or equal to 3 mol % and less than or equal to 7.5 mol %, greater than or equal to 3 mol % and less than or equal to 7 mol %, greater than or equal to 3 mol % and less than or equal to 6.5 mol %, greater than or equal to 3 mol % and less than or equal to 6 mol %, greater than or equal to 3 mol % and less than or equal to 5.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 15 mol %, greater than or equal to 3.5 mol % and less than or equal to 12 mol %, greater than or equal to 3.5 and less than or equal to 10 mol %, greater than or equal to 3.5 and less than or equal to 9 mol %, greater than or equal to 3.5 mol % and less than or equal to 8 mol %, greater than or equal to 3.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 7 mol %, greater than or equal to 3.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 6 mol %, greater than or equal to 3.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 4 mol % and less than or equal to 15 mol %, greater than or equal to 4 mol % and less than or equal to 12 mol %, greater than or equal to 4 and less than or equal to 10 mol %, greater than or equal to 4 and less than or equal to 9 mol %, greater than or equal to 4 mol % and less than or equal to 8 mol %, greater than or equal to 4 mol % and less than or equal to 7.5 mol %, greater than or equal to 4 mol % and less than or equal to 7 mol %, greater than or equal to 4 mol % and less than or equal to 6.5 mol %, greater than or equal to 4 mol % and less than or equal to 6 mol %, greater than or equal to 4 mol % and less than or equal to 5.5 mol %, greater than or equal to 4.5 mol % and less than or equal to 15 mol %, greater than or equal to 4.5 mol % and less than or equal to 12 mol %, greater than or equal to 4.5 and less than or equal to 10 mol %, greater than or equal to 4.5 mol % and less than or equal to 8 mol %, greater than or equal to 4.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 4.5 mol % and less than or equal to 7 mol %, greater than or equal to 4.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 4.5 mol % and less than or equal to 6 mol %, or even greater than or equal to 4.5 mol % and less than or equal to 5.5 mol %, or any and all sub-ranges formed from any of these endpoints.

K₂O, when included, promotes ion-exchange and may increase the depth of compression and decrease the melting point to improve the formability of the colored glass article. However, adding too much K₂O may cause the surface compressive stress and melting point to be too low. Accordingly, in embodiments, the amount of K₂O added to the glass composition may be limited.

In embodiments, the glass composition and the resultant colored glass article may optionally comprise greater than or equal to 0 mol % and less than or equal to 3 mol % K₂O, greater than or equal to 0 mol % and less than or equal to 1 mol % K₂O, greater than or equal to 0.01 mol % and less than or equal to 1 mol % K₂O or even greater than or equal to 0.1 mol % and less than or equal to 1 mol % K₂O. In embodiments, the glass composition and the resultant colored glass article may optionally comprise greater than 0.1 mol % and less than or equal to 0.5 mol % K₂O. In embodiments, the concentration of K₂O in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.1 mol %, greater than or equal to 0.2 mol %, greater than or equal to 0.25 mol %, greater than or equal to 0.4 mol %, or even greater than or equal to 0.5 mol %. In embodiments, the concentration of K₂O in the glass composition and the resultant colored glass article may be less than or equal to 3 mol %, less than or equal to 2.5 mol %, less than or equal to 2 mol %, less than or equal to 1.5 mol %, less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, or even less than or equal to 0.25 mol %. In embodiments, the concentration of K₂O in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2.5 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.7 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 3 mol %, greater than or equal to 0.01 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.7 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.7 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 3 mol %, greater than or equal to 0.2 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 2 mol %, greater than or equal to 0.2 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 1 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.7 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 3 mol %, greater than or equal to 0.25 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 2 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 1 mol %, greater than or equal to 0.25 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.25 mol % and less than or equal to 0.7 mol %, greater than or equal to 0.25 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 3 mol %, greater than or equal to 0.3 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 2 mol %, greater than or equal to 0.3 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 1 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.7 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.4 mol % and less than or equal to 3 mol %, greater than or equal to 0.4 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.4 mol % and less than or equal to 2 mol %, greater than or equal to 0.4 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.4 mol % and less than or equal to 1 mol %, greater than or equal to 0.4 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.4 mol % and less than or equal to 0.7 mol %, or even greater than or equal to 0.4 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of K₂O.

R₂O, as used herein, is the sum (in mol %) of Li₂O, Na₂O, and K₂O present in the glass composition and the resultant colored glass article (i.e., R₂O=Li₂O (mol %)+Na₂O (mol %)+K₂O (mol %). Like B₂O₃, the alkali oxides aid in decreasing the softening point and molding temperature of the glass composition, thereby offsetting the increase in the softening point and molding temperature of the glass composition due to higher amounts of SiO₂ in the glass composition, for example. The softening point and molding temperature may be further reduced by including combinations of alkali oxides (e.g., two or more alkali oxides) in the glass composition, a phenomenon referred to as the “mixed alkali effect.” However, it has been found that if the amount of alkali oxide is too high, the average coefficient of thermal expansion of the glass composition increases to greater than 100×10⁻⁷/° C., which may be undesirable.

In embodiments, the concentration of R₂O in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol % and less than or equal to 35 mol %. In embodiments, the concentration of R₂O in the glass composition and the resultant colored glass article may be greater than or equal to 6 mol % and less than or equal to 25 mol % or even greater than or equal to 8 mol % and less than or equal to 23 mol %. In embodiments, the concentration of R₂O in the glass composition and the resultant colored glass article may be greater than or equal to 2 mol %, greater than or equal to 4 mol %, greater than 6 mol %, greater than or equal to 8 mol %, greater than or equal to 10 mol %, greater than or equal to 10.3 mol %, greater than or equal to 11 mol %, greater than or equal to 12 mol %, greater than or equal to 13 mol %, greater than or equal to 12 mol %, or even greater than or equal to 14 mol %. In embodiments, the concentration of R₂O in the glass composition and the resultant colored glass article may be less than or equal to 35 mol %, less than or equal to 30 mol %, less than or equal to 25 mol %, less than or equal to 23 mol %, less than or equal to 22 mol %, less than or equal to 21 mol %, less than or equal to 20 mol %, less than or equal to 19 mol %, less than or equal to 18 mol %, less than or equal to 17 mol %, or even less than or equal to 16 mol %. In embodiments, the concentration of R₂O in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol % and less than or equal to 35 mol %, greater than or equal to 1 mol % and less than or equal to 30 mol %, greater than or equal to 1 mol % and less than or equal to 25 mol %, greater than or equal to 1 mol % and less than or equal to 23 mol %, greater than or equal to 1 mol % and less than or equal to 22 mol %, greater than or equal to 1 mol % and less than or equal to 21 mol %, greater than or equal to 1 mol % and less than or equal to 20 mol %, greater than or equal to 1 mol % and less than or equal to 19 mol %, greater than or equal to 1 mol % and less than or equal to 18 mol %, greater than or equal to 1 mol % and less than or equal to 17 mol %, greater than or equal to 1 mol % and less than or equal to 16 mol %, greater than or equal to 2 mol % and less than or equal to 35 mol %, greater than or equal to 2 mol % and less than or equal to 30 mol %, greater than or equal to 2 mol % and less than or equal to 25 mol %, greater than or equal to 2 mol % and less than or equal to 23 mol %, greater than or equal to 2 mol % and less than or equal to 22 mol %, greater than or equal to 2 mol % and less than or equal to 21 mol %, greater than or equal to 2 mol % and less than or equal to 20 mol %, greater than or equal to 2 mol % and less than or equal to 19 mol %, greater than or equal to 2 mol % and less than or equal to 18 mol %, greater than or equal to 2 mol % and less than or equal to 17 mol %, greater than or equal to 2 mol % and less than or equal to 16 mol %, greater than or equal to 4 mol % and less than or equal to 35 mol %, greater than or equal to 4 mol % and less than or equal to 30 mol %, greater than or equal to 4 mol % and less than or equal to 25 mol %, greater than or equal to 4 mol % and less than or equal to 23 mol %, greater than or equal to 4 mol % and less than or equal to 22 mol %, greater than or equal to 4 mol % and less than or equal to 21 mol %, greater than or equal to 4 mol % and less than or equal to 20 mol %, greater than or equal to 4 mol % and less than or equal to 19 mol %, greater than or equal to 4 mol % and less than or equal to 18 mol %, greater than or equal to 4 mol % and less than or equal to 17 mol %, greater than or equal to 4 mol % and less than or equal to 16 mol %, greater than or equal to 6 mol % and less than or equal to 35 mol %, greater than or equal to 6 mol % and less than or equal to 30 mol %, greater than or equal to 6 mol % and less than or equal to 25 mol %, greater than or equal to 6 mol % and less than or equal to 23 mol %, greater than or equal to 6 mol % and less than or equal to 22 mol %, greater than or equal to 6 mol % and less than or equal to 21 mol %, greater than or equal to 6 mol % and less than or equal to 20 mol %, greater than or equal to 6 mol % and less than or equal to 19 mol %, greater than or equal to 6 mol % and less than or equal to 18 mol %, greater than or equal to 6 mol % and less than or equal to 17 mol %, greater than or equal to 6 mol % and less than or equal to 16 mol %, greater than or equal to 8 mol % and less than or equal to 35 mol %, greater than or equal to 8 mol % and less than or equal to 30 mol %, greater than or equal to 8 mol % and less than or equal to 25 mol %, greater than or equal to 8 mol % and less than or equal to 23 mol %, greater than or equal to 8 mol % and less than or equal to 22 mol %, greater than or equal to 8 mol % and less than or equal to 21 mol %, greater than or equal to 8 mol % and less than or equal to 20 mol %, greater than or equal to 8 mol % and less than or equal to 19 mol %, greater than or equal to 8 mol % and less than or equal to 18 mol %, greater than or equal to 8 mol % and less than or equal to 17 mol %, greater than or equal to 8 mol % and less than or equal to 16 mol %, greater than or equal to 10 mol % and less than or equal to 35 mol %, greater than or equal to 10 mol % and less than or equal to 30 mol %, greater than or equal to 10 mol % and less than or equal to 25 mol %, greater than or equal to 10 mol % and less than or equal to 23 mol %, greater than or equal to 10 mol % and less than or equal to 22 mol %, greater than or equal to 10 mol % and less than or equal to 21 mol %, greater than or equal to 10 mol % and less than or equal to 20 mol %, greater than or equal to 10 mol % and less than or equal to 19 mol %, greater than or equal to 10 mol % and less than or equal to 18 mol %, greater than or equal to 10 mol % and less than or equal to 17 mol %, greater than or equal to 10 mol % and less than or equal to 16 mol %, greater than or equal to 11 mol % and less than or equal to 35 mol %, greater than or equal to 11 mol % and less than or equal to 30 mol %, greater than or equal to 11 mol % and less than or equal to 25 mol %, greater than or equal to 11 mol % and less than or equal to 23 mol %, greater than or equal to 11 mol % and less than or equal to 22 mol %, greater than or equal to 11 mol % and less than or equal to 21 mol %, greater than or equal to 11 mol % and less than or equal to 20 mol %, greater than or equal to 11 mol % and less than or equal to 19 mol %, greater than or equal to 11 mol % and less than or equal to 18 mol %, greater than or equal to 11 mol % and less than or equal to 17 mol %, greater than or equal to 11 mol % and less than or equal to 16 mol %, greater than or equal to 12 mol % and less than or equal to 35 mol %, greater than or equal to 12 mol % and less than or equal to 30 mol %, greater than or equal to 12 mol % and less than or equal to 25 mol %, greater than or equal to 12 mol % and less than or equal to 23 mol %, greater than or equal to 12 mol % and less than or equal to 22 mol %, greater than or equal to 12 mol % and less than or equal to 21 mol %, greater than or equal to 12 mol % and less than or equal to 20 mol %, greater than or equal to 12 mol % and less than or equal to 19 mol %, greater than or equal to 12 mol % and less than or equal to 18 mol %, greater than or equal to 12 mol % and less than or equal to 17 mol %, greater than or equal to 12 mol % and less than or equal to 16 mol %, greater than or equal to 13 mol % and less than or equal to 35 mol %, greater than or equal to 13 mol % and less than or equal to 30 mol %, greater than or equal to 13 mol % and less than or equal to 25 mol %, greater than or equal to 13 mol % and less than or equal to 23 mol %, greater than or equal to 13 mol % and less than or equal to 22 mol %, greater than or equal to 13 mol % and less than or equal to 21 mol %, greater than or equal to 13 mol % and less than or equal to 20 mol %, greater than or equal to 13 mol % and less than or equal to 19 mol %, greater than or equal to 13 mol % and less than or equal to 18 mol %, greater than or equal to 13 mol % and less than or equal to 17 mol %, greater than or equal to 13 mol % and less than or equal to 16 mol %, greater than or equal to 14 mol % and less than or equal to 35 mol %, greater than or equal to 14 mol % and less than or equal to 30 mol %, greater than or equal to 14 mol % and less than or equal to 25 mol %, greater than or equal to 14 mol % and less than or equal to 23 mol %, greater than or equal to 14 mol % and less than or equal to 22 mol %, greater than or equal to 14 mol % and less than or equal to 21 mol %, greater than or equal to 14 mol % and less than or equal to 20 mol %, greater than or equal to 14 mol % and less than or equal to 19 mol %, greater than or equal to 14 mol % and less than or equal to 18 mol %, greater than or equal to 14 mol % and less than or equal to 17 mol %, or even greater than or equal to 14 mol % and less than or equal to 16 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the difference between R₂O and Al₂O₃ (i.e. R₂O (mol %)-Al₂O₃ (mol %)) in the glass composition may be adjusted to produce a desired observable color (e.g., pink, purple, red, orange, or blue). The analyzed R₂O—Al₂O₃ of the resultant colored glass article, along with the added colorant package, may correlate with the observable color of the colored glass article after heat treatment, as discussed herein. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −5 mol % and less than or equal to 7 mol % or even greater than or equal to −3 mol % and less than or equal to 2 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −3 mol % and less than or equal to 6 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −1 mol % and less than or equal to 5 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −5 mol % and less than or equal to 1.5 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −3 mol % and less than or equal to 1.5 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 1.5 mol % and less than or equal to 7 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 1.5 mol % and less than or equal to 5 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −5 mol %, greater than or equal to −4 mol %, greater than or equal to −3 mol %, greater than or equal to −2.5 mol %, greater than or equal to −2 mol %, greater than or equal to −1.5 mol %, greater than or equal to 0.2 mol %, greater than or equal to 0.5 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, or even greater than or equal to 2 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 7 mol %, less than or equal to 6.5 mol %, less than or equal to 6 mol %, less than or equal to 5.5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4 mol %, less than or equal to 3.5 mol %, less than or equal to 3 mol %, less than or equal to 2.5 mol %, less than or equal to 2 mol %, less than or equal to 1.5 mol %, less than or equal to 1 mol %, or even less than or equal to 0.5 mol %. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −5 mol % and less than or equal to 7 mol %, greater than or equal to −5 mol % and less than or equal to 5 mol %, greater than or equal to −5 mol % and less than or equal to 3 mol %, greater than or equal to −5 mol % and less than or equal to 1.5 mol %, greater than or equal to −3 mol % and less than or equal to 7 mol %, greater than or equal to −3 mol % and less than or equal to 5 mol %, greater than or equal to −3 mol % and less than or equal to 3 mol %, greater than or equal to −3 mol % and less than or equal to 1.5 mol %, greater than or equal to −1 mol % and less than or equal to 7 mol %, greater than or equal to −1 mol % and less than or equal to 5 mol %, greater than or equal to −1 mol % and less than or equal to 3 mol %, greater than or equal to −1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 7 mol %, greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 7 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, or even greater than or equal to 1.5 mol % and less than or equal to 3 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, R₂O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to −3 mol % and less than or equal to 2 mol %, greater than or equal to −3 mol % and less than or equal to 1.5 mol %, greater than or equal to −3 mol % and less than or equal to 1 mol %, greater than or equal to −3 mol % and less than or equal to 0.5 mol %, greater than or equal to −2.5 mol % and less than or equal to 2 mol %, greater than or equal to −2.5 mol % and less than or equal to 1.5 mol %, greater than or equal to −2.5 mol % and less than or equal to 1 mol %, greater than or equal to −2.5 mol % and less than or equal to 0.5 mol %, greater than or equal to −2 mol % and less than or equal to 2 mol %, greater than or equal to −2 mol % and less than or equal to 1.5 mol %, greater than or equal to −2 mol % and less than or equal to 1 mol %, greater than or equal to −2 mol % and less than or equal to 0.5 mol %, greater than or equal to −1.5 mol % and less than or equal to 2 mol %, greater than or equal to −1.5 mol % and less than or equal to 1.5 mol %, greater than or equal to −1.5 mol % and less than or equal to 1 mol %, or even greater than or equal to −1.5 mol % and less than or equal to 0.5 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the difference between the concentrations of R₂O and Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0.2 mol % and less than or equal to 5 mol %, greater than or equal to 0.2 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 4 mol %, greater than or equal to 0.2 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4.5 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 3.5 mol %, greater than or equal to 1 mol % and less than or equal to 3 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4 mol %, greater than or equal to 1.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 3 mol %, greater than or equal to 2 mol % and less than or equal to 5 mol %, greater than or equal to 2 mol % and less than or equal to 4.5 mol %, greater than or equal to 2 mol % and less than or equal to 4 mol %, greater than or equal to 2 mol % and less than or equal to 3.5 mol %, greater than or equal to 2 mol % and less than or equal to 3 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass compositions and the resultant colored glass articles described herein further include MgO and/or ZnO to improve retention of colorants in the glass, such as Au or the like, by lowering the melting point of the glass composition. Decreasing the melting point of the glass composition may help improve colorant retention because the glass compositions may be melted at relatively lower temperatures and the evaporation of colorants from the glass, such as gold, may be reduced. While not wishing to be bound by theory, it is also believed that partially replacing Li₂O and/or Na₂O with MgO and/or ZnO may also help improve retention of the colorants. Specifically, Li₂O and/or Na₂O is included in the batch glass composition as lithium carbonate and sodium carbonate, respectively. Upon melting the glass composition, carbonate gas is released from the glass composition. Colorants such as Au escape from the glass composition within the carbonate gas. Therefore, the improved colorant retention may be due to the reduced amount of carbonate. Further, it is believed that MgO and/or ZnO may improve the solubility of some colorants in the glass (such as Cr₂O₃, for example), thereby avoiding the formation of undesirable crystal phases (such as Cr-spinel crystals) and expanding the color gamut that may be achieved by the resultant colored glass articles. For example, in embodiments where the colorant includes Cr₂O₃, the sum of MgO and ZnO present in the glass composition and the resultant colored glass article (i.e., MgO (mol %)+ZnO (mol %)) may be greater than or equal to 0 mol % and less than or equal to 6 mol % or even less than or equal to 4.5 mol %. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Au and Cr₂O₃.

In embodiments, the sum (in mol %) of MgO and ZnO present in the glass composition and the resultant colored glass article (i.e., MgO (mol %)+ZnO (mol %)) may be greater than or equal to 0 mol % and less than or equal to 8 mol %, greater than or equal to 0.1 mol % and less than or equal to 8 mol %, greater than or equal to 0 mol % and less than or equal to 6 mol %, greater than or equal to 0.1 mol % and less than or equal to 6 mol %, or even greater than or equal to 0 mol % and less than or equal to 4.5 mol %. In embodiments, the sum of MgO and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 0.5 mol % and less than or equal to 5.5 mol %. In embodiments, the sum of MgO and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.1 mol %, greater than or equal to 0.5 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, greater than or equal to 2 mol %, greater than or equal to 2.5 mol %, greater than or equal to 3 mol %, or even greater than or equal to 3.5 mol %. In embodiments, the sum of MgO and ZnO in the glass composition and the resultant colored glass article may be less than or equal to 8 mol %, less than or equal to 7 mol %, less than or equal to 6 mol %, less than or equal to 5.5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4.25 mol %, or even less than or equal to 4 mol %. In embodiments, the sum of MgO and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 8 mol %, greater than or equal to 0 mol % and less than or equal to 7 mol %, greater than or equal to 0 mol % and less than or equal to 6 mol %, greater than or equal to 0 mol % and less than or equal to 5.5 mol %, greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4.5 mol %, greater than or equal to 0 mol % and less than or equal to 4.25 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 8 mol %, greater than or equal to 0.1 mol % and less than or equal to 7 mol %, greater than or equal to 0.1 mol % and less than or equal to 6 mol %, greater than or equal to 0.1 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 8 mol %, greater than or equal to 0.5 mol % and less than or equal to 7 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 0.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.25 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 8 mol %, greater than or equal to 1 mol % and less than or equal to 7 mol %, greater than or equal to 1 mol % and less than or equal to 6 mol %, greater than or equal to 1 mol % and less than or equal to 5.5 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4.5 mol %, greater than or equal to 1 mol % and less than or equal to 4.25 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1.5 mol % and less than or equal to 8 mol %, greater than or equal to 1.5 mol % and less than or equal to 7 mol %, greater than or equal to 1.5 mol % and less than or equal to 6 mol %, greater than or equal to 1.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.25 mol %, greater than or equal to 1.5 mol % and less than or equal to 4 mol %, greater than or equal to 2 mol % and less than or equal to 8 mol %, greater than or equal to 2 mol % and less than or equal to 7 mol %, greater than or equal to 2 mol % and less than or equal to 6 mol %, greater than or equal to 2 mol % and less than or equal to 5.5 mol %, greater than or equal to 2 mol % and less than or equal to 5 mol %, greater than or equal to 2 mol % and less than or equal to 4.5 mol %, greater than or equal to 2 mol % and less than or equal to 4.25 mol %, greater than or equal to 2 mol % and less than or equal to 4 mol %, greater than or equal to 2.5 mol % and less than or equal to 8 mol %, greater than or equal to 2.5 mol % and less than or equal to 7 mol %, greater than or equal to 2.5 mol % and less than or equal to 6 mol %, greater than or equal to 2.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 5 mol %, greater than or equal to 2.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 4.25 mol %, greater than or equal to 2.5 mol % and less than or equal to 4 mol %, greater than or equal to 3 mol % and less than or equal to 8 mol %, greater than or equal to 3 mol % and less than or equal to 7 mol %, greater than or equal to 3 mol % and less than or equal to 6 mol %, greater than or equal to 3 mol % and less than or equal to 5.5 mol %, greater than or equal to 3 mol % and less than or equal to 5 mol %, greater than or equal to 3 mol % and less than or equal to 4.5 mol %, greater than or equal to 3 mol % and less than or equal to 4.25 mol %, greater than or equal to 3 mol % and less than or equal to 4 mol %, greater than or equal to 3 mol % and less than or equal to 8 mol %, greater than or equal to 3 mol % and less than or equal to 7 mol %, greater than or equal to 3.5 mol % and less than or equal to 6 mol %, greater than or equal to 3.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 5 mol %, or even greater than or equal to 3.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 3.5 mol % and less than or equal to 4.25 mol %, greater than or equal to 3.5 mol % and less than or equal to 4 mol %, or any and all sub-ranges formed from any of these endpoints.

In addition to improving colorant retention, MgO lowers the viscosity of the glass compositions, which enhances the formability, the strain point, and the Young's modulus, and may improve ion-exchangeability. However, when too much MgO is added to the glass composition, the diffusivity of sodium and potassium ions in the glass composition decreases which, in turn, adversely impacts the ion-exchange performance (i.e., the ability to ion-exchange) of the resultant colored glass article.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 8 mol % MgO or even greater than or equal to 0 mol % and less than or equal to 4.5 mol % MgO. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.5 mol % and less than or equal to 7 mol % MgO. In embodiments, the concentration of MgO in the glass composition may be greater than or equal to 0 mol %, greater than or equal to 0.5 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, greater than or equal to 2 mol %, or even greater than or equal to 2.5 mol %. In embodiments, the concentration of MgO in the glass composition may be less than or equal to 8 mol %, less than or equal to 7 mol %, less than or equal to 6 mol %, less than or equal to 5.5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4 mol %, less than or equal to 3.5 mol %, less than or equal to 3 mol %, less than or equal to 2.5 mol %, less than or equal to 2 mol %, less than or equal to 1.5 mol %, or even less than or equal to 1 mol %. In embodiments, the concentration of MgO in the glass composition may be greater than or equal to 0 mol % and less than or equal to 8 mol %, greater than or equal to 0 mol % and less than or equal to 7 mol %, greater than or equal to 0 mol % and less than or equal to 6 mol %, greater than or equal to 0 mol % and less than or equal to 5.5 mol %, greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4.5 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3.5 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2.5 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 8 mol %, greater than or equal to 0.5 mol % and less than or equal to 7 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 0.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, greater than or equal to 1 mol % and less than or equal to 8 mol %, greater than or equal to 1 mol % and less than or equal to 7 mol %, greater than or equal to 1 mol % and less than or equal to 6 mol %, greater than or equal to 1 mol % and less than or equal to 5.5 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4.5 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 3.5 mol %, greater than or equal to 1 mol % and less than or equal to 3 mol %, greater than or equal to 1 mol % and less than or equal to 2.5 mol %, greater than or equal to 1 mol % and less than or equal to 2 mol %, greater than or equal to 1 mol % and less than or equal to 1.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 8 mol %, greater than or equal to 1.5 mol % and less than or equal to 7 mol %, greater than or equal to 1.5 mol % and less than or equal to 6 mol %, greater than or equal to 1.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4 mol %, greater than or equal to 1.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 3 mol %, greater than or equal to 1.5 mol % and less than or equal to 2.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 2 mol %, greater than or equal to 2 mol % and less than or equal to 8 mol %, greater than or equal to 2 mol % and less than or equal to 7 mol %, greater than or equal to 2 mol % and less than or equal to 6 mol %, greater than or equal to 2 mol % and less than or equal to 5.5 mol %, greater than or equal to 2 mol % and less than or equal to 5 mol %, greater than or equal to 2 mol % and less than or equal to 4.5 mol %, greater than or equal to 2 mol % and less than or equal to 4 mol %, greater than or equal to 2 mol % and less than or equal to 3.5 mol %, greater than or equal to 2 mol % and less than or equal to 3 mol %, greater than or equal to 2 mol % and less than or equal to 2.5 mol %, greater than or equal to 0 mol % and less than or equal to 8 mol %, greater than or equal to 2.5 mol % and less than or equal to 7 mol %, greater than or equal to 2.5 mol % and less than or equal to 6 mol %, greater than or equal to 2.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 5 mol %, greater than or equal to 2.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 4 mol %, greater than or equal to 2.5 mol % and less than or equal to 3.5 mol %, or even greater than or equal to 2.5 mol % and less than or equal to 3 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of MgO.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 6 mol % MgO. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.1 mol % and less than or equal to 5 mol % MgO. In embodiments, the concentration of MgO in the glass composition may be greater than or equal to 0 mol %, greater than or equal to 0.1 mol %, or even greater than or equal to 0.5 mol %. In embodiments, the concentration of MgO in the glass composition may be less than or equal to 6 mol %, less than or equal to 5 mol %, less than or equal to 4 mol %, less than or equal to 3 mol %, less than or equal to 2 mol %, or even less than or equal to 1 mol %. In embodiments, the concentration of MgO in the glass composition may be greater than or equal to 0 mol % and less than or equal to 6 mol %, greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 6 mol %, greater than or equal to 0.1 mol % and less than or equal to 5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, or even greater than or equal to 0.5 mol % and less than or equal to 1 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of MgO.

In addition to improving colorant retention, ZnO lowers the viscosity of the glass compositions, which enhances the formability, the strain point, and the Young's modulus, and may improve ion-exchangeability. However, when too much ZnO is added to the glass composition, the diffusivity of sodium and potassium ions in the glass composition decreases which, in turn, adversely impacts the ion-exchange performance (i.e., the ability to ion-exchange) of the resultant colored glass article.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 5 mol % ZnO or even greater than or equal to 0 mol % and less than or equal to 4.5 mol % ZnO. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.1 mol % and less than or equal to 4 mol % ZnO. In embodiments, the concentration of ZnO in the glass composition may be greater than or equal to 0 mol %, greater than or equal to 0.1 mol %, greater than or equal to 0.25 mol %, greater than or equal to 0.5 mol %, greater than or equal to 0.75 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, or even greater than or equal to 2 mol %. In embodiments, the concentration of ZnO in the glass composition may be less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4 mol %, less than or equal to 3.5 mol %, less than or equal to 3 mol %, less than or equal to 2.5 mol %, less than or equal to 2 mol %, less than or equal to 1.75 mol %, less than or equal to 1.5 mol %, less than or equal to 1.25 mol %, or even less than or equal to 1 mol %. In embodiments, the concentration of ZnO in the glass composition may be greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4.5 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3.5 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2.5 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.75 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1.25 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.25 mol % and less than or equal to 5 mol %, greater than or equal to 0.25 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 4 mol %, greater than or equal to 0.25 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 3 mol %, greater than or equal to 0.25 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 2 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.25 mol % and less than or equal to 1 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, greater than or equal to 0.75 mol % and less than or equal to 5 mol %, greater than or equal to 0.75 mol % and less than or equal to 4 mol %, greater than or equal to 0.75 mol % and less than or equal to 3 mol %, greater than or equal to 0.75 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 2 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.25 mol %, greater than or equal to 1 mol % and less than or equal to 1 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4.5 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 3.5 mol %, greater than or equal to 1 mol % and less than or equal to 3 mol %, greater than or equal to 1 mol % and less than or equal to 2.5 mol %, greater than or equal to 1 mol % and less than or equal to 2 mol %, greater than or equal to 1 mol % and less than or equal to 1.75 mol %, greater than or equal to 1 mol % and less than or equal to 1.5 mol %, greater than or equal to 1 mol % and less than or equal to 1.25 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4 mol %, greater than or equal to 1.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 3 mol %, greater than or equal to 1.5 mol % and less than or equal to 2.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 2 mol %, greater than or equal to 1.5 mol % and less than or equal to 1.75 mol %, greater than or equal to 2 mol % and less than or equal to 5 mol %, greater than or equal to 2 mol % and less than or equal to 4.5 mol %, greater than or equal to 2 mol % and less than or equal to 4 mol %, greater than or equal to 2 mol % and less than or equal to 3.5 mol %, greater than or equal to 2 mol % and less than or equal to 3 mol %, or even greater than or equal to 2 mol % and less than or equal to 2.5 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of ZnO.

Like ZnO and the alkaline earth oxide MgO, other alkaline earth oxides, such as CaO, SrO and BaO, decrease the melting point of the glass composition. Accordingly, CaO, SrO, and/or BaO may be included in the glass composition and the resultant colored glass articles to lower the melting point of the glass composition, which may help improve colorant retention.

In embodiments, the glass compositions and the resultant colored glass articles described herein may further comprise CaO. CaO lowers the viscosity of a glass composition, which enhances the formability, the strain point and the Young's modulus, and may improve the ion-exchangeability. However, when too much CaO is added to the glass composition, the diffusivity of sodium and potassium ions in the glass composition decreases which, in turn, adversely impacts the ion-exchange performance (i.e., the ability to ion-exchange) of the resultant glass.

In embodiments, the concentration of CaO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.25 mol %, greater than or equal to 0.5 mol %, or even greater than or equal to 0.75 mol %. In embodiments, the concentration of CaO in the glass composition and the resultant colored glass article may be less than or equal to 7 mol %, less than or equal to 6.5 mol %, less than or equal to 6 mol %, less than or equal to 5.5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4 mol %, less than or equal to 3.5 mol %, less than or equal to 3 mol %, less than or equal to 2.5 mol %, less than or equal to 2 mol %, less than or equal to 1.75 mol %, less than or equal to 1.5 mol %, less than or equal to 1.25 mol %, or even less than or equal to 1 mol %. In embodiments, the concentration of CaO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 7 mol %, greater than or equal to 0 mol % and less than or equal to 6.5 mol %, greater than or equal to 0 mol % and less than or equal to 6 mol %, greater than or equal to 0 mol % and less than or equal to 5.5 mol %, greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4.5 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3.5 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2.5 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.75 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1.25 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0.25 mol % and less than or equal to 7 mol %, greater than or equal to 0.25 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 6 mol %, greater than or equal to 0.25 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 5 mol %, greater than or equal to 0.25 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 4 mol %, greater than or equal to 0.25 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 3 mol %, greater than or equal to 0.25 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 2 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.25 mol % and less than or equal to 1 mol %, greater than or equal to 0.5 mol % and less than or equal to 7 mol %, greater than or equal to 0.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 0.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, greater than or equal to 0.75 mol % and less than or equal to 7 mol %, greater than or equal to 0.75 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 6 mol %, greater than or equal to 0.75 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 5 mol %, greater than or equal to 0.75 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 4 mol %, greater than or equal to 0.75 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 3 mol %, greater than or equal to 0.75 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 2 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.25 mol %, or even greater than or equal to 0.75 mol % and less than or equal to 1 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of CaO.

In embodiments, the concentration of SrO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.25 mol %, greater than or equal to 0.5 mol %, or even greater than or equal to 0.75 mol %. In embodiments, the concentration of SrO in the glass composition and the resultant colored glass article may be less than or equal to 2 mol %, less than or equal to 1.75 mol %, less than or equal to 1.5 mol %, less than or equal to 1.25 mol %, or even less than or equal to 1 mol %. In embodiments, the concentration of SrO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.75 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1.25 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0.25 mol % and less than or equal to 2 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.25 mol % and less than or equal to 1 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, greater than or equal to 0.75 mol % and less than or equal to 2 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.25 mol %, or even greater than or equal to 0.75 mol % and less than or equal to 1 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of SrO.

In embodiments, the concentration of BaO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.25 mol %, greater than or equal to 0.5 mol %, or even greater than or equal to 0.75 mol %. In embodiments, the concentration of BaO in the glass composition and the resultant colored glass article may be less than or equal to 2 mol %, less than or equal to 1.75 mol %, less than or equal to 1.5 mol %, less than or equal to 1.25 mol %, or even less than or equal to 1 mol %. In embodiments, the concentration of BaO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.75 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1.25 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0.25 mol % and less than or equal to 2 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.25 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.25 mol % and less than or equal to 1 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.25 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, greater than or equal to 0.75 mol % and less than or equal to 2 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.75 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.75 mol % and less than or equal to 1.25 mol %, or even greater than or equal to 0.75 mol % and less than or equal to 1 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of BaO.

R′O, as used herein, is the sum (in mol %) of MgO, ZnO, CaO, BaO, and SrO (i.e. R′O=MgO (mol %)+ZnO (mol %)+CaO (mol %)+BaO (mol %)+SrO (mol %)). In embodiments, the concentration of R′O in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.5 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, greater than or equal to 2 mol %, or even greater than or equal to 2.5 mol %. In embodiments, the concentration of R′O in the glass composition and the resultant colored glass article may be less than or equal to 8 mol %, less than or equal to 7.5 mol %, less than or equal to 7 mol %, less than or equal to 6.5 mol %, less than or equal to 6 mol %, less than or equal to 5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4 mol %, or even less than or equal to 3.5 mol %. In embodiments, the concentration of R′O in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 8 mol %, greater than or equal to 0 mol % and less than or equal to 7.5 mol %, greater than or equal to 0 mol % and less than or equal to 7 mol %, greater than or equal to 0 mol % and less than or equal to 6.5 mol %, greater than or equal to 0 mol % and less than or equal to 6 mol %, greater than or equal to 0 mol % and less than or equal to 5.5 mol %, greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4.5 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 8 mol %, greater than or equal to 0.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 7 mol %, greater than or equal to 0.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 0.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 8 mol %, greater than or equal to 1 mol % and less than or equal to 7.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 7 mol %, greater than or equal to 1 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 1 mol % and less than or equal to 5.5 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4.5 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 3.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 8 mol %, greater than or equal to 1.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 7 mol %, greater than or equal to 1.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 6 mol %, greater than or equal to 1.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4 mol %, greater than or equal to 1.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 2 mol % and less than or equal to 8 mol %, greater than or equal to 2 mol % and less than or equal to 7.5 mol %, greater than or equal to 2 mol % and less than or equal to 7 mol %, greater than or equal to 2 mol % and less than or equal to 6.5 mol %, greater than or equal to 2 mol % and less than or equal to 6 mol %, greater than or equal to 2 mol % and less than or equal to 5.5 mol %, greater than or equal to 2 mol % and less than or equal to 5 mol %, greater than or equal to 2 mol % and less than or equal to 4.5 mol %, greater than or equal to 2 mol % and less than or equal to 4 mol %, greater than or equal to 2 mol % and less than or equal to 3.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 8 mol %, greater than or equal to 2.5 mol % and less than or equal to 7.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 7 mol %, greater than or equal to 2.5 mol % and less than or equal to 6.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 6 mol %, greater than or equal to 2.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 5 mol %, greater than or equal to 2.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 2.5 mol % and less than or equal to 4 mol %, or even greater than or equal to 2.5 mol % and less than or equal to 3.5 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the sum of R₂O, CaO, MgO, and ZnO (R₂O (mol %)+CaO (mol %)+MgO (mol %)+ZnO (mol %) may be less than or equal to 35 mol %. While not wishing to be bound by theory, it is believed that minimizing the combination of R₂O, CaO, MgO, and ZnO in the glass composition may provide the resultant colored glass article with a desirable dielectric constant, such as when the colored glass article is used as a portion of a housing for an electronic device. In embodiments, R₂O (mol %)+CaO (mol %)+MgO (mol %)+ZnO (mol %) may be greater than or equal to 1 mol % and less than or equal to 35 mol %, greater than or equal to 1 mol % and less than or equal to 30 mol %, greater than or equal to 1 mol % and less than or equal to 25 mol %, greater than or equal to 1 mol % and less than or equal to 20 mol %, greater than or equal to 1 mol % and less than or equal to 15 mol %, greater than or equal to 1 mol % and less than or equal to 10 mol %, greater than or equal to 2 mol % and less than or equal to 35 mol %, greater than or equal to 2 mol % and less than or equal to 30 mol %, greater than or equal to 2 mol % and less than or equal to 25 mol %, greater than or equal to 2 mol % and less than or equal to 20 mol %, greater than or equal to 2 mol % and less than or equal to 15 mol %, greater than or equal to 2 mol % and less than or equal to 10 mol %, greater than or equal to 3 mol % and less than or equal to 35 mol %, greater than or equal to 3 mol % and less than or equal to 30 mol %, greater than or equal to 3 mol % and less than or equal to 25 mol %, greater than or equal to 3 mol % and less than or equal to 20 mol %, greater than or equal to 3 mol % and less than or equal to 15 mol %, greater than or equal to 3 mol % and less than or equal to 10 mol %, greater than or equal to 4 mol % and less than or equal to 35 mol %, greater than or equal to 4 mol % and less than or equal to 30 mol %, greater than or equal to 4 mol % and less than or equal to 25 mol %, greater than or equal to 4 mol % and less than or equal to 20 mol %, greater than or equal to 4 mol % and less than or equal to 15 mol %, greater than or equal to 4 mol % and less than or equal to 10 mol %, greater than or equal to 4 mol % and less than or equal to 35 mol %, greater than or equal to 5 mol % and less than or equal to 30 mol %, greater than or equal to 5 mol % and less than or equal to 25 mol %, greater than or equal to 5 mol % and less than or equal to 20 mol %, greater than or equal to 5 mol % and less than or equal to 15 mol %, greater than or equal to 5 mol % and less than or equal to 10 mol %, greater than or equal to 6 mol % and less than or equal to 35 mol %, greater than or equal to 6 mol % and less than or equal to 30 mol %, greater than or equal to 6 mol % and less than or equal to 25 mol %, greater than or equal to 6 mol % and less than or equal to 20 mol %, greater than or equal to 6 mol % and less than or equal to 15 mol %, greater than or equal to 6 mol % and less than or equal to 10 mol %, greater than or equal to 7 mol % and less than or equal to 35 mol %, greater than or equal to 7 mol % and less than or equal to 30 mol %, greater than or equal to 7 mol % and less than or equal to 25 mol %, greater than or equal to 7 mol % and less than or equal to 20 mol %, greater than or equal to 7 mol % and less than or equal to 15 mol %, greater than or equal to 7 mol % and less than or equal to 10 mol %, greater than or equal to 8 mol % and less than or equal to 35 mol %, greater than or equal to 8 mol % and less than or equal to 30 mol %, greater than or equal to 8 mol % and less than or equal to 25 mol %, greater than or equal to 8 mol % and less than or equal to 20 mol %, greater than or equal to 8 mol % and less than or equal to 15 mol %, or even greater than or equal to 8 mol % and less than or equal to 10 mol %.

In embodiments, the sum of Al₂O₃, MgO, and ZnO present in the glass composition and the resultant colored glass article (i.e., Al₂O₃ (mol %)+MgO (mol %)+ZnO (mol %)) may be greater than or equal to 12 mol % and less than or equal to 22 mol %. While not wishing to be bound by theory, it is believed that combinations of Al₂O₃, MgO, and ZnO within this range may aid in avoiding the formation of undesired crystal phases in the resultant colored glass articles. For example and without limitation, when the colorant package in the glass composition and the resultant colored glass article includes Cr₂O₃, combinations of Al₂O₃, MgO, and ZnO within this range may avoid the formation of Cr-spinel crystals by increasing the solubility of the Cr₂O₃ colorant and thereby expanding the color gamut that may be achieved in the resultant colored glass articles. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Cr₂O₃.

In embodiments, the sum of Al₂O₃, MgO, and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 13 mol % and less than or equal to 21.5 mol %. In embodiments, the sum of Al₂O₃, MgO, and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 12 mol %, greater than or equal to 13 mol %, greater than or equal to 14 mol %, greater than or equal to 15 mol %, or even greater than or equal to 16 mol %. In embodiments, the sum of Al₂O₃, MgO, and ZnO in the glass composition and the resultant colored glass article may be less than or equal to 22 mol %, less than or equal to 21.5 mol %, less than or equal to 21 mol %, less than or equal to 20.5 mol %, or even less than or equal to 20 mol %. In embodiments, the sum of Al₂O₃, MgO, and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 12 mol % and less than or equal to 22 mol %, greater than or equal to 12 mol % and less than or equal to 21.5 mol %, greater than or equal to 12 mol % and less than or equal to 21 mol %, greater than or equal to 12 mol % and less than or equal to 20.5 mol %, greater than or equal to 12 mol % and less than or equal to 20 mol %, greater than or equal to 13 mol % and less than or equal to 22 mol %, greater than or equal to 13 mol % and less than or equal to 21.5 mol %, greater than or equal to 13 mol % and less than or equal to 21 mol %, greater than or equal to 13 mol % and less than or equal to 20.5 mol %, greater than or equal to 13 mol % and less than or equal to 20 mol %, greater than or equal to 14 mol % and less than or equal to 22 mol %, greater than or equal to 14 mol % and less than or equal to 21.5 mol %, greater than or equal to 14 mol % and less than or equal to 21 mol %, greater than or equal to 14 mol % and less than or equal to 20.5 mol %, greater than or equal to 15 mol % and less than or equal to 20 mol %, greater than or equal to 15 mol % and less than or equal to 22 mol %, greater than or equal to 15 mol % and less than or equal to 21.5 mol %, greater than or equal to 15 mol % and less than or equal to 21 mol %, greater than or equal to 15 mol % and less than or equal to 20.5 mol %, greater than or equal to 15 mol % and less than or equal to 20 mol %, greater than or equal to 16 mol % and less than or equal to 22 mol %, greater than or equal to 16 mol % and less than or equal to 21.5 mol %, greater than or equal to 16 mol % and less than or equal to 21 mol %, greater than or equal to 16 mol % and less than or equal to 20.5 mol %, or even greater than or equal to 16 mol % and less than or equal to 20 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the sum of Al₂O₃, MgO, CaO, and ZnO present in the glass composition and the resultant colored glass article (i.e., Al₂O₃ (mol %)+MgO (mol %)+CaO (mol %)+ZnO (mol %)) may be greater than or equal to 12 mol % and less than or equal to 24 mol %. While not wishing to be bound by theory, it is believed that combinations of Al₂O₃, MgO, CaO and ZnO within this range may aid in avoiding the formation of undesired crystal phases in the resultant colored glass articles. In addition, a relatively high concentration of high field strength modifiers, such as Mg, Ca, and Zn cations, may also improve the mechanical properties, such as fracture toughness, elastic modulus and drop test performance, of the resultant colored glass article.

In embodiments, the sum of Al₂O₃, MgO, CaO and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 12 mol % and less than or equal to 24 mol %. In embodiments, the sum of Al₂O₃, MgO, CaO and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 12 mol %, greater than or equal to 13 mol %, greater than or equal to 14 mol %, greater than or equal to 15 mol %, or even greater than or equal to 16 mol %. In embodiments, the sum of Al₂O₃, MgO, CaO and ZnO in the glass composition and the resultant colored glass article may be less than or equal to 24 mol %, less than or equal to 23 mol %, less than or equal to 22 mol %, less than or equal to 21.5 mol %, less than or equal to 21 mol %, less than or equal to 20.5 mol %, or even less than or equal to 20 mol %. In embodiments, the sum of Al₂O₃, MgO, CaO and ZnO in the glass composition and the resultant colored glass article may be greater than or equal to 12 mol % and less than or equal to 24 mol %, greater than or equal to 12 mol % and less than or equal to 23 mol %, greater than or equal to 12 mol % and less than or equal to 22 mol %, greater than or equal to 12 mol % and less than or equal to 21.5 mol %, greater than or equal to 12 mol % and less than or equal to 21 mol %, greater than or equal to 12 mol % and less than or equal to 20.5 mol %, greater than or equal to 12 mol % and less than or equal to 20 mol %, greater than or equal to 13 mol % and less than or equal to 24 mol %, greater than or equal to 13 mol % and less than or equal to 23 mol %, greater than or equal to 13 mol % and less than or equal to 22 mol %, greater than or equal to 13 mol % and less than or equal to 21.5 mol %, greater than or equal to 13 mol % and less than or equal to 21 mol %, greater than or equal to 13 mol % and less than or equal to 20.5 mol %, greater than or equal to 13 mol % and less than or equal to 20 mol %, greater than or equal to 14 mol % and less than or equal to 24 mol %, greater than or equal to 14 mol % and less than or equal to 23 mol %, greater than or equal to 14 mol % and less than or equal to 22 mol %, greater than or equal to 14 mol % and less than or equal to 21.5 mol %, greater than or equal to 14 mol % and less than or equal to 21 mol %, greater than or equal to 14 mol % and less than or equal to 20.5 mol %, greater than or equal to 15 mol % and less than or equal to 24 mol %, greater than or equal to 15 mol % and less than or equal to 23 mol %, greater than or equal to 15 mol % and less than or equal to 22 mol %, greater than or equal to 15 mol % and less than or equal to 21.5 mol %, greater than or equal to 15 mol % and less than or equal to 21 mol %, greater than or equal to 15 mol % and less than or equal to 20.5 mol %, greater than or equal to 15 mol % and less than or equal to 20 mol %, greater than or equal to 16 mol % and less than or equal to 24 mol %, greater than or equal to 16 mol % and less than or equal to 23 mol %, greater than or equal to 16 mol % and less than or equal to 22 mol %, greater than or equal to 16 mol % and less than or equal to 21.5 mol %, greater than or equal to 16 mol % and less than or equal to 21 mol %, greater than or equal to 16 mol % and less than or equal to 20.5 mol %, or even greater than or equal to 16 mol % and less than or equal to 20 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may optionally include Cl, which may enable growth of particular crystal phases containing colorant. For example, when the colorant package included in the glass comprises Au, the inclusion of Cl may enable the growth of certain Au crystals. In embodiments, the concentration of Cl in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % or even greater than or equal to 0.1 mol %. In embodiments, the concentration of Cl in the glass composition and the resultant colored glass article may be less than or equal to 0.5 mol % or even less than or equal to 0.25 mol %. In embodiments, the concentration of Cl in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, or even greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of Cl. In embodiments where the colorant package comprises Ag, the glass composition and resultant colored glass article include less than 100 ppm of halides, including Cl.

In embodiments, the glass compositions and the resultant colored glass articles described herein may further comprise ZrO₂. While not wishing to be bound by theory, it is believed that ZrO₂ may act as a multivalent species that serves as redox couples to supply oxygen to certain colorants, for example Au, during relatively low-temperature heat treatment, which helps improve retention of the colorant. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Au. ZrO₂ may also act as an additional colorant, producing colored glass articles that may be, for example, red in color. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.01 mol % and less than or equal to 2 mol % ZrO₂. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.01 mol % and less than or equal to 2 mol % ZrO₂. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.1 mol % and less than or equal to 1.5 mol % ZrO₂. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.25 mol % and less than or equal to 1.5 mol % ZrO₂. In embodiments, the concentration of ZrO₂ in the glass composition may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.1 mol %, or even greater than or equal to 0.2 mol %. In embodiments, the concentration of ZrO₂ in the glass composition may be less than or equal to 2 mol %, less than or equal to 1.5 mol %, less than or equal to 1 mol %, less than or equal to 0.75 mol %, or even less than or equal to 0.5 mol %. In embodiments, the concentration of ZrO₂ in the glass composition may be greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 2 mol %, greater than or equal to 0.2 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 1 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.75 mol %, or even greater than or equal to 0.2 mol % and less than or equal to 0.5 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of ZrO₂.

In embodiments, the glass compositions and the resultant colored glass articles described herein may further comprise Fe₂O₃, which may help improve colorant retention. Fe₂O₃ is a multivalent species that serves as redox couples to supply oxygen to certain colorants, for example Au, during relatively low-temperature heat treatment, which helps improve retention of the colorant. Without wishing to be bound by theory, it is hypothesized that similar behavior may occur with colorants other than Au. Fe₂O₃ may also act as a colorant, producing colored glass articles that may, for example, be pink or red in color. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.01 mol % and less than or equal to 1 mol % Fe₂O₃ or even greater than or equal to 0.1 mol % and less than or equal to 1 mol % Fe₂O₃. In embodiments, the concentration of Fe₂O₃ in the glass composition may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, or even greater than or equal to 0.1 mol %. In embodiments, the concentration of Fe₂O₃ in the glass composition may be less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, or even less than or equal to 0.25 mol %. In embodiments, the concentration of Fe₂O₃ in the glass composition may be greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of Fe₂O₃.

In embodiments, the glass compositions and the resultant colored glass articles described herein may further comprise SnO₂, Sb₂O₃, and/or Bi₂O₃. Like MgO and ZnO, SnO₂, Sb₂O₃, and Bi₂O₃ may help lower the melting point of the glass composition. Accordingly, SnO₂, Sb₂O₃, and/or Bi₂O₃ may be included in the glass composition and the resultant colored glass articles to lower the melting point and improve colorant retention. In embodiments in which the colorant package includes Ag, SnO₂ also aids in the reduction of Ag in the glass leading to the formation of silver particles in the glass. While not wishing to be bound by theory, in embodiments where the colorant package includes Au, it is believed that additions of SnO₂ may also aid in the reduction of Au in the glass, leading to the formation of gold particles. In embodiments that include SnO₂ and/or Sb₂O₃, the SnO₂ and/or Sb₂O₃ may also function as a fining agent.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.01 mol % and less than or equal to 1 mol % SnO₂. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.05 mol % and less than or equal to 0.75 mol % SnO₂, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol % SnO₂, or even greater than or equal to 0.1 mol % and less than or equal to 0.25 mol % SnO₂. In embodiments, the concentration of SnO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.05 mol %, or even greater than or equal to 0.1 mol %. In embodiments, the concentration of SnO₂ in the glass composition and the resultant colored glass article may be less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, or even less than or equal to 0.25 mol %. In embodiments, the concentration of SnO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, or even greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of SnO₂.

In embodiments, the concentration of Sb₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.05 mol %, or even greater than or equal to 0.1 mol %. In embodiments, the concentration of Sb₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, or even less than or equal to 0.25 mol %. In embodiments, the concentration of Sb₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, or even greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of Sb₂O₃.

In embodiments, the concentration of Bi₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, greater than or equal to 0.05 mol %, or even greater than or equal to 0.1 mol %. In embodiments, the concentration of Bi₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, or even less than or equal to 0.25 mol %. In embodiments, the concentration of Bi₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, or even greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of Bi₂O₃.

In embodiments, the concentration of SO₃ in the glass composition and the resultant colored glass article may be less than or equal to 0.1 mol %, less than or equal to 0.01 mol %, or even less than or equal to 0.001 mol %. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of SO₃.

In embodiments, the glass compositions and the resultant colored glass articles described herein may further comprise a reduced concentration or be substantially free or free of P₂O₅. In embodiments where P₂O₅ is included, the P₂O₅ may enhance the ion exchange characteristics of the resultant colored glass article. However, an increased concentration (i.e., greater than 1 mol %) of P₂O₅ may reduce the retention of one or more colorants in the colorant package. While not wishing to be bound by theory, it is believed that P₂O₅ may be more volatile than other glass network formers, such as SiO₂, which may contribute to reduced retention of colorants in the colorant package. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.1 mol % and less than or equal to 1 mol % P₂O₅. In embodiments, the concentration of P₂O₅ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.1 mol %, greater than or equal to 0.25 mol %, or even greater than or equal to 0.5 mol %. In embodiments, the concentration of P₂O₅ in the glass composition and the resultant colored glass article may be less than or equal to 1 mol % or even less than or equal to 0.75 mol %. In embodiments, the concentration of P₂O₅ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.25 mol % and less than or equal to 1 mol %, greater than or equal to 0.25 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.5 mol % and less than or equal to 1 mol %, or even greater than or equal to 0.5 mol % and less than or equal to 0.75 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of P₂O₅.

In the embodiments described herein, the glass compositions and resultant colored glass articles further comprise at least one colorant in a colorant package that functions to impart a desired color to the resultant colored glass article. In embodiments, the colorant package may comprise at least one of Au, Ag, Cr₂O₃, transition metal oxides (e.g., CuO, NiO, Co₃O₄, TiO₂, Cr₂O₃), rare earth metal oxides (e.g., CeO₂), and/or combinations thereof as colorants in the colorant package. In embodiments, the colorants in the colorant package may be selected from the group consisting of Au, Ag, Cr₂O₃, transition metal oxides (e.g., CuO, NiO, Co₃O₄, TiO₂, Cr₂O₃), rare earth metal oxides (e.g., CeO₂), and combinations thereof. In embodiments, the glass compositions and resultant colored glass articles may include greater than or equal to 1×10⁻⁶ mol % and less than or equal to 10 mol % of colorant (i.e., the sum of all colorants in the colorant package). In embodiments, the concentration of the colorant package in the glass compositions and resultant colored glass articles may be greater than or equal to 1×10⁻⁶ mol % and less than or equal to 9.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 9 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 8.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 8 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 7.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 7 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 6.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 6 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 5.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 4.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 4 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 3.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 3 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 2.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 2 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 1.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 1 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 10 mol %, greater than or equal to 0.0005 mol % and less than or equal to 9.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 9 mol %, greater than or equal to 0.0005 mol % and less than or equal to 8.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 8 mol %, greater than or equal to 0.0005 mol % and less than or equal to 7.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 7 mol %, greater than or equal to 0.0005 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 6 mol %, greater than or equal to 0.0005 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 4 mol %, greater than or equal to 0.0005 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 3 mol %, greater than or equal to 0.0005 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 2 mol %, greater than or equal to 0.0005 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 1 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 9.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 9 mol %, greater than or equal to 0.001 mol % and less than or equal to 8.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 8 mol %, greater than or equal to 0.001 mol % and less than or equal to 7.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 7 mol %, greater than or equal to 0.001 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 6 mol %, greater than or equal to 0.001 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 5 mol %, greater than or equal to 0.001 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 4 mol %, greater than or equal to 0.001 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 3 mol %, greater than or equal to 0.001 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 2 mol %, greater than or equal to 0.001 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 9.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 9 mol %, greater than or equal to 0.01 mol % and less than or equal to 8.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 8 mol %, greater than or equal to 0.01 mol % and less than or equal to 7.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 7 mol %, greater than or equal to 0.01 mol % and less than or equal to 6.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 6 mol %, greater than or equal to 0.01 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 5 mol %, greater than or equal to 0.01 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 4 mol %, greater than or equal to 0.01 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 3 mol %, greater than or equal to 0.01 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, or any and all sub-ranges formed from any of these endpoints.

Colorant: Transition Metal Oxides and/or Rare Earth Oxides

In embodiments, the colorant package in the glass compositions and the resultant colored glass articles may include colorants that comprise or consist of transition metal oxides, rare earth oxides, or combinations thereof, to achieve a desired color. In embodiments, transition metal oxides and/or rare earth oxides may be included in the glass compositions as the sole colorant or in combination with other colorants. In embodiments, colorants based on transition metal oxides and/or rare earth oxides may include NiO, Co₃O₄, Cr₂O₃, CuO, CeO₂, TiO₂ and/or combinations thereof. In embodiments, colorants based on transition metal oxides and/or rare earth oxides may further include oxides of V, Mn, Fe, Cu, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.001 mol %, such as greater than or equal to 0.001 mol % and less than or equal to 10 mol %, NiO+Co₃O₄+Cr₂O₃+CuO+CeO₂+TiO₂. In embodiments, the concentration of NiO+Co₃O₄+Cr₂O₃+CuO+CeO₂+TiO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 0.001 mol % and less than or equal to 5 mol %, greater than or equal to 0.001 mol % and less than or equal to 4 mol %, greater than or equal to 0.001 mol % and less than or equal to 3 mol %, greater than or equal to 0.001 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 2 mol %, greater than or equal to 0.001 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 5 mol %, greater than or equal to 0.01 mol % and less than or equal to 4 mol %, greater than or equal to 0.01 mol % and less than or equal to 3 mol %, greater than or equal to 0.01 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.02 mol % and less than or equal to 5 mol %, greater than or equal to 0.02 mol % and less than or equal to 4 mol %, greater than or equal to 0.02 mol % and less than or equal to 3 mol %, greater than or equal to 0.02 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.02 mol % and less than or equal to 2 mol %, greater than or equal to 0.02 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.7 mol % and less than or equal to 5 mol %, greater than or equal to 0.7 mol % and less than or equal to 4 mol %, greater than or equal to 0.7 mol % and less than or equal to 3 mol %, greater than or equal to 0.7 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.7 mol % and less than or equal to 2 mol %, greater than or equal to 0.7 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.9 mol % and less than or equal to 5 mol %, greater than or equal to 0.9 mol % and less than or equal to 4 mol %, greater than or equal to 0.9 mol % and less than or equal to 3 mol %, greater than or equal to 0.9 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.9 mol % and less than or equal to 2 mol %, greater than or equal to 0.9 mol % and less than or equal to 1.5 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and resultant glass article may comprise 0 mol % of one or more of NiO, Co₃O₄, Cr₂O₃, CuO, CeO₂, and/or TiO₂.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.001 mol %, such as greater than or equal to 0.001 mol % and less than or equal to 3 mol %, NiO+Co₃O₄+Cr₂O₃+CuO. In embodiments, the concentration of NiO+Co₃O₄+Cr₂O₃+CuO in the glass composition and the resultant colored glass article may be greater than or equal to 0.001 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 2 mol %, greater than or equal to 0.001 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.01 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.02 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.02 mol % and less than or equal to 2 mol %, greater than or equal to 0.02 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.02 mol % and less than or equal to 1 mol %, greater than or equal to 0.02 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.02 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.1 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.2 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 2 mol %, greater than or equal to 0.2 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 1 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.4 mol %, or any and all sub-ranges formed from any of these endpoints. In embodiments, the glass composition and resultant glass article may comprise 0 mol % of one or more of NiO, Co₃O₄, Cr₂O₃, and/or CuO.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % TiO₂, such as greater than or equal to 0 mol % and less than or equal to 2 mol % or even greater than or equal to 0.01 mol % and less than or equal to 2 mol %, TiO₂. In embodiments, the concentration of TiO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.75 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.2 mol % and less than or equal to 2 mol %, greater than or equal to 0.2 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 1 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.3 mol % and less than or equal to 2 mol %, greater than or equal to 0.3 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 1 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.4 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.1 mol %, such as greater than or equal to 0.1 mol % and less than or equal to 2 mol %, CeO₂. In embodiments, the concentration of CeO₂ in the glass composition and the resultant colored glass article may be greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.2 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 1 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.2 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.3 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 1 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.3 mol % and less than or equal to 0.4 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol %, such as greater than or equal to 0.01 mol % and less than or equal to 0.05 mol %, NiO. In embodiments, the concentration of NiO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 0.05 mol %, greater than or equal to 0 mol % and less than or equal to 0.04 mol %, greater than or equal to 0 mol % and less than or equal to 0.035 mol %, greater than or equal to 0 mol % and less than or equal to 0.03 mol %, greater than or equal to 0 mol % and less than or equal to 0.025 mol %, greater than or equal to 0 mol % and less than or equal to 0.02 mol %, greater than or equal to 0 mol % and less than or equal to 0.015 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.04 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.035 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.03 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.025 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.02 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.015 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.04 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.035 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.03 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.025 mol %, or even greater than or equal to 0.015 mol % and less than or equal to 0.02 mol %, and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol %, such as greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, CuO. In embodiments, the concentration of CuO in the glass composition and the resultant colored glass article may be greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.35 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.3 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.2 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.15 mol %, greater than or equal to 0.15 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.15 mol % and less than or equal to 0.4 mol %, greater than or equal to 0.15 mol % and less than or equal to 0.35 mol %, greater than or equal to 0.15 mol % and less than or equal to 0.3 mol %, greater than or equal to 0.15 mol % and less than or equal to 0.25 mol %, or even greater than or equal to 0.15 mol % and less than or equal to 0.2 mol %, and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol %, such as greater than or equal to 0.0001 mol % and less than or equal to 0.01 mol %, Co₃O₄. In embodiments, the concentration of Co₃O₄ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 0.01 mol %, greater than or equal to 0 mol % and less than or equal to 0.0095 mol %, greater than or equal to 0 mol % and less than or equal to 0.009 mol %, greater than or equal to 0 mol % and less than or equal to 0.0085 mol %, greater than or equal to 0 mol % and less than or equal to 0.0075 mol %, greater than or equal to 0 mol % and less than or equal to 0.007 mol %, greater than or equal to 0 mol % and less than or equal to 0.0065 mol %, greater than or equal to 0 mol % and less than or equal to 0.006 mol %, greater than or equal to 0 mol % and less than or equal to 0.0055 mol %, greater than or equal to 0 mol % and less than or equal to 0.005 mol %, greater than or equal to 0 mol % and less than or equal to 0.0045 mol %, greater than or equal to 0 mol % and less than or equal to 0.004 mol %, greater than or equal to 0 mol % and less than or equal to 0.0035 mol %, greater than or equal to 0 mol % and less than or equal to 0.003 mol %, greater than or equal to 0 mol % and less than or equal to 0.0025 mol %, greater than or equal to 0 mol % and less than or equal to 0.002 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.01 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0095 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.009 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0085 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0075 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.007 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0065 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.006 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0055 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.005 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0045 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.004 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0035 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.003 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.0025 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.002 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.01 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0095 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.009 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0085 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0075 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.007 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0065 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.006 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0055 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.005 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0045 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.004 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0035 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.003 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.0025 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.002 mol %, and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol %, such as greater than or equal to 0.01 mol % and less than or equal to 0.05 mol %, Cr₂O₃. In embodiments, the concentration of Cr₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 0.05 mol %, greater than or equal to 0 mol % and less than or equal to 0.04 mol %, greater than or equal to 0 mol % and less than or equal to 0.035 mol %, greater than or equal to 0 mol % and less than or equal to 0.03 mol %, greater than or equal to 0 mol % and less than or equal to 0.025 mol %, greater than or equal to 0 mol % and less than or equal to 0.02 mol %, greater than or equal to 0 mol % and less than or equal to 0.015 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.04 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.035 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.03 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.025 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.02 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.015 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.04 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.035 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.03 mol %, greater than or equal to 0.015 mol % and less than or equal to 0.025 mol %, or even greater than or equal to 0.015 mol % and less than or equal to 0.02 mol %, and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise at least one of: greater than or equal to 0.001 mol % NiO+Co₃O₄+Cr₂O₃+CuO, such as greater than or equal to 0.001 mol % and less than or equal to 3 mol % NiO+Co₃O₄+Cr₂O₃+CuO (or any of the ranges of NiO+Co₃O₄+Cr₂O₃+CuO described herein); greater than or equal to 0.1 mol % CeO₂, such as greater than or equal to 0.1 mol % and less than or equal to 1.5 mol % CeO₂ (or any of the ranges of CeO₂ described herein); and greater than or equal to 0.1 mol % TiO₂, such as greater than or equal to 0.1 mol % and less than or equal to 2 mol % TiO₂ (or any of the ranges of TiO₂ described herein).

Colorant: Gold

In embodiments, the colorant package in the glass compositions and the resultant colored glass articles may comprise or consist of Au as a colorant to achieve a desired color. In embodiments, Au may be included in the glass compositions as the sole colorant or in combination with other colorants. As described herein, in embodiments, the glass compositions and the resultant colored glass articles may be formulated to improve the retention of Au, thereby expanding the color gamut achievable in the resultant colored glass articles.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than 0.0005 mol % and less than or equal to 1 mol % Au. In embodiments, the glass composition and the resultant colored glass article may comprise greater than 0.001 mol % and less than or equal to 0.5 mol % Au. In embodiments, the concentration of Au in the glass composition and the resultant colored glass article may be greater than or equal to 0.0005 mol %, greater than or equal to 0.001 mol %, greater than or equal to 0.002 mol % Au, greater than or equal to 0.005 mol %, or even greater than or equal to 0.01 mol %. In embodiments, the concentration of Au in the glass composition and the resultant colored glass article may be less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, less than or equal to 0.25 mol %, less than or equal to 0.1 mol %, or even less than or equal to 0.05 mol %. In embodiments, the concentration of Au in the glass composition and the resultant colored glass article may be greater than or equal to 0.0005 mol % and less than or equal to 1 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.001 mol % and less than or equal to 1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.002 mol % and less than or equal to 1 mol %, greater than or equal to 0.002 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.002 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.002 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.002 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.002 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.005 mol % and less than or equal to 1 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.1 mol %, or even greater than or equal to 0.01 mol % and less than or equal to 0.05 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 1×10⁻⁶ mol % and less than or equal to 1 mol % Au. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.01 mol % Au. In embodiments, the concentration of Au in the glass composition and the resultant colored glass article may be greater than or equal to 1×10⁻⁶ mol %, greater than or equal to 1×10⁻⁵ mol %, greater than or equal to 0.0001 mol %, greater than or equal to 0.0005 mol %, or even greater than or equal to 0.001 mol %. In embodiments, the concentration of Au in the glass composition and the resultant colored glass article may be less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, less than or equal to 0.25 mol %, less than or equal to 0.1 mol %, less than or equal to 0.05 mol %, or even less than or equal to 0.01. In embodiments, the concentration of Au in the glass composition and the resultant colored glass article may be greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.75 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.5 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.25 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.1 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.05 mol %, greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.01 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 1 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 0.75 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 0.5 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 0.25 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 0.1 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 0.05 mol %, greater than or equal to 1×10⁻⁵ mol % and less than or equal to 0.01 mol %, greater than or equal to 0.0001 mol % and less than or equal to 1 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.0001 mol % and less than or equal to 0.01 mol %, greater than or equal to 0.0005 mol % and less than or equal to 1 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.0005 mol % and less than or equal to 0.01 mol %, greater than or equal to 0.001 mol % and less than or equal to 1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.05 mol %, or even greater than or equal to 0.001 mol % and less than or equal to 0.01 mol %, or any and all sub-ranges formed from any of these endpoints.

A different color gamut may be achieved by including secondary colorants in addition to Au. For example, in embodiments, the glass composition and resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 1 mol % of a cation “M”, wherein “M” is at least one of F, Cl, Br, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Se, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Te, W, Ir, Pt, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er.

Colorant: Cr₂O₃

In embodiments, the colorant package used in the glass compositions and the resultant colored glass articles described herein may comprise or consist of Cr₂O₃ as a colorant to achieve a desired color. In embodiments, Cr₂O₃ may be included in the glass compositions as the sole colorant or in combination with other colorants. For example, in embodiments where Cr₂O₃ is utilized as a colorant, other transition metal oxides may be included in the glass composition to modify the color imparted to the glass, including, for example and without limitation, CuO, NiO, and/or Co₃O₄. As described herein, in embodiments, the glass compositions and the resultant colored glass articles may be formulated to improve the solubility of Cr₂O₃, thereby expanding the color gamut achievable in the resultant colored glass articles.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.001 mol % and less than or equal to 1.5 mol % Cr₂O₃. In embodiments, the concentration of Cr₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.001 mol %, greater than or equal to 0.005 mol %, greater than or equal to 0.01 mol %, or even greater than or equal to 0.05 mol %. In embodiments, the concentration of Cr₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 2 mol %, less than or equal to 1.5 mol %, less than or equal to 1 mol %, less than or equal to 0.5 mol %, or even less than or equal to 0.1 mol %. In embodiments, the concentration of Cr₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.001 mol % and less than or equal to 2 mol %, greater than or equal to 0.001 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.005 mol % and less than or equal to 2 mol %, greater than or equal to 0.005 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.005 mol % and less than or equal to 1 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.05 mol % and less than or equal to 2 mol %, greater than or equal to 0.05 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, or even greater than or equal to 0.05 mol % and less than or equal to 0.1 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments where the colorant package includes Cr₂O₃ as a colorant, the glass compositions and the resultant colored glass articles are per-alkali (i.e., R₂O (mol %)+R′O (mol %)-Al₂O₃ (mol %) is greater than or equal to 0.5 mol %) to increase the solubility of Cr₂O₃ and avoid Cr-spinel crystal formation. However, when the glass composition has an excessive amount of alkali after charge balancing Al₂O₃, the alkali may form non-bridging oxygen around SiO₂, which degrades fracture toughness. Accordingly, in embodiments, R₂O+R′O—Al₂O₃ in the glass composition and the resultant colored glass article may be limited (e.g., less than or equal to 6 mol %) to prevent a reduction in fracture toughness.

In embodiments, R₂O+R′O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0.5 mol % and less than or equal to 6 mol %. In embodiments, R₂O+R′O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 1 mol % and less than or equal to 5.5 mol %. In embodiments, R₂O+R′O—Al₂O₃ in the glass composition and the colored resultant glass article may be greater than or equal to 0.5 mol %, greater than or equal to 1 mol %, greater than or equal to 1.5 mol %, or even greater than or equal to 2 mol %. In embodiments, R₂O+R′O—Al₂O₃ in the glass composition and the resultant colored glass article may be less than or equal to 6 mol %, less than or equal to 5.5 mol %, less than or equal to 5 mol %, less than or equal to 4.5 mol %, less than or equal to 4 mol %, less than or equal to 3.5 mol %, or even less than or equal to 3 mol %. In embodiments, R₂O+R′O—Al₂O₃ in the glass composition and the resultant colored glass article may be greater than or equal to 0.5 mol % and less than or equal to 6 mol %, greater than or equal to 0.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 1 mol % and less than or equal to 6 mol %, greater than or equal to 1 mol % and less than or equal to 5.5 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4.5 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 3.5 mol %, greater than or equal to 1 mol % and less than or equal to 3 mol %, greater than or equal to 1.5 mol % and less than or equal to 6 mol %, greater than or equal to 1.5 mol % and less than or equal to 5.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 4 mol %, greater than or equal to 1.5 mol % and less than or equal to 3.5 mol %, greater than or equal to 1.5 mol % and less than or equal to 3 mol %, greater than or equal to 2 mol % and less than or equal to 6 mol %, greater than or equal to 2 mol % and less than or equal to 5.5 mol %, greater than or equal to 2 mol % and less than or equal to 5 mol %, greater than or equal to 2 mol % and less than or equal to 4.5 mol %, greater than or equal to 2 mol % and less than or equal to 4 mol %, greater than or equal to 2 mol % and less than or equal to 3.5 mol %, or even greater than or equal to 2 mol % and less than or equal to 3 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments where the colorant package comprises Cr₂O₃ as a colorant, the glass compositions and the resultant colored glass articles may satisfy at least one of the following conditions and achieve the desired color: (1) less than or equal to 17.5 mol % Al₂O₃ and/or R₂O+R′O—Al₂O₃ greater than or equal to 0.5 mol %; (2) Al₂O₃+MgO+ZnO less than or equal to 22 mol %; and (3) MgO+ZnO less than or equal to 4.5 mol %.

In embodiments where the colorant comprises Cr₂O₃, different color gamuts may be achieved by including other colorants in addition to Cr₂O₃. For example, in embodiments, the glass composition and resultant colored glass article may comprise NiO, Co₃O₄, CuO, or combinations thereof in addition to Cr₂O₃.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 4 mol % NiO as a colorant in addition to Cr₂O₃. In embodiments, the concentration of NiO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.01 mol %, or even greater than or equal to 0.05 mol %. In embodiments, the concentration of NiO in the glass composition and the resultant colored glass article may be less than or equal to 4 mol %, less than or equal to 3 mol %, less than or equal to 2 mol %, less than or equal to 1 mol %, less than or equal to 0.5 mol %, less than or equal to 0.25 mol %, or even less than or equal to 0.1 mol %. In embodiments, the concentration of NiO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.25 mol %, greater than or equal to 0 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.01 mol % and less than or equal to 4 mol %, greater than or equal to 0.01 mol % and less than or equal to 3 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.05 mol % and less than or equal to 4 mol %, greater than or equal to 0.05 mol % and less than or equal to 3 mol %, greater than or equal to 0.05 mol % and less than or equal to 2 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.25 mol %, or even greater than or equal to 0.05 mol % and less than or equal to 0.1 mol %, or any and all sub-ranges formed between any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0 mol % and less than or equal to 2 mol % Co₃O₄ as a colorant in addition to Cr₂O₃. In embodiments, the concentration of Co₃O₄ in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol %, greater than or equal to 0.001 mol %, greater than or equal to 0.005 mol %, or even greater than or equal to 0.01 mol %. In embodiments, the concentration of Co₃O₄ in the glass composition and the resultant colored glass article may be less than or equal to 2 mol %, less than or equal to 1.5 mol %, less than or equal to 1 mol %, less than or equal to 0.5 mol %, less than or equal to 0.1 mol %, or even less than or equal to 0.05 mol %. In embodiments, the concentration of Co₃O₄ in the glass composition and the resultant colored glass article may greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.1 mol %, greater than or equal to 0 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.001 mol % and less than or equal to 2 mol %, greater than or equal to 0.001 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.001 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.005 mol % and less than or equal to 2 mol %, greater than or equal to 0.005 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.005 mol % and less than or equal to 1 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.1 mol %, greater than or equal to 0.005 mol % and less than or equal to 0.05 mol %, greater than or equal to 0.01 mol % and less than or equal to 2 mol %, greater than or equal to 0.01 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.1 mol %, or even greater than or equal to 0.01 mol % and less than or equal to 0.05 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or 0 mol % and less than or equal to 5 mol % CuO as a colorant in addition to Cr₂O₃. In embodiments, the concentration of CuO in the glass composition and the resultant colored glass article may be greater than or equal 0 mol %, greater than or equal to 0.05 mol %, greater than or equal to 0.1 mol %, greater than or equal to 0.5 mol %, or even greater than or equal to 1 mol %. In embodiments, the concentration of CuO in the glass composition and the resultant colored glass article may be less than or equal to 5 mol %, less than or equal to 4 mol %, less than or equal to 3 mol %, or even less than or equal to 2 mol %. In embodiments, the concentration of CuO in the glass composition and the resultant colored glass article may be greater than or equal to 0 mol % and less than or equal to 5 mol %, greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol, greater than or equal to 0.05 mol % and less than or equal to 5 mol %, greater than or equal to 0.05 mol % and less than or equal to 4 mol %, greater than or equal to 0.05 mol % and less than or equal to 3 mol %, greater than or equal to 0.05 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.5 mol % and less than or equal to 5 mol %, greater than or equal to 0.5 mol % and less than or equal to 4 mol %, greater than or equal to 0.5 mol % and less than or equal to 3 mol %, greater than or equal to 0.5 mol % and less than or equal to 2 mol %, greater than or equal to 1 mol % and less than or equal to 5 mol %, greater than or equal to 1 mol % and less than or equal to 4 mol %, greater than or equal to 1 mol % and less than or equal to 3 mol %, or even greater than or equal to 1 mol % and less than or equal to 2 mol %, or any and all sub-ranges formed from any of these endpoints.

Colorant: Silver

In embodiments, the colorant package used in the glass compositions and the resultant colored glass articles may comprise or consist of Ag as a colorant to achieve a desired color. As described herein, in embodiments, the glass compositions and the resultant colored glass articles may be formulated to improve the retention of Ag, thereby expanding the color gamut achievable in the resultant colored glass articles. In embodiments, Ag may be included in the glass compositions as the sole colorant or in combination with other colorants. In embodiments where Ag is utilized as a colorant in the glass composition, the color is created by the presence of anisotropic silver particles in the colored glass article that are formed from the reduction of silver ions in the glass composition.

Accordingly, in embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.01 mol % and less than or equal to 5 mol % Ag. In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 0.05 mol % and less than or equal to 2.5 mol % Ag, greater than or equal to 0.1 mol % and less than or equal to 1 mol % Ag, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol % Ag, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol % Ag, or greater than or equal to 0.1 mol % and less than or equal to 0.25 mol % Ag. In embodiments, the concentration of Ag in the glass composition and the resultant colored glass article may be greater than or equal to 0.01 mol %, greater than or equal to 0.05 mol %, or greater than or equal to 0.1 mol %. In embodiments, the concentration of Ag in the glass composition and the resultant colored glass article may be less than or equal to 5 mol %, less than or equal to 2.5 mol %, less than or equal to 1 mol %, less than or equal to 0.75 mol %, less than or equal to 0.5 mol %, or less than or equal to 0.25 mol %. In embodiments, the concentration of Ag in the glass composition and the resultant colored glass article may be greater than or equal to 0.01 mol % and less than or equal to 5 mol %, greater than or equal to 0.01 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 1 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.01 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 5 mol %, greater than or equal to 0.05 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 0.25 mol %, greater than or equal to 0.1 mol % and less than or equal to 5 mol %, greater than or equal to 0.1 mol % and less than or equal to 2.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.75 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 0.25 mol %, or any and all sub-ranges formed from any of these endpoints.

Conventionally, halide-free colored glass articles that comprise silver in as-formed condition (i.e., colored glass articles that have not been subjected to mechanical stretching) produce only yellow, orange, and red colors upon a suitable heat treatment applied to the glass article in as-formed condition. These colors are generated by the formation of isotropic (i.e., nominally spherical) silver particles in the conventional, halide-free colored glass article. These isotropic silver particles support a single localized surface plasmon resonance. Isotropic silver particles are the most energetically favorable to form because they have the lowest surface area to volume ratio and, as a result, they are the most common geometry observed in colored glass articles that comprise silver.

In contrast, colored glass articles that comprise anisotropic silver particles can produce a much broader range of colors, such as pink, purple, blue, green, brown and black. As used herein, anisotropic silver particles refer to silver particles having an aspect ratio greater than 1, where the aspect ratio is the ratio of longest dimension of the particle to the shortest dimension of the particle (e.g., a ratio of the length of the particle to the width of the particle is greater than 1). This is in contrast to an isotropic silver particle in which the aspect ratio is 1. The broader color gamut produced in glasses having anisotropic silver particles is because anisotropic silver particles support two distinct plasmonic modes: a higher energy transverse mode, and a lower energy longitudinal mode. These two distinct plasmonic modes can be observed via absorption spectra of the colored glass articles, which typically have at least two distinct peaks when anisotropic silver particles are present in the glass. By varying the aspect ratio of anisotropic particles, the resonant absorption of these two plasmonic modes can be tuned and, as a result, the color shifted.

Conventionally, the formation of anisotropic metallic silver particles in glass can be either induced by elongating spherical particles of silver through shear forces (e.g., by stretching the colored glass article via re-draw) using mechanical stretching processes. The mechanical stretching process results in a glass article having silver particles that are generally aligned in parallel with one another along the stretching direction (i.e., the glass is polarized).

A conventional alternative to mechanical stretching processes for creating anisotropic metallic particles in a glass article is the incorporation of halides (e.g., F, Cl, and Br) in the glass composition. In halide-containing colored glass articles, anisotropic silver particles are formed by templating the particles on elongated and/or pyramidal-shaped halide crystals. However, the inclusion of halides in the glass composition may be undesirable.

In contrast, the colored glass articles comprising Ag as a colorant described herein may generate a broad range of colors, such as yellow, orange, red, green, pink, purple, brown, and black without the inclusion of halides in the glass composition or the use of mechanical stretching processes. Without being bound by any particular theory, it is believed that anisotropic silver particles may form in the colored glass articles of the present disclosure due to a mechanism similar to the template growth caused by the inclusion of halides in the glass composition. However, instead of templating on a halide-containing crystal or mechanically stretching isotropic silver particles, it has been unexpectedly found that anisotropic silver crystals may form on nano-sized crystals of spodumene, lithium silicate, and/or beta quartz during heat treatment of the glass article in its as formed condition. Additionally and/or alternatively, it is believed that anisotropic silver particles may precipitate at the interfaces between phase separated regions of the colored glass article and/or regions that are only partially crystalized. Further, these crystals and/or phase separated regions may form a nucleation site for the growth of anisotropic silver particles.

Accordingly, in embodiments, the glass composition and the resultant colored glass article including silver as a colorant may comprise less than 100 parts per million (ppm) of halides. For example, the glass compositions and the resultant colored glass articles comprising Ag as a colorant may comprise less than 100 ppm halides, such as less than 50 ppm halides, less than 25 ppm halides, less than 10 ppm halides, or even 0 ppm halides.

As noted previously, colored glass articles comprising Ag produced using mechanical stretching processes generally include anisotropic silver particles similar to those of the colored glass article of the present application. However, it should be noted that these mechanical stretching processes also result in the anisotropic silver particles being ordered and aligned (e.g., the longer dimensions of each anisotropic silver particles are facing in the same direction, such as in the direction of mechanical stretching). Put more simply, the colored glass articles produced using mechanical stretching processes are polarized due to the alignment of the anisotropic silver particles in the glass as a result of mechanical stretching.

In contrast, in the embodiments described herein, the colored glass articles comprising Ag as a colorant, which are not subjected to mechanical stretching processes, are non-polarized. In embodiments, the anisotropic silver particles of the colored glass article are not aligned (e.g., the longer dimensions of two or more anisotropic silver particles are facing in different directions) and, instead, the anisotropic silver particles are randomly aligned in the glass.

The term “length,” as used herein, refers to the longest dimension of the anisotropic silver particles. In embodiments, the anisotropic silver particles in the colored glass articles described herein have a length greater than or equal to 10 nm, greater than or equal to 12 nm, greater than or equal to 14 nm, greater than or equal to 16 nm, greater than or equal to 18 nm, greater than or equal to 10 nm, greater than or equal to 22 nm, greater than or equal to 24 nm, greater than or equal to 26 nm, greater than or equal to 28 nm, greater than or equal to 30 nm, greater than or equal to 32 nm, greater than or equal to 34 nm, greater than or equal to 36 nm, or even greater than or equal to 38 nm. The length of the anisotropic silver particles may be measured using image analysis on electron micrographs obtained from samples of the colored glass articles using software such as ImageJ software. To obtain the length and width of the anisotropic silver particles, a calibration is set by measuring the scale bar on the electron micrograph, converting each pixel to the appropriate unit length. The image is then converted into a grayscale image. A software measuring tool is then used to measure the number of pixels from one end to the other of each particle as well as the number of pixels across the greatest width of the particle. In embodiments an automated script is run to measure the length and aspect ratios of multiple particles automatically. In embodiments, the anisotropic silver particles in the colored glass articles described herein have a length less than or equal to 40 nm, less than or equal to 38 nm, less than or equal to 36 nm, less than or equal to 34 nm, less than or equal to 32 nm, less than or equal to 30 nm, less than or equal to 28 nm, less than or equal to 26 nm, less than or equal to 24 nm, less than or equal to 22 nm, or even less than or equal to 20 nm. In embodiments, the anisotropic silver particles in the colored glass articles described herein have a length greater than or equal to 10 nm and less than or equal to 40 nm, greater than or equal to 12 nm and less than or equal to 36 nm, greater than or equal to 14 nm and less than or equal to 34 nm, greater than or equal to 14 nm and less than or equal to 32 nm, greater than or equal to 14 nm and less than or equal to 28 nm, greater than or equal to 14 nm and less than or equal to 26 nm, greater than or equal to 16 nm and less than or equal to 26 nm, greater than or equal to 16 nm and less than or equal to 24 nm, greater than or equal to 16 nm and less than or equal to 22 nm, greater than or equal to 16 nm and less than or equal to 20 nm, or any and all sub-ranges formed from any of these endpoints.

The term “width,” as used herein, refers to the dimension of the anisotropic particles in a direction perpendicular to the longest dimension of the anisotropic particles (i.e., the dimension in a direction perpendicular to the length). In embodiments, the anisotropic silver particles in the colored glass articles described herein have a width greater than or equal to 6 nm, greater than or equal to 8 nm, greater than or equal to 10 nm, greater than or equal to 12 nm, or even greater than or equal to 14 nm. In embodiments, the anisotropic silver particles in the colored glass articles described herein have a width less than or equal to 20 nm, less than or equal to 18 nm, less than or equal to 16 nm, less than or equal to 12 nm, or even less than or equal to 10 nm. In embodiments, the anisotropic silver particles in the colored glass articles described herein have a width greater than or equal to 6 nm and less than or equal to 20 nm, greater than or equal to 6 nm and less than or equal to 18 nm, greater than or equal to 6 nm and less than or equal to 16 nm, greater than or equal to 8 nm and less than or equal to 20 nm, greater than or equal to 8 nm and less than or equal to 18 nm, greater than or equal to 8 nm and less than or equal to 16 nm, greater than or equal to 10 nm and less than or equal to 20 nm, greater than or equal to 10 nm and less than or equal to 18 nm, greater than or equal to 10 nm and less than or equal to 16 nm, greater than or equal to 10 nm and less than or equal to 14 nm, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the anisotropic silver particles in the colored glass articles described herein have an aspect ratio (i.e., the ratio of the length to the width of the anisotropic silver nanoparticles) greater than 1, greater than or equal to 1.5, greater than or equal to 2, or even greater than or equal to 2.5. In embodiments, the anisotropic silver particles in the colored glass articles described herein have an aspect ratio less than or equal to 3, less than or equal to 2.5, less than or equal to 2, or even less than or equal to 1.5. In embodiments, the anisotropic silver particles in the colored glass articles described herein have an aspect ratio greater than 1 and less than or equal to 3, greater than 1 and less than or equal to 2.5, greater than 1 and less than or equal to 2, greater than 1 and less than or equal to 1.5, greater than or equal to 1.5 and less than or equal to 3, greater than or equal to 1.5 and less than or equal to 2.5, greater than or equal to 1.5 and less than or equal to 2, greater than or equal to 2 and less than or equal to 3, greater than or equal to 2 and less than or equal to 2.5, or any and all sub-ranges formed from any of these endpoints.

The glass compositions and the resultant colored glass articles that include Ag as a colorant may further comprise one or more rare-earth oxides, such as CeO₂, Nd₂O₃, Er₂O₃. Rare-earth oxides may be added to provide additional visible light absorbance to the glass (in addition to that imparted by the silver) to further alter the color of the glass. Rare-earth oxides may also be added to increase the Young's modulus and/or the annealing point of the resultant glass.

In embodiments, the glass compositions and the resultant colored glass articles that include Ag as a colorant may further comprise greater than or equal to 0 mol % and less than or equal to 4 mol % of CeO₂, In embodiments, the glass compositions and the resultant colored glass articles that include Ag as a colorant may further comprise greater than or equal to 0 mol % and less than or equal to 3 mol % CeO₂, greater than or equal to 0 mol % and less than or equal to 1 mol % of CeO₂, greater than or equal to 0.05 mol % and less than or equal to 1 mol % of CeO₂, or greater than or equal to 0.05 mol % and less than or equal to 0.5 mol % of CeO₂. In embodiments, the concentration of CeO₂ in the glass compositions and the resultant colored glass articles that comprise Ag as a colorant may be greater than or equal to 0 mol %, or even greater than or equal to 0.05 mol %. In embodiments, the concentration of CeO₂ in the glass compositions and the resultant colored glass articles that comprise Ag as a colorant may be less than or equal to 4 mol %, less than or equal to 3 mol %, less than or equal to 2 mol %, less than or equal to 1 mol % or less than or equal to 0.5 mol %. In embodiments, the concentration of CeO₂ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.05 mol % and less than or equal to 4 mol %, greater than or equal to 0.05 mol % and less than or equal to 3 mol %, greater than or equal to 0.05 mol % and less than or equal to 2 mol %, greater than or equal to 0.05 mol % and less than or equal to 1 mol %, or even greater than or equal to 0.05 mol % and less than or equal to 0.5 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass compositions and the resultant colored glass articles that include Ag as a colorant may comprise greater than or equal to 0 mol % and less than or equal to 4 mol % of Nd₂O₃, In embodiments, the glass compositions and the resultant colored glass articles that include Ag as a colorant may comprise greater than or equal to 0 mol % and less than or equal to 3 mol % Nd₂O₃, greater than or equal to 0 mol % and less than or equal to 1 mol % of Nd₂O₃, greater than or equal to 0 mol % and less than or equal to 1 mol % of Nd₂O₃, greater than or equal to 0.1 mol % and less than or equal to 1 mol % of Nd₂O₃, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol % of Nd₂O₃, or greater than or equal to 0.1 mol % and less than or equal to 0.5 mol % of Nd₂O₃. In embodiments, the concentration of Nd₂O₃ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be greater than or equal to 0 mol %, or even greater than or equal to 0.1 mol %. In embodiments, the concentration of Nd₂O₃ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be less than or equal to 4 mol %, less than or equal to 3 mol %, less than or equal to 2 mol %, less than or equal to 1 mol % or less than or equal to 0.5 mol %. In embodiments, the concentration of one or more of Nd₂O₃ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, or even greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass compositions and the resultant colored glass articles that include Ag as a colorant may comprise greater than or equal to 0 mol % and less than or equal to 4 mol % of Er₂O₃. In embodiments, the glass compositions and the resultant colored glass articles that include Ag as a colorant may comprise greater than or equal to 0 mol % and less than or equal to 3 mol % Er₂O₃, greater than or equal to 0 mol % and less than or equal to 1.5 mol % of Er₂O₃, greater than or equal to 0 mol % and less than or equal to 1 mol % of Er₂O₃, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol % of Er₂O₃, greater than or equal to 0.1 mol % and less than or equal to 1 mol % of Er₂O₃, or greater than or equal to 0.1 mol % and less than or equal to 0.5 mol % of Er₂O₃. In embodiments, the concentration of Er₂O₃ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be greater than or equal to 0 mol %, or even greater than or equal to 0.1 mol %. In embodiments, the concentration of Er₂O₃ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be less than or equal to 4 mol %, less than or equal to 3 mol %, less than or equal to 2 mol %, less than or equal to 1 mol % or less than or equal to 0.5 mol %. In embodiments, the concentration of one or more of Er₂O₃ in the glass compositions and the resultant colored glass articles that include Ag as a colorant may be greater than or equal to 0 mol % and less than or equal to 4 mol %, greater than or equal to 0 mol % and less than or equal to 3 mol %, greater than or equal to 0 mol % and less than or equal to 2 mol %, greater than or equal to 0 mol % and less than or equal to 1.5 mol %, greater than or equal to 0 mol % and less than or equal to 1 mol %, greater than or equal to 0 mol % and less than or equal to 0.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 4 mol %, greater than or equal to 0.1 mol % and less than or equal to 3 mol %, greater than or equal to 0.1 mol % and less than or equal to 2 mol %, greater than or equal to 0.1 mol % and less than or equal to 1.5 mol %, greater than or equal to 0.1 mol % and less than or equal to 1 mol %, or even greater than or equal to 0.1 mol % and less than or equal to 0.5 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the glass compositions and the resultant colored glass articles described herein may further include tramp materials such as TiO₂, MnO, MoO₃, WO₃, Y₂O₃, CdO, As₂O₃, sulfur-based compounds, such as sulfates, halogens, or combinations thereof. In embodiments, the glass composition and the resultant colored glass article may be substantially free or free of tramp materials such as TiO₂, MnO, MoO₃, WO₃, Y₂O₃, CdO, As₂O₃, sulfur-based compounds, such as sulfates, halogens, or combinations thereof.

In embodiments described herein, decreasing the melting point of the glass composition may help improve colorant retention because the glass compositions may be melted at relatively lower temperatures and colorant evaporation may be reduced.

Accordingly, the glass compositions and the resultant colored glass articles described herein may optionally include MgO and/or ZnO, which help lower the melting point of the glass composition. B₂O₃, Li₂O, and Na₂O also decrease the melting point of the glass composition. As described herein, other components may be added to the glass composition to lower the melting point thereof, such as SnO₂, Sb₂O₃, and Bi₂O₃. In embodiments, the glass composition may have a melting point less than or equal to 1550° C. In embodiments, the glass composition may have a melting point greater than or equal to 1300° C., greater than or equal to 1325° C., greater than or equal to 1350° C., greater than or equal to 1375° C., or even greater than or 1400° C. In embodiments, the glass composition may have a melting point less than or equal to 1550° C., less than or equal to 1525° C., less than or equal 1500° C., less than or equal to 1475° C., or even less than or equal to 1450° C. In embodiments, the melting point of the glass composition may be greater than or equal to 1300° C. and less than or equal to 1550° C., greater than or equal to 1300° C. and less than or equal to 1525° C., greater than or equal to 1300° C. and less than or equal to 1500° C., greater than or equal to 1300° C. and less than or equal to 1475° C., greater than or equal to 1300° C. and less than or equal to 1450° C., greater than or equal to 1325° C. and less than or equal to 1550° C., greater than or equal to 1325° C. and less than or equal to 1525° C., greater than or equal to 1325° C. and less than or equal to 1500° C., greater than or equal to 1325° C. and less than or equal to 1475° C., greater than or equal to 1325° C. and less than or equal to 1450° C., greater than or equal to 1350° C. and less than or equal to 1550° C., greater than or equal to 1350° C. and less than or equal to 1525° C., greater than or equal to 1350° C. and less than or equal to 1500° C., greater than or equal to 1350° C. and less than or equal to 1475° C., greater than or equal to 1350° C. and less than or equal to 1450° C., greater than or equal to 1375° C. and less than or equal to 1550° C., greater than or equal to 1375° C. and less than or equal to 1525° C., greater than or equal to 1375° C. and less than or equal to 1500° C., greater than or equal to 1375° C. and less than or equal to 1475° C., greater than or equal to 1375° C. and less than or equal to 1450° C., greater than or equal to 1400° C. and less than or equal to 1550° C., greater than or equal to 1400° C. and less than or equal to 1525° C., greater than or equal to 1400° C. and less than or equal to 1500° C., greater than or equal to 1400° C. and less than or equal to 1475° C., or even greater than or equal to 1400° C. and less than or equal to 1450° C., or any and all sub-ranges formed from any of these endpoints.

In embodiments, a liquidus temperature of the glass composition may be greater than or equal to 1000° C., greater than or equal to 1050° C., or even greater than or equal to 1100° C. In embodiments, a liquidus temperature of the precursor glass composition may be less than or equal to 1400° C., less than or equal to 1350° C. or even less than or equal to 1300° C. In embodiments, a liquidus temperature of the glass composition may be greater than or equal to 1000° C. and less than or equal to 1400° C., greater than or equal to 1000° C. and less than or equal to 1350° C., greater than or equal to 1000° C. and less than or equal to 1300° C., greater than or equal to 1050° C. and less than or equal to 1400° C., greater than or equal to 1050° C. and less than or equal to 1350° C., greater than or equal to 1000° C. and less than or equal to 1300° C., greater than or equal to 1100° C. and less than or equal to 1400° C., greater than or equal to 1100° C. and less than or equal to 1350° C., or even greater than or equal to 1100° C. and less than or equal to 1300° C., or any and all sub-ranges formed from any of these endpoints.

In embodiments, the viscosity of the glass composition may be adjusted to prevent devitrification of the glass composition and formation of colorant particles, such as Au particles, during melting and forming. Formation of colorant particles during melting and forming may limit the color gamut that may be achieved by heat treatment. In embodiments, to achieve the desired viscosity and thereby prevent formation of colorant particles before melting, the glass compositions and the resultant glass articles described herein may satisfy the relationship 5.72*Al₂O₃ (mol %)-21.4*ZnO (mol %)-2.5*P₂O₅ (mol %)-35*Li₂O (mol %)-16.6*B₂O₃ (mol %)-20.5*MgO (mol %)-23.3*Na₂O (mol %)-27.9*SrO (mol %)-18.5*K₂O (mol %)-26.3*CaO (mol %) is greater than −609 mol %. While not wishing to be bound by theory, it is believe that this relationship may also hold true for glass compositions containing colorants other than Au, such as when the colorant comprises Ag (which may also form colorant particles in the glass). In embodiments, the glass compositions and the resultant glass articles described herein may satisfy the relationship 5.72*Al₂O₃ (mol %)-21.4*ZnO (mol %)-2.5*P₂O₅ (mol %)-35*Li₂O (mol %)-16.6*B₂O₃ (mol %)-20.5*MgO (mol %)-23.3*Na₂O (mol %)-27.9*SrO (mol %)-18.5*K₂O (mol %)-26.3*CaO (mol %) is greater than −609 mol %, greater than or equal to −575 mol %, greater than or equal to −550 mol %, or even greater than or equal to −525 mol %. In embodiments, the glass compositions and the resultant glass articles described herein may satisfy the relationship 5.72*Al₂O₃ (mol %)-21.4*ZnO (mol %)-2.5*P₂O₅ (mol %)-35*Li₂O (mol %)-16.6*B₂O₃ (mol %)-20.5*MgO (mol %)-23.3*Na₂O (mol %)-27.9*SrO (mol %)-18.5*K₂O (mol %)-26.3*CaO (mol %) is less than or equal to −400 mol %, less than or equal to −425 mol %, or even less than or equal to −450 mol %. In embodiments, the glass compositions and the resultant glass articles described herein may satisfy the relationship 5.72*Al₂O₃ (mol %)-21.4*ZnO (mol %)-2.5*P₂O₅ (mol %)-35*Li₂O (mol %)-16.6*B₂O₃ (mol %)-20.5*MgO (mol %)-23.3*Na₂O (mol %)-27.9*SrO (mol %)-18.5*K₂O (mol %)-26.3*CaO (mol %) is greater than −609 mol % and less than or equal to −400 mol %, greater than −609 mol % and less than or equal to −425 mol %, greater than −609 mol % and less than or equal to −450 mol %, greater than or equal to −575 mol % and less than or equal to −400 mol %, greater than or equal to −575 mol % and less than or equal to −425 mol %, greater than or equal to −575 mol % and less than or equal to −450 mol %, greater than or equal to −550 mol % and less than or equal to −400 mol %, greater than or equal to −550 mol % and less than or equal to −425 mol %, greater than or equal to −550 mol % and less than or equal to −450 mol %, greater than or equal to −525 mol % and less than or equal to −400 mol %, greater than or equal to −525 mol % and less than or equal to −425 mol %, or even greater than or equal to −525 mol % and less than or equal to −450 mol %, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the colored glass articles may be formed by first melting a glass composition comprising a combination of constituent glass components as described herein and one or more colorants in a colorant package. Thereafter, the molten glass is formed into a precursor glass article using conventional forming techniques and, thereafter, cooled. The precursor glass article may take on any number of forms including, without limitation, sheets, tubes, rods, containers (e.g., vials, bottles, jars, etc.) or the like. In embodiments, the precursor glass article may be exposed to a heat treatment to produce color in the glass. For example and without limitation, the heat treatment may induce the formation of colorant particles in the glass which, in turn, cause the glass to become colored. In some embodiments, the glass may appear clear (i.e., colorless) prior to heat treatment. Examples of colorant particles may include, for example and without limitation, Au particles (such as when the colorant package in the glass comprises Au), randomly oriented, anisotropic silver particles (such as when the colorant package comprises Ag) and/or the like, thereby forming a colored glass article. The time and/or temperature of the heat treatment may be specifically selected to produce a colored glass article having a desired color. Without wishing to be bound by theory, it is believed that a desired color is a result of the morphology of the particles precipitated in the glass which, in turn, is dependent on the time and/or temperature of the heat treatment. Accordingly, it should be understood that a single glass composition can be used to form colored glass articles having different colors based on the time and/or temperature of the applied heat treatment in addition to the composition of the colorant package included in the glass.

Specifically, different color coordinates within the color gamut may be achieved by altering the heat treatment cycle of the glass composition used to produce the resultant colored glass articles. The heat treatment cycle is characterized by the temperature of the environment (i.e., the oven) and the duration of the cycle (i.e., the time exposed to the heated environment). As used herein, the phrase “temperature of the heat treatment cycle” refers to the temperature of the environment (i.e., the oven). In embodiments, glass articles formed from the glass compositions described herein are heat treated in an isothermal oven to produce the resultant colored glass articles.

In embodiments, the temperature of the heat treatment cycle is greater than or equal to 500° C., greater than or equal to 550° C., greater than or equal to 575° C., greater than or equal to 600° C., greater than or equal to 625° C., or even greater than or equal to 650° C. In embodiments, the temperature of the heat treatment cycle is less than or equal to 800° C., less than or equal to 775° C., less than or equal to 750° C., less than or equal to 725° C., or even less than or equal to 700° C. In embodiments, the temperature of the heat treatment cycle is greater than or equal to 500° C. and less than or equal to 800° C., greater than or equal to 500° C. and less than or equal to 775° C., greater than or equal to 500° C. and less than or equal to 750° C., greater than or equal to 500° C. and less than or equal to 725° C., greater than or equal to 550° C. and less than or equal to 700° C., greater than or equal to 550° C. and less than or equal to 800° C., greater than or equal to 550° C. and less than or equal to 775° C., greater than or equal to 550° C. and less than or equal to 750° C., greater than or equal to 550° C. and less than or equal to 725° C., greater than or equal to 550° C. and less than or equal to 700° C., greater than or equal to 575° C. and less than or equal to 800° C., greater than or equal to 575° C. and less than or equal to 775° C., greater than or equal to 575° C. and less than or equal to 750° C., greater than or equal to 575° C. and less than or equal to 725° C., greater than or equal to 575° C. and less than or equal to 700° C., greater than or equal to 600° C. and less than or equal to 800° C., greater than or equal to 600° C. and less than or equal to 775° C., greater than or equal to 600° C. and less than or equal to 750° C., greater than or equal to 600° C. and less than or equal to 725° C., greater than or equal to 600° C. and less than or equal to 700° C., greater than or equal to 625° C. and less than or equal to 800° C., greater than or equal to 625° C. and less than or equal to 775° C., greater than or equal to 625° C. and less than or equal to 750° C., greater than or equal to 625° C. and less than or equal to 725° C., greater than or equal to 625° C. and less than or equal to 700° C., greater than or equal to 650° C. and less than or equal to 800° C., greater than or equal to 650° C. and less than or equal to 775° C., greater than or equal to 650° C. and less than or equal to 750° C., greater than or equal to 650° C. and less than or equal to 725° C., or even greater than or equal to 650° C. and less than or equal to 700° C., or any and all sub-ranges formed from any of these endpoints.

In embodiments, the duration of the heat treatment cycle is greater than or equal to 0.15 hour, greater than or equal to 0.25 hour, greater than or equal to 0.5 hour, greater than or equal 1 hour, or even greater than or equal to 2 hours. In embodiments, the durations of the heat treatment cycle is less than or equal to 24 hours, less than or equal to 16 hours, less than or equal to 8 hours, less than or equal to 6 hours, less than or equal to 4 hours, or even less than or equal to 3 hours. In embodiments, the duration of the heat treatment cycle is greater than or equal to 0.25 hour and less than or equal to 24 hours, greater than or equal to 0.25 hour and less than or equal to 16 hours, greater than or equal to 0.25 hour and less than or equal to 8 hours, greater than or equal to 0.25 hour and less than or equal to 4 hours, greater than or equal to 0.5 hour and less than or equal to 24 hours, greater than or equal to 0.5 hour and less than or equal to 16 hours, greater than or equal to 0.5 hour and less than or equal to 8 hours, greater than or equal to 0.5 hour and less than or equal to 4 hours, greater than or equal to 1 hour and less than or equal to 24 hours, greater than or equal to 1 hour and less than or equal to 16 hours, greater than or equal to 1 hour and less than or equal to 8 hours, greater than or equal to 1 hour and less than or equal to 4 hours, greater than or equal to 2 hours and less than or equal to 24 hours, greater than or equal to 2 hours and less than or equal to 16 hours, greater than or equal to 2 hours and less than or equal to 8 hours, or even greater than or equal to 2 hours and less than or equal to 4 hours, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the heat treatment may comprise ramping up to a heat treatment temperature at a heating rate and cooling down from the heat treatment temperature at a cooling rate. In embodiments, the selected heating rate and cooling rate may effect the color coordinates of the resultant colored glass articles.

In embodiments, the heating rate of the heat treatment may be greater than or equal to 2° C./min or even greater than or equal to 3° C./min. In embodiments, the heating rate of the heat treatment may be less than equal to 10° C./min, less than or equal to 7° C./min, or even less than or equal to 5° C./min. In embodiments, the heating rate of the heat treatment may be greater than or equal to 2° C./min and less than or equal to 10° C./min, greater than or equal to 2° C./min and less than or equal to 7° C./min, greater than or equal to 2° C./min and less than or equal to 5° C./min, greater than or equal to 3° C./min and less than or equal to 10° C./min, greater than or equal to 3° C./min and less than or equal to 7° C./min, or even greater than or equal to 3° C./min and less than or equal to 5° C./min, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the cooling rate of the heat treatment may be greater than or equal to 1° C./min or even greater than or equal to 2° C./min. In embodiments, the cooling rate of the heat treatment may be less than or equal to 10° C./min, less than or equal to 8° C./min, less than or equal to 6° C./min, or even less than or equal to 4° C./min. In embodiments, the cooling rate of the heat treatment may be greater than or equal to 1° C./min and less than or equal to 10° C./min, greater than or equal to 1° C./min and less than or equal to 8° C./min, greater than or equal to 1° C./min and less than or equal to 6° C./min, greater than or equal to 1° C./min and less than or equal to 4° C./min, greater than or equal to 2° C./min and less than or equal to 10° C./min, greater than or equal to 2° C./min and less than or equal to 8° C./min, greater than or equal to 2° C./min and less than or equal to 6° C./min, or even greater than or equal to 2° C./min and less than or equal to 4° C./min, or any and all sub-ranges formed from any of these endpoints.

For example and without limitation, in embodiments in which the glass composition comprises Ag, colored glass articles having an orange color may be formed by heat treating the precursor glass article at a heat treatment temperature from about 590° C. to about 610° C. for a heat treatment time from about 45 minutes to about 180 minutes.

For example and without limitation, in embodiments in which the glass composition comprises Ag, colored glass articles having a red color may be formed by heat treating the precursor glass article at a heat treatment temperature from about 600° C. to about 615° C. for a heat treatment time from about 180 minutes to about 300 minutes.

For example and without limitation, in embodiments in which the glass composition comprises Ag, colored glass articles having a green color may be formed by heat treating the precursor glass article at a heat treatment temperature from about 620° C. to about 640° C. for a heat treatment time from about 20 minutes to about 40 minutes.

For example and without limitation, in embodiments in which the glass composition comprises Ag, colored glass articles having a brown color may be formed by heat treating the precursor glass article at a heat treatment temperature from about 640° C. to about 660° C. for a heat treatment time from about 30 minutes to about 90 minutes.

For example and without limitation, in embodiments in which the glass composition comprises Ag, colored glass articles having a purple color may be formed by heat treating the precursor glass article at a heat treatment temperature from about 625° C. to about 650° C. for a heat treatment time from about 30 minutes to about 90 minutes.

While some embodiments of the glasses described herein require a heat treatment to impart color to the glass, it is noted that other embodiments of glasses described herein do not require a heat treatment to impart color to the glass. For example, some glasses containing transition metal oxides and/or rare earth oxides may not require a heat treatment to impart color to the glass. As such, it should be understood that the heat treatment is optional.

Following heat treatment (if required), the glasses described herein are colored and, as such, are referred to as colored glass articles. In embodiments, the colored glass articles are predominantly glass (i.e., predominantly non-crystalline), but may include particles (such as colorant particles) that have crystalline morphology. As such, the colored glass articles may include at least one crystalline phase. In embodiments, the crystalline phase may be, for example and without limitation, an Au crystalline phase and/or a Ag crystalline phase. However, it should be understood that other crystalline phases are possible and may be present as an alternative to an Au crystalline phase and/or an Ag crystalline phase or instead of an Au crystalline phase and/or an Ag crystalline phase. In embodiments, the crystallinity of the colored glass article is less than or equal to 10 wt. %, less than or equal to 9 wt. %, less than or equal to 8 wt. %, less than or equal to 7 wt. %, less than or equal to 6 wt. %, less than or equal to 5 wt. %, less than or equal to 4 wt. %, less than or equal to 3 wt. %, less than or equal to 2 wt. %, or even less than or equal to 1 wt. % by weight of the glass article.

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 96.5. In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of absolute value of a* (i.e., |a*|) greater than or equal to 0.3. In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of absolute value of b* (i.e., |b*|) greater than or equal to 0.5. In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of: L* greater than or equal to 20 and less than or equal to 96.5; absolute value of a* (i.e., |a*|) greater than or equal to 0.3; and absolute value of b* (i.e., |b*|) greater than or equal to 0.5. In these embodiments, L* may be greater than or equal to 25, greater than or equal to 30, greater than or equal to 35, greater than or equal to 40, greater than or equal to 45, greater than or equal to 50, or even greater than or equal to 55. As noted herein, unless otherwise specified, the transmittance color coordinates in the CIELAB color space are specified for article thicknesses of 0.4 to 5 mm (inclusive of endpoints) under F2 illumination and a 10° standard observer angle.

Without wishing to be bound by theory, it is believed that glasses having CIELAB color coordinates within the range of L* greater than or equal to 20 and less than or equal to 96.5 are transparent to wavelengths of visible light (i.e., wavelengths of light from 380 nm to 750 nm, inclusive of endpoints) rather than opaque. However, as the value of L* decreases, the color of the colored glass articles becomes more saturated and the glasses become more opaque (i.e., less transparent). As the value for L* increases, the color of the colored glass articles becomes less saturated and, when the L* value exceeds 96.5, the colored glass article may appear colorless.

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −5 and less than or equal to 25 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −20 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −10 and less than or equal to 25 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −20 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −18 and less than or equal to 0.3, and b* greater than or equal to 0.5 and less than or equal to 82.

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −18 and less than or equal to 18 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to 0.5 and less than or equal to 82.

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −20 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 85 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to −0.3, and b* greater than or equal to 0.5 and less than or equal to 82.

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to 20 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to 0.5 and less than or equal to 75.

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −15 and less than or equal to 65 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 80 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 80 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 80 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −11.12 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −20 and less than or equal to 120 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the transmitted color coordinates of the CIELAB color space may be described in terms of a range of L* values and a region of the a* (horizontal axis or x-axis) and b* (vertical axis or y-axis) color space. The region of the a* vs. b* color space may be defined by the intersection of a plurality of lines defined by a* and b*.

In embodiments, colored glass articles that appear yellow in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 90 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=0.2879·a*+27.818; b*=7.0833·a*−94.5; b*=0.45·a*+104.5; and b*=15.3·a*+253. This region is graphically depicted in FIG. 20 as the region being bound by lines A, B, C, and D.

In embodiments, colored glass articles that appear orange in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 90 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=7.0833·a*−94.5; b*=−0.9583·a*+146.75; b*=2.6957·a*−50.565; and b*=33. This region is graphically depicted in FIG. 20 as the region being bound by lines B, E, F and G.

In embodiments, colored glass articles that appear red in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 90 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=2.6957·a*−50.565; a*=54; b*=1.0769·a*−17.154; and b*=6.6667·a*−173.67. This region is graphically depicted in FIG. 20 as the region being bound by lines F, H, I and J.

In embodiments, colored glass articles that appear green in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 4 and less than or equal to 80 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=0.2879·a*+27.818; a*=0; b*=−1.375·a*+1; and b*=9.333·a*+86.667, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5. This region is graphically depicted in FIG. 20 as the region being bound by lines A, K, L, and M.

In embodiments, colored glass articles that appear pink/purple in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 10 and less than or equal to 80 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=0.0833·a*+20.833; b*=2.1182·a*−32.073; b*=−0.3; and b*=1.5929·a*−0.3, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5. This region is graphically depicted in FIG. 20 as the region being bound by lines N, O, P and Q.

In embodiments, colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −15 and less than or equal to −0.3, and b* greater than or equal to −10 and less than or equal to 10 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, colored glass articles may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 85 and less than or equal to 96.5, a* greater than or equal to −10 and less than −0.3, and b* greater than or equal to −5 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments of the colored glass articles described herein in which the colorant package includes Au, the concentrations of R₂O and Al₂O₃ may be adjusted such that the difference R₂O—Al₂O₃, in combination with Au, produces colored glass articles having the desired color (e.g., pink, purple, red, orange, etc.). In embodiments, the colored glass article may have a transmittance color coordinate in the CIELAB color space of: L* greater than or equal to 55 and less than or equal to 96.5; a* greater than or equal to −15 and less than or equal to 25; and b* greater than or equal to −25 and less than or equal to 25, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5.

In embodiments where the colorant package comprises Au, relatively smaller concentrations of R₂O—Al₂O₃ (e.g., less than or equal to 1.5 mol %) may result in a blue or purple glass article. Relatively higher concentrations of R₂O—Al₂O₃ (e.g., greater than 1.5 mol %) may result in an orange or red glass article.

For example, in embodiments in which the colorant package includes Au, R₂O—Al₂O₃ may be greater than or equal to −5 mol % and less than or equal to 1.5 mol % and b* may be greater than or equal to −25 and less than or equal to 10, exclusive of b* greater than −0.5 and less than 0.5. In embodiments, R₂O—Al₂O₃ may greater than or equal to −3 mol % and less than or equal to 1.5 mol % and b* may be greater than or equal to −15 and less than or equal to 7, exclusive of b* greater than −0.5 and less than 0.5. In embodiments, R₂O—Al₂O₃ may be greater than or equal to −5 mol % and less than or equal to 1.5 mol %, greater than or equal to −3 mol % and less than or equal to 1.5 mol %, greater than or equal to −1 mol % and less than or equal to 1.5 mol %, or even greater than or equal to 0 mol % and less than or equal to 1.5 mol %, or any and all sub-ranges formed from any of these endpoints; and b* may be greater than or equal to −25 and less than or equal to 10 (exclusive of b* greater than −0.5 and less than 0.5), greater than or equal to −25 and less than or equal to 7, greater than or equal to −25 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5), greater than or equal to −15 and less than or equal to 10 (exclusive of b* greater than −0.5 and less than 0.5), greater than or equal to −15 and less than or equal to 7 (exclusive of b* greater than −0.5 and less than 0.5), greater than or equal to −15 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5), greater than or equal to −10 and less than or equal to 10 (exclusive of b* greater than −0.5 and less than 0.5), greater than or equal to −10 and less than or equal to 7 (exclusive of b* greater than −0.5 and less than 0.5), or even greater than or equal to −10 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5), or any and all sub-ranges formed from any of these endpoints.

In embodiments in which the colorant package includes Au, R₂O—Al₂O₃ may be greater than 1.5 mol % and less than or equal to 7 mol % and b* may be greater than or equal to 0.5 and less than or equal to 25. In embodiments, R₂O—Al₂O₃ may be greater than 1.5 mol % and less than or equal to 5 mol % and b* may be greater than or equal to 0.5 and less than or equal to 15. In embodiments, R₂O—Al₂O₃ may be greater than 1.5 mol % and less than or equal to 7 mol %, greater than 1.5 mol % and less than or equal to 5 mol %, or even greater than 1.5 mol % and less than or equal to 3 mol %, or any and all sub-ranges formed from any of these endpoints; and b* may be greater than or equal to 0.5 and less than or equal to 25, greater than or equal to 0.5 and less than or equal to 15, greater than or equal to 0.5 and less than or equal to 10, greater than or equal to 2.5 and less than or equal to 25, greater than or equal to 2.5 and less than or equal to 15, greater than or equal to 2.5 and less than or equal to 10, greater than or equal to 5 and less than or equal to 25, greater than or equal to 5 and less than or equal to 15, or even greater than or equal to 5 and less than or equal to 10, or any and all sub-ranges formed from any of these endpoints.

In embodiments, the colored glass articles including Au as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −5 and less than or equal to 25 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −20 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles including Au as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −10 and less than or equal to 25 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −20 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles including Cr₂O₃ as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −18 and less than or equal to 0.3, and b* greater than or equal to 0.5 and less than or equal to 82.

In embodiments, the colored glass articles including Cr₂O₃ and NiO as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −18 and less than or equal to 18 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to 0.5 and less than or equal to 82.

In embodiments, the colored glass articles including Cr₂O₃ and Co₃O₄ as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −20 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 85 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles including Cr₂O₃ and CuO as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to −0.3, and b* greater than or equal to 0.5 and less than or equal to 82.

In embodiments, the colored glass articles including Cr₂O₃, NiO, and CuO as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to 20 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to 0.5 and less than or equal to 75.

In embodiments, the colored glass articles including Cr₂O₃, NiO, and Co₃O₄ as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −15 and less than or equal to 65 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 80 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles including Cr₂O₃, CuO, and Co₃O₄ as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 80 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles including Cr₂O₃, NiO, CuO, and Co₃O₄ as a colorant may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −35 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −90 and less than or equal to 80 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the colored glass articles including Ag as a colorant may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −11.12 and less than or equal to 60 (exclusive of a* greater than −0.3 and less than 0.3), and b* greater than or equal to −20 and less than or equal to 120 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, the transmitted color coordinates of the CIELAB color space may be described in terms of a range of L* values and a region of the a* (horizontal axis or x-axis) and b* (vertical axis or y-axis) color space. The region of the a* vs. b* color space may be defined by the intersection of a plurality of lines defined by a* and b*.

For example, in embodiments, colored glass articles comprising Ag as a colorant that appear yellow in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 90 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=0.2879·a*+27.818; b*=7.0833·a*−94.5; b*=0.45·a*+104.5; and b*=15.3·a*+253. This region is graphically depicted in FIG. 20 as the region being bound by lines A, B, C, and D.

In embodiments, colored glass articles comprising Ag as a colorant that appear orange in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 90 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=7.0833·a*−94.5; b*=−0.9583·a*+146.75; b*=2.6957·a*−50.565; and b*=33. This region is graphically depicted in FIG. 20 as the region being bound by lines B, E, F and G.

In embodiments, colored glass articles comprising Ag as a colorant that appear red in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 20 and less than or equal to 90 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=2.6957·a*−50.565; a*=54; b*=1.0769·a*−17.154; and b*=6.6667·a*−173.67. This region is graphically depicted in FIG. 20 as the region being bound by lines F, H, I and J.

In embodiments, colored glass articles comprising Ag as a colorant that appear green in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 4 and less than or equal to 80 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=0.2879·a*+27.818; a*=0; b*=−1.375·a*+1; and b*=9.333·a*+86.667, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5. This region is graphically depicted in FIG. 20 as the region being bound by lines A, K, L, and M.

In embodiments, colored glass articles comprising Ag as a colorant that appear pink/purple in color may have a transmitted color coordinate in the CIELAB color space of L* greater than or equal to 10 and less than or equal to 80 and a* and b* values within a region of the a* vs. b* color space bound by the intersection of the lines: b*=0.0833·a*+20.833; b*=2.1182·a*−32.073; b*=−0.3; and b*=1.5929·a*−0.3, exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5. This region is graphically depicted in FIG. 20 as the region being bound by lines N, O, P and Q.

In embodiments, colored glass articles that include a transition metal oxides and/or rare earth metal oxides as a colorant (such as NiO, CuO, TiO₂, Co₃O₄, Cr₂O₃, and/or CeO₂) may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −15 and less than or equal to −0.3, and b* greater than or equal to −10 and less than or equal to 10 (exclusive of b* greater than −0.5 and less than 0.5).

In embodiments, colored glass articles that include a transition metal oxides and/or rare earth metal oxides as a colorant (such as NiO, CuO, TiO₂, Co₃O₄, Cr₂O₃, and/or CeO₂) may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 85 and less than or equal to 96.5, a* greater than or equal to −10 and less than −0.3, and b* greater than or equal to −5 and less than or equal to 5 (exclusive of b* greater than −0.5 and less than 0.5).

In some embodiments, the colored glass articles have an average transmittance of greater than or equal to 10% and less than or equal to 92% of light over the wavelength range from 380 nm to 750 nm. As noted herein, unless otherwise specified, the average transmittance is indicated for article thicknesses of 0.4 to 5 mm, inclusive of endpoints. In embodiments, the colored glass articles have an average transmittance greater than or equal to 15% and less than or equal to 92% over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 20% and less than or equal to 92% for light over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 25% and less than or equal to 92% for light over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 30% and less than or equal to 92% for light over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 19% and less than or equal to 88% over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 15% and less than or equal to 88% over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 20% and less than or equal to 88% for light over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 25% and less than or equal to 88% for light over the wavelength range of 380 nm to 750 nm. In embodiments, the colored glass articles have an average transmittance greater than or equal to 30% and less than or equal to 88% for light over the wavelength range of 380 nm to 750 nm.

In embodiments, the colored glass articles described herein may have a dielectric constant Dk at 10 GHz of less than or equal to 6.4, such as less than or equal to 6.4 and greater than or equal to 5.6. In embodiments, the dielectric constant of the colored glass article may be less than or equal to 6.4 and greater than or equal to 5.7, less than or equal to 6.4 and greater than or equal to 5.8, less than or equal to 6.4 and greater than or equal to 5.9, less than or equal to 6.4 and greater than or equal to 6.0, less than or equal to 6.4 and greater than or equal to 6.2, less than or equal to 6.3 and greater than or equal to 5.6, less than or equal to 6.3 and greater than or equal to 5.7, less than or equal to 6.3 and greater than or equal to 5.8, less than or equal to 6.3 and greater than or equal to 5.9, less than or equal to 6.3 and greater than or equal to 6.0, less than or equal to 6.3 and greater than or equal to 6.2, less than or equal to 6.2 and greater than or equal to 5.7, less than or equal to 6.2 and greater than or equal to 5.8, less than or equal to 6.2 and greater than or equal to 5.9, less than or equal to 6.2 and greater than or equal to 6.0, or even less than or equal to 6.2 and greater than or equal to 6.1. As noted herein, while not wishing to be bound by theory, it is believed that the dielectric constant of the colored glass articles measured at 10 GHz approximates the dielectric constant at each frequency in the range from 10 GHz to 60 GHz. Accordingly, a dielectric constant reported for a colored glass article at a frequency of 10 GHz approximates the dielectric constant of the colored glass article at each frequency over the frequency range of 10 GHz to 60 GHz, inclusive of endpoints.

The colored glass articles formed from the glass compositions described herein may be any suitable thickness, which may vary depending on the particular application of the colored glass article. In embodiments, the colored glass articles may have a thickness greater than or equal to 200 μm and less than or equal to 6 mm, greater than or equal to 200 μm and less than or equal to 4 mm, greater than or equal to 200 μm and less than or equal to 2 mm, greater than or equal to 200 μm and less than or equal to 1 mm, greater than or equal to 200 μm and less than or equal to 750 μm, greater than or equal to 200 μm and less than or equal to 650 μm, greater than or equal to 200 μm and less than or equal to 600 μm, greater than or equal to 200 μm and less than or equal to 550 μm, greater than or equal to 200 μm and less than or equal to 500 μm, greater than or equal to 250 μm and less than or equal to 6 mm, greater than or equal to 250 μm and less than or equal to 4 mm, greater than or equal to 250 μm and less than or equal to 2 mm, greater than or equal to 250 μm and less than or equal to 1 mm, greater than or equal to 250 μm and less than or equal to 750 μm, greater than or equal to 250 μm and less than or equal to 650 μm, greater than or equal to 250 μm and less than or equal to 600 μm, greater than or equal to 250 μm and less than or equal to 550 μm, greater than or equal to 250 μm and less than or equal to 500 μm, greater than or equal to 300 μm and less than or equal to 6 mm, greater than or equal to 300 μm and less than or equal to 4 mm, greater than or equal to 300 μm and less than or equal to 2 mm, greater than or equal to 300 μm and less than or equal to 1 mm, greater than or equal to 300 μm and less than or equal to 750 μm, greater than or equal to 300 μm and less than or equal to 650 μm, greater than or equal to 300 μm and less than or equal to 600 μm, greater than or equal to 300 μm and less than or equal to 550 μm, greater than or equal to 300 μm and less than or equal to 500 μm, greater than or equal to 350 μm and less than or equal to 6 mm, greater than or equal to 350 μm and less than or equal to 4 mm, greater than or equal to 350 μm and less than or equal to 2 mm, greater than or equal to 350 μm and less than or equal to 1 mm, greater than or equal to 350 μm and less than or equal to 750 μm, greater than or equal to 350 μm and less than or equal to 650 μm, greater than or equal to 350 μm and less than or equal to 600 μm, greater than or equal to 350 μm and less than or equal to 550 μm, greater than or equal to 350 μm and less than or equal to 500 μm, greater than or equal to 400 μm and less than or equal to 6 mm, greater than or equal to 400 μm and less than or equal to 4 mm, greater than or equal to 400 μm and less than or equal to 2 mm, greater than or equal to 400 μm and less than or equal to 1 mm, greater than or equal to 400 μm and less than or equal to 750 μm, greater than or equal to 400 μm and less than or equal to 650 μm, greater than or equal to 400 μm and less than or equal to 600 μm, greater than or equal to 400 μm and less than or equal to 550 μm, greater than or equal to 400 μm and less than or equal to 500 μm, greater than or equal to 450 μm and less than or equal to 6 mm, greater than or equal to 450 μm and less than or equal to 4 mm, greater than or equal to 450 μm and less than or equal to 2 mm, greater than or equal to 450 μm and less than or equal to 1 mm, greater than or equal to 450 μm and less than or equal to 750 μm, greater than or equal to 450 μm and less than or equal to 650 μm, greater than or equal to 450 μm and less than or equal to 600 μm, greater than or equal to 450 μm and less than or equal to 550 μm, greater than or equal to 450 μm and less than or equal to 500 μm, greater than or equal to 500 μm and less than or equal to 6 mm, greater than or equal to 500 μm and less than or equal to 4 mm, greater than or equal to 500 μm and less than or equal to 2 mm, greater than or equal to 500 μm and less than or equal to 1 mm, greater than or equal to 500 μm and less than or equal to 750 μm, greater than or equal to 750 μm and less than or equal to 6 mm, greater than or equal to 750 μm and less than or equal to 4 mm, greater than or equal to 750 μm and less than or equal to 2 mm, greater than or equal to 750 μm and less than or equal to 1 mm, greater than or equal to 1 mm and less than or equal to 6 mm, greater than or equal to 1 mm and less than or equal to 4 mm, greater than or equal to 1 mm and less than or equal to 2 mm, greater than or equal to 2 mm and less than or equal to 6 mm, greater than or equal to 2 mm and less than or equal to 4 mm, or even greater than or equal to 4 mm and less than or equal to 6 mm, or any and all sub-ranges formed from any of these endpoints.

As discussed hereinabove, colored glass articles formed from the glass compositions described herein may have an increased fracture toughness such that the colored glass articles are more resistant to damage. In embodiments, the colored glass article may have a K_(IC) fracture toughness as measured by a CNSB method, prior to ion exchange, greater than or equal to 0.7 MPa·m^(1/2). In embodiments, the colored glass article may have a K_(IC) fracture toughness, prior to ion exchange as measured by a CNSB method greater than or equal to 0.7 MPa·m^(1/2), greater than or equal to 0.8 MPa·m^(1/2), greater than or equal to 0.9 MPa·m^(1/2), or even greater than or equal to 1.0 MPa·m^(1/2).

As discussed hereinabove, colored glass articles formed from the glass compositions described herein may have an increased fracture toughness such that the colored glass articles are more resistant to damage. In embodiments, the colored glass article may have a K_(IC) fracture toughness as measured by a DCB method, prior to ion exchange, greater than or equal to 0.7 MPa·m^(1/2). In embodiments, the colored glass article may have a K_(IC) fracture toughness, prior to ion exchange as measured by a DCB method greater than or equal to 0.7 MPa·m^(1/2), greater than or equal to 0.8 MPa·m^(1/2), greater than or equal to 0.9 MPa·m^(1/2), or even greater than or equal to 1.0 MPa·m^(1/2).

In embodiments, the glass compositions described herein are ion-exchangeable to facilitate strengthening the colored glass articles made from the glass compositions. In typical ion-exchange processes, smaller metal ions in the glass compositions are replaced or “exchanged” with larger metal ions of the same valence within a layer that is close to the outer surface of the colored glass article made from the glass composition. The replacement of smaller ions with larger ions creates a compressive stress within the layer of the colored glass article made from the glass composition. In embodiments, the metal ions are monovalent metal ions (e.g., Li⁺, Na⁺, K⁺, and the like), and ion-exchange is accomplished by immersing the glass article made from the glass composition in a bath comprising at least one molten salt of the larger metal ion that is to replace the smaller metal ion in the colored glass article. Alternatively, other monovalent ions such as Ag⁺, Tl⁺, Cu⁺, and the like may be exchanged for monovalent ions. The ion-exchange process or processes that are used to strengthen the colored glass article made from the glass composition may include contacting the colored glass article with an ion-exchange medium. In embodiments, the ion-exchange medium may be a molten salt bath. For example, the ion-exchange process may include, but is not limited to, immersion in a single bath or multiple baths of like or different compositions with optional washing and/or annealing steps between immersions.

Upon exposure to the colored glass article, the ion-exchange solution (e.g., KNO₃ and/or NaNO₃ molten salt bath) may, according to embodiments, be at a temperature greater than or equal to 350° C. and less than or equal to 500° C., greater than or equal to 360° C. and less than or equal to 450° C., greater than or equal to 370° C. and less than or equal to 440° C., greater than or equal to 360° C. and less than or equal to 420° C., greater than or equal to 370° C. and less than or equal to 400° C., greater than or equal to 375° C. and less than or equal to 475° C., greater than or equal to 400° C. and less than or equal to 500° C., greater than or equal to 410° C. and less than or equal to 490° C., greater than or equal to 420° C. and less than or equal to 480° C., greater than or equal to 430° C. and less than or equal to 470° C., or even greater than or equal to 440° C. and less than or equal to 460° C., or any and all sub-ranges between the foregoing values. In embodiments, the colored glass article may be exposed to the ion-exchange solution for a duration greater than or equal to 2 hours and less than or equal to 24 hours, greater than or equal to 2 hours and less than or equal to 12 hours, greater than or equal to 2 hours and less than or equal to 6 hours, greater than or equal to 8 hours and less than or equal to 24 hours, greater than or equal to 6 hours and less than or equal to 24 hours, greater than or equal to 6 hours and less than or equal to 12 hours, greater than or equal to 8 hours and less than or equal to 24 hours, or even greater than or equal to 8 hours and less than or equal to 12 hours, or any and all sub-ranges formed from any of these endpoints.

In embodiments, a colored glass article made from a glass composition may be ion-exchanged to achieve a depth of compression of 10 μm or greater, 20 μm or greater, 30 μm or greater, 40 μm or greater, 50 μm or greater, 60 μm or greater, 70 μm or greater, 80 μm or greater, 90 μm or greater, or 100 μm or greater. In embodiments, the colored glass article made from the glass composition may have a thickness “t” and may be ion-exchanged to achieve a depth of compression greater than or equal to 0.15t, greater than or equal to 0.17t, or even greater than or equal to 0.2t. In embodiments, the colored glass article made from the glass composition may have a thickness “t” and may be ion-exchanged to achieve a depth of compression less than or equal to 0.3t, less than or equal to 0.27t, or even less than or equal to 0.25t. In embodiments, the colored glass article made from the glass composition described herein may have a thickness “t” and may be ion-exchanged to achieve a depth of compression greater than or equal to 0.15t and less than or equal to 0.3t, greater than or equal to 0.15t and less than or equal to 0.27t, greater than or equal to 0.15t and less than or equal to 0.25t, greater than or equal to 0.17t and less than or equal to 0.3t, greater than or equal to 0.17t and less than or equal to 0.27t, greater than or equal to 0.17t and less than or equal to 0.25t, greater than or equal to 0.2t and less than or equal to 0.3t, greater than or equal to 0.2t and less than or equal to 0.27t, or even greater than or equal to 0.2t and less than or equal to 0.25t, or any and all sub-ranges formed from any of these endpoints.

The development of this surface compression layer is beneficial for achieving a better crack resistance and higher flexural strength compared to non-ion-exchanged materials. The surface compression layer has a higher concentration of the ions exchanged into the colored glass article in comparison to the concentration of the ions exchanged into the colored glass article for the body (i.e., the area not including the surface compression) of the colored glass article. In embodiments, the colored glass article made from the glass composition may have a surface compressive stress after ion-exchange strengthening greater than or equal to 300 MPa, greater than or equal to 400 MPa, greater than or equal to 500 MPa, or even greater than or equal to 600 MPa. In embodiments, the colored glass article made from the glass composition may have a surface compressive stress after ion-exchange strengthening less than or equal to 1 GPa, less than or equal to 900 MPa, or even less than or equal to 800 MPa. In embodiments, the colored glass article made from the glass composition may have a surface compressive stress after ion-exchange strengthening greater than or equal to 300 MPa and less than or equal to 1 GPa, greater than or equal to 300 MPa and less than or equal to 900 MPa, greater than or equal to 300 MPa and less than or equal to 800 MPa, greater than or equal to 400 MPa and less than or equal to 1 GPa, greater than or equal to 400 MPa and less than or equal to 900 MPa, greater than or equal to 400 MPa and less than or equal to 800 MPa, greater than or equal to 500 MPa and less than or equal to 1 GPa, greater than or equal to 500 MPa and less than or equal to 900 MPa, greater than or equal to 500 MPa and less than or equal to 800 MPa, greater than or equal to 600 MPa and less than or equal to 1 GPa, greater than or equal to 600 MPa and less than or equal to 900 MPa, greater than or equal to 600 MPa and less than or equal to 800 MPa.

In embodiments, the colored glass articles made from the glass composition may have a maximum central tension after ion-exchange strengthening greater than or equal to 40 MPa, greater than or equal to 60 MPa, greater than or equal to 80 MPa, or even greater than or equal to 100 MPa. In embodiments, the colored glass article made from the glass composition may have a maximum central tension after ion-exchange strengthening less than or equal to 250 MPa, less than or equal to 200 MPa, or even less than or equal to 150 MPa. In embodiments, the colored glass article made from the glass composition may have a maximum central tension after ion-exchange strengthening greater than or equal to 40 MPa and less than or equal to 250 MPa, greater than or equal to 40 MPa and less than or equal to 200 MPa, greater than or equal to 40 MPa and less than or equal to 150 MPa, greater than or equal to 60 MPa and less than or equal to 250 MPa, greater than or equal to 60 MPa and less than or equal to 200 MPa, greater than or equal to 60 MPa and less than or equal to 150 MPa, greater than or equal to 80 MPa and less than or equal to 250 MPa, greater than or equal to 80 MPa and less than or equal to 200 MPa, greater than or equal to 80 MPa and less than or equal to 150 MPa, greater than or equal to 100 MPa and less than or equal to 250 MPa, greater than or equal to 100 MPa and less than or equal to 200 MPa, or even greater than or equal to 100 MPa and less than or equal to 150 MPa, or any and all sub-ranges formed from any of these endpoints. As utilized herein, central tension refers to a maximum central tension value unless otherwise indicated.

As described herein, in embodiments, the glass compositions described herein may be formulated to increase the retention of Au, which increases the concentration of Au in the resultant colored glass articles, thereby expanding the color gamut achievable by the colored glass articles. In embodiments, a colored glass article having greater than or equal to 0.01 mol % and less than or equal to 1 mol % Au may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −5 and less than or equal to 25, exclusive of a* greater than −0.3 and less than 0.3, and b* greater than or equal to −20 and less than or equal to 5, exclusive of b* greater than −0.5 and less than 0.5. In embodiments, colored glass article having greater than or equal to 1×10⁻⁶ mol % and less than or equal to 1 mol % Au may have a transmittance color coordinate in the CIELAB color space of L* greater than or equal to 55 and less than or equal to 96.5, a* greater than or equal to −10 and less than or equal to 25 exclusive of a* greater than −0.3 and less than 0.3, and b* greater than or equal to −20 and less than or equal to 5 exclusive of b* greater than −0.5 and less than 0.5.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 60 mol % and less than or equal to 70 mol % SiO₂; greater than or equal to 11 mol % and less than or equal to 17 mol % Al₂O₃; greater than or equal to 2 mol % and less than or equal to 8 mol % B₂O₃; greater than or equal to 9 mol % and less than or equal to 14 mol % Li₂O; greater than or equal to 2 mol % and less than or equal to 6 mol % Na₂O; greater than or equal to 0.1 mol % and less than or equal to 2 mol % MgO; greater than or equal to 0.1 mol % and less than or equal to 2 mol % ZnO; and greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.01 mol % Au. In these embodiments, MgO+ZnO is greater than or equal to 0.1 mol % and less than or equal to 4.5 mol %.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 60 mol % and less than or equal to 70 mol % SiO₂; greater than or equal to 11 mol % and less than or equal to 17 mol % Al₂O₃; greater than or equal to 2 mol % and less than or equal to 8 mol % B₂O₃; greater than or equal to 9 mol % and less than or equal to 14 mol % Li₂O; greater than or equal to 2 mol % and less than or equal to 6 mol % Na₂O; greater than or equal to 0.1 mol % and less than or equal to 0.5 mol % K₂O; and greater than or equal to 1×10⁻⁶ mol % and less than or equal to 0.05 mol % Au. In these embodiments, R₂O—Al₂O₃ is greater than or equal to 0 mol % and less than or equal to 3 mol %, R₂O being the sum of Li₂O, Na₂O, and K₂O.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 40 mol % and less than or equal to 70 mol % SiO₂; greater than or equal to 8 mol % and less than or equal to 20 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 10 mol % B₂O₃; greater than or equal to 1 mol % and less than or equal to 20 mol % Li₂O; greater than or equal to 1 mol % and less than or equal to 15 mol % Na₂O; greater than or equal to 0 mol % and less than or equal to 8 mol % MgO; greater than or equal to 0 mol % and less than or equal to 5 mol % ZnO; and greater than or equal to 0.0005 mol % and less than or equal to 1 mol % Au, wherein: MgO+ZnO is greater than or equal to 0.1 mol % and less than or equal to 6 mol %.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 40 mol % and less than or equal to 70 mol % SiO₂; greater than or equal to 8 mol % and less than or equal to 20 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 10 mol % B₂O₃; greater than or equal to 1 mol % and less than or equal to 20 mol % Li₂O; greater than or equal to 1 mol % and less than or equal to 15 mol % Na₂O; greater than or equal to 0 mol % and less than or equal to 6 mol % MgO; greater than or equal to 0 mol % and less than or equal to 5 mol % ZnO; and greater than or equal to 1×10⁻⁶ mol % and less than or equal to 1 mol % Au, wherein: MgO+ZnO is greater than or equal to 0.1 mol % and less than or equal to 6 mol %.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 50 mol % and less than or equal to 80 mol % SiO₂; greater than or equal to 7 mol % and less than or equal to 25 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 15 mol % B₂O₃; greater than or equal to 5 mol % and less than or equal to 20 mol % Li₂O; greater than or equal to 0.5 mol % and less than or equal to 15 mol % Na₂O; greater than 0 mol % and less than or equal to 1 mol % K₂O; and greater than or equal to 1×10⁻⁶ mol % and less than or equal to 1 mol % Au, wherein: R₂O—Al₂O₃ is greater than or equal to −5 mol % and less than or equal to 7 mol %, R₂O being the sum of Li₂O, Na₂O, and K₂O.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 50 mol % and less than or equal to 70 mol % SiO₂; greater than or equal to 10 mol % and less than or equal to 17.5 mol % Al₂O₃; greater than or equal to 3 mol % and less than or equal to 10 mol % B₂O₃; greater than or equal to 8.8 mol % and less than or equal to 14 mol % Li₂O greater than or equal to 1.5 mol % and less than or equal to 8 mol % Na₂O; and greater than 0 mol % and less than or equal to 2 mol % Cr₂O₃, wherein: R₂O+R′O—Al₂O₃ is greater than or equal to 0.5 mol % and less than or equal to 6 mol %, wherein R₂O is the sum of Li₂O, Na₂O, and K₂O and R′O is the sum of MgO, ZnO, and CaO; and Al₂O₃+MgO+ZnO is greater than or equal to 12 mol % and less than or equal to 22 mol %.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 50 mol. % and less than or equal to 70 mol. % SiO₂; greater than or equal to 10 mol. % and less than or equal to 20 mol. % Al₂O₃; greater than or equal to 4 mol. % and less than or equal to 10 mol. % B₂O₃; greater than or equal to 7 mol. % and less than or equal to 17 mol. % Li₂O greater than or equal to 1 mol. % and less than or equal to 9 mol. % Na₂O; greater than or equal to 0.01 mol. % and less than or equal to 1 mol. % SnO₂; and greater than or equal to 0.01 mol. % and less than or equal to 5 mol. % Ag, wherein R₂O—Al₂O₃ is greater than 0.2 mol. % and less than or equal to 5.00 mol. % and R₂O is the sum of Li₂O, Na₂O, and K₂O.

In embodiments, the glass composition and the resultant colored glass article may comprise greater than or equal to 50 mol % and less than or equal to 70 mol % SiO₂; greater than or equal to 10 mol % and less than or equal to 20 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 10 mol % B₂O₃; greater than or equal to 7 mol % and less than or equal to 14 mol % Li₂O; greater than or equal to 0.01 mol % and less than or equal to 8 mol % Na₂O; greater than or equal to 0.01 mol % and less than or equal to 1 mol % K₂O; greater than or equal to 0 mol % and less than or equal to 7 mol % CaO; and greater than or equal to 0 mol % and less than or equal to 8 mol % MgO, wherein Li₂O+K₂O+Na₂O+CaO+MgO+ZnO is less than or equal to 25 mol % and at least one of: CuO+NiO+Co₃O₄+Cr₂O₃ is greater than or equal to 0.001 mol %, CeO₂ is greater than or equal to 0.1 mol %, and TiO₂ is greater than or equal to 0.1 mol %.

In embodiments, the colored glass articles may have an average CTE of less than about 85×10⁻⁷ C⁻¹, less than about 80×10⁻⁷ C⁻¹, less than about 75×10⁻⁷ C⁻¹, less than about 70×10⁻⁷ C⁻¹, less than about 65×10⁻⁷ C⁻¹, or even less than about 60×10⁻⁷ C⁻¹. These relatively low CTE values improve the survivability of the glass to thermal cycling or thermal stress conditions relative to articles with higher CTEs.

In embodiments, the colored glass articles described herein may generally have a strain point greater than or equal to about 400° C. and less than or equal to about 550° C.

In embodiments, the colored glass articles described herein may generally have an anneal point greater than or equal to about 450° C. and less than or equal to about 650° C.

In embodiments, the colored glass articles described herein may generally have a softening point greater than or equal to about 700° C. and less than or equal to about 900° C.

The colored glass articles described herein may be used for a variety of applications including, for example, for housings for consumer electronic devices; for architectural glass applications; for automotive or vehicular glass applications; or for commercial or household appliance applications. In embodiments, a consumer electronic device (e.g., smartphones, tablet computers, watches, personal computers, ultrabooks, televisions, and cameras), an architectural glass, and/or an automotive glass may comprise a colored glass article as described herein.

An example article incorporating any of the colored glass articles disclosed herein is shown in FIGS. 1 and 2 . Specifically, FIGS. 1 and 2 show a consumer electronic device 100 including a housing 102 having front 104, back 106, and side surfaces 108; electrical components (not shown) that are at least partially inside or entirely within the housing and including at least a controller, a memory, and a display 110 at or adjacent to the front surface of the housing; and a cover substrate 112 at or over the front surface of the housing such that it is over the display. In embodiments, at least a portion of housing 102, such as the back 106, may include any of the colored glass articles disclosed herein.

EXAMPLES

In order that various embodiments be more readily understood, reference is made to the following examples, which illustrate various embodiments of the colored glass articles described herein.

Heat Treatment—The heat treatment of the Examples below included placing the glass articles between a SiC setter, placing the glass articles in an oven and heating the oven to the indicated heat treatment temperature at a rate of 4° C./min, and cooling from the heat treatment temperature after the heat treatment time had lapsed at a cooling rate of 3° C./min.

Table 1 shows comparative examples Comp. 1 and Comp. 2 and examples 1-30, with the batch compositions utilized to form each example reported (in terms of mol %). Table 1 also reports the heat treatment used to produce colored glass articles from the batch compositions and the analyzed Au concentration (in terms of mol %) of the resultant colored glass articles.

TABLE 1 Example 1 2 3 Comp. 1 Comp. 2 4 SiO₂ 58.8 58.8 58.8 58.5 58.5 58.5 Al₂O₃ 16.5 16.5 16.5 16.5 16.5 16.5 B₂O₃ 6.0 6.0 6.0 6.0 6.0 6.0 Li₂O 10.0 10.0 10.0 12.0 12.0 10.0 Na₂O 4.5 4.5 4.5 6.5 6.5 4.5 K₂O 0.2 0.2 0.2 0.5 0.5 0.5 MgO 3.0 3.0 3.0 — — 3.0 ZnO 1.0 1.0 1.0 — — 1.0 ZrO₂ — — — — — — P₂O₅ — — — — — — SnO₂ — — — — — — Fe₂O₃ — — — — — — Au 0.005 0.005 0.005 0.010 0.020 0.010 R₂O 14.7 14.7 14.7 19.0 19.0 15.0 MgO + ZnO 4.0 4.0 4.0 0.0 0.0 4.0 R₂O − Al₂O₃ −1.8 −1.8 −1.8 2.5 2.5 −1.5 5.72*Al₂O₃ − −546.7 −546.7 −546.7 −585.9 −585.9 −552.2 21.4*ZnO − 2.5*P205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO HEAT TREATMENT Melting temperature 1550 1500 1450 1450 1450 1450 (° C.) Melting time (hours) 18 18 18 18 18 18 Analyzed Au (mol %) 0.0009 0.0017 0.0018 0.0013 0.0023 0.0030 % of Au retained 18.0 34.0 36.0 13.0 11.5 30.0 Example 5 6 7 8 9 10 SiO₂ 58.5 60.7 60.7 60.7 60.7 60.7 Al₂O₃ 16.5 14.5 14.5 14.5 14.5 14.5 B₂O₃ 6.0 6.0 6.0 6.0 6.0 6.0 Li₂O 10.0 10.0 10.0 10.0 10.0 10.0 Na₂O 4.5 4.5 4.5 4.5 4.5 4.5 K₂O 0.5 0.5 0.5 0.5 0.5 0.2 MgO 3.0 3.0 3.0 3.0 3.0 3.0 ZnO 1.0 1.0 1.0 1.0 1.0 1.0 ZrO₂ — — 0.5 — 0.5 0.5 P₂O₅ — — — 1.0 1.0 — SnO₂ — 0.10 0.10 0.10 0.10 0.05 Fe₂O₃ — — — — — — Au 0.020 0.005 0.005 0.005 0.005 0.005 R₂O 15.0 15.0 15.0 15.0 15.0 14.7 MgO + ZnO 4.0 4.0 4.0 4.0 4.0 4.0 R₂O − Al₂O₃ −1.5 0.5 0.5 0.5 0.5 0.2 5.72*Al₂O₃ − −552.2 −563.7 −563.7 −566.2 −566.2 −558.1 21.4*ZnO − 2.5*P205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO HEAT TREATMENT Melting temperature 1450 1550 1550 1550 1550 1550 (° C.) Melting time (hours) 18 18 18 18 18 18 Analyzed Au (mol %) 0.0043 0.0013 0.0018 0.0006 0.0007 0.0019 % of Au retained 21.5 26.0 36.0 12.0 14.0 38.0 Example 11 12 13 14 15 16 SiO₂ 60.7 60.7 60.7 61.8 61.8 61.8 Al₂O₃ 14.5 14.5 14.5 14.5 14.5 14.5 B₂O₃ 6.0 6.0 6.0 6.0 6.0 6.0 Li₂O 10.0 10.0 10.0 6.5 6.5 6.5 Na₂O 4.5 4.5 4.5 8.0 8.0 8.0 K₂O 0.2 0.2 0.2 0.2 0.2 0.2 MgO 3.0 3.0 3.0 2.0 2.0 2.0 ZnO 1.0 1.0 1.0 1.0 1.0 1.0 ZrO₂ 0.2 0.3 0.5 — — 0.2 P₂O₅ — — — — — — SnO₂ 0.01 0.03 0.05 — 0.05 0.05 Fe₂O₃ — — — — — — Au 0.005 0.005 0.005 0.005 0.005 0.005 R₂O 14.7 14.7 14.7 14.7 14.7 14.7 MgO + ZnO 4.0 4.0 4.0 3.0 3.0 3.0 R₂O − Al₂O₃ 0.2 0.2 0.2 0.2 0.2 0.2 5.72*Al₂O₃ − −558.1 −558.1 −558.1 −496.7 −496.7 −496.7 21.4*ZnO − 2.5*P205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO HEAT TREATMENT Melting temperature 1550 1550 1550 1500 1500 1500 (° C.) Melting time (hours) 18 18 18 18 18 18 Analyzed Au (mol %) 0.0013 0.0016 0.0017 0.0009 0.0010 0.0012 % of Au retained 26.0 32.0 34.0 18.0% 20.0% 24.0% Example 17 18 19 20 21 22 SiO₂ 61.8 61.8 61.8 60.8 60.8 60.8 Al₂O₃ 14.5 14.5 14.5 15.5 15.5 15.5 B₂O₃ 6.0 6.0 6.0 6.0 6.0 6.0 Li₂O 6.5 6.5 6.5 6.5 6.5 6.5 Na₂O 8.0 8.0 8.0 8.0 8.0 8.0 K₂O 0.2 0.2 0.2 0.2 0.2 0.2 MgO 2.0 2.0 2.0 2.0 2.0 2.0 ZnO 1.0 1.0 1.0 1.0 1.0 1.0 ZrO₂ — — 0.2 — — 0.2 P₂O₅ — — — — — — SnO₂ — 0.05 0.05 — 0.05 0.05 Fe₂O₃ — — — — — — Au 0.005 0.005 0.005 0.005 0.005 0.005 R₂O 14.7 14.7 14.7 14.7 14.7 14.7 MgO + ZnO 3.0 3.0 3.0 3.0 3.0 3.0 R₂O − Al₂O₃ 0.2 0.2 0.2 −0.8 −0.8 −0.8 5.72*Al₂O₃ − −496.7 −496.7 −496.7 −490.9 −490.9 −490.9 21.4*ZnO − 2.5*P205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO HEAT TREATMENT Melting temperature 1500 1500 1500 1500 1500 1500 (° C.) Melting time (hours) 18 18 18 18 18 18 Analyzed Au (mol %) 0.0010 0.0011 0.0014 0.0012 0.0012 0.0012 % of Au retained 20.0% 22.0% 28.0% 24.0% 24.0% 24.0% Example 23 24 25 26 27 28 SiO₂ 61.2 61.2 60.7 60.7 60.7 60.7 Al₂O₃ 14.5 14.5 14.5 14.5 14.5 14.5 B₂O₃ 6.0 6.0 6.0 6.0 6.0 6.0 Li₂O 6.5 6.5 8.0 9.0 9.0 9.0 Na₂O 8.0 8.0 4.5 4.5 4.5 4.5 K₂O 0.8 0.8 0.2 0.2 0.2 0.2 MgO 2.0 2.0 4.0 4.0 3.0 4.0 ZnO 1.0 1.0 2.0 1.0 2.0 1.0 ZrO₂ — — — — — — P₂O₅ — — — — — — SnO₂ 0.10 0.10 0.05 0.05 0.05 0.05 Fe₂O₃ 0.05 0.05 0.10 0.05 0.05 0.10 Au 0.005 0.005 0.005 0.005 0.005 0.005 R₂O 15.3 15.3 12.7 13.7 13.7 13.7 MgO + ZnO 3.0 3.0 6.0 5.0 5.0 5.0 R₂O − Al₂O₃ 0.8 0.8 −1.8 −0.8 −0.8 −0.8 5.72*Al₂O₃ − −506.8 −506.8 −530.0 −543.6 −544.5 −543.6 21.4*ZnO − 2.5*P205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO HEAT TREATMENT Melting temperature 1500 1500 1500 1500 1500 1500 (° C.) Melting time (hours) 16 16 18 18 18 18 Analyzed Au (mol %) 0.0016 0.0017 0.0005 0.0009 0.0005 0.0006 % of Au retained 32.0% 34.0% 10.0% 18.0% 10.0% 12.0% Example 29 30 SiO₂ 61.2 61.2 Al₂O₃ 14.5 14.5 B₂O₃ 6.0 6.0 Li₂O 6.5 6.5 Na₂O 8.0 8.0 K₂O 0.8 0.8 MgO 2.0 2.0 ZnO 1.0 1.0 ZrO₂ — — P₂O₅ — — SnO₂ 0.10 0.10 Fe₂O₃ 0.05 0.05 Au 0.005 0.005 R₂O 15.3 15.3 MgO + ZnO 3.0 3.0 R₂O − Al₂O₃ −0.8 −0.8 5.72*Al₂O₃ − −544.5 −544.5 21.4*ZnO − 2.5*P205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO HEAT TREATMENT Melting temperature 1500 1500 (° C.) Melting time (hours) 18 18 Analyzed Au (mol %) 0.0006 0.0013 % of Au retained 12.0% 26.0%

Referring to Table 1, Examples 1-3 were formed from the same glass composition, but melted at different temperatures. Example 1, which was melted at 1550° C., had an Au retention of 18.0%. Examples 2 and 3, which were melted at 1500° C. and 1450° C., respectively, had Au retentions of 34.0% and 36.0%, respectively. As indicated by Examples 1-3, a lower melting temperature favors Au retention. Therefore, it may be desirable to form a glass composition having a lower melting point such that Au retention during processing may be improved.

Comparative Examples Comp. 1 and Comp. 2 had an Au retention of 13.0% and 11.5%, respectively, after being melted at 1450° C. for 18 hours. Examples 4 and 5, which were similar to Comparative Examples Comp. 1 and Comp. 2, respectively, but included MgO and ZnO, had Au retentions of 30.0% and 21.5%, respectively, after being melted at 1450° C. for 18 hours. As indicated by Comparative Examples Comp. 1 and Comp. 2 and Examples 4 and 5, including MgO and ZnO in the glass composition improves Au retention of the resultant colored glass article.

Example 6 had an Au retention of 26.0% after being melted at 1550° C. for 18 hours. Example 7, which was similar to Example 3 but included ZrO₂, had an Au retention of 36.0% after being melted at 1550° C. for 18 hours. As indicated by Examples 6 and 7, including ZrO₂ in addition to MgO and ZnO in the glass composition improves Au retention of the resultant colored glass article.

Examples 8 and 9, which were similar to Examples 6 and 7, respectively, but included P₂O₅, had lower Au retentions of 12.0% and 14.0%, respectively, after being melted at 1550° C. for 18 hours. As indicated by Examples 6-9, including P₂O₅ in the glass composition impairs Au retention of the resultant colored glass article.

Examples 10-13, which included ZrO₂ and SnO₂, had relatively higher Au retentions of 38.0%, 26.0%, 32.0%, and 34%, respectively, after being melted at 1550° C. for 18 hours. As indicated by Examples 10-13, including SnO₂ in addition to MgO, ZnO, and ZrO₂ in the glass compositions improves Au retention of the resultant colored glass article.

Examples 14 and 17 had an Au retention of 18.0% and 20.0%, respectively, after being melted at 1550° C. for 18 hours. Examples 15 and 18, which were similar to Examples 14 and 17, but included SnO₂, had an Au retention of 20.0% and 22%, respectively, after being melted at 1550° C. for 18 hours. As indicated by Examples 15 and 18, including SnO₂ in addition to MgO and ZnO in the glass composition improves Au retention of the resultant colored glass article.

Examples 16 and 19, which included ZrO₂ and SnO₂, had relatively higher Au retentions of 24.0% and 28.0%, respectively, after being melted at 1550° C. for 18 hours. As indicated by Examples 16 and 19, including SnO₂ in addition to MgO, ZnO, and ZrO₂ in the glass compositions improves Au retention of the resultant colored glass article.

Examples 23 and 24, which included Fe₂O₃, had relatively higher Au retentions of 32.0% and 34.0%, respectively, after being melted at 1550° C. for 18 hours. As indicated by Examples 23 and 24, including Fe₂O₃ in addition to MgO, ZnO, and ZrO₂ in the glass compositions improves Au retention of the resultant colored glass article.

Referring now to FIGS. 3A-3C, 4A-4C, 5A-5C, and 6A-6C, a gradient-temperature approach was used to identify the heat treatment cycle parameters (i.e., temperature and duration) to achieve the desired color coordinates. Specifically, a 12 cm long and 1.5 mm thick sample formed from the glass composition of Example 11 was placed in a gradient-temperature oven and held at a heat treatment temperature, which varied along the length of the sample, for the prescribed duration. The sample was then rapidly cooled to quench the sample and the precipitated Au particles therein. Optical transmission spectra were then measured every 2 mm along the direction of the gradient. The coordinates in the CIELAB color space were plotted, as measured under F2 illumination and a 10° standard observer angle, in which the heat treatment temperature moved through the color space with separate plots for the four different heat treatment durations: 0.25 hour (FIGS. 3A-3C), 0.5 hour (FIGS. 4A-4C), 1 hour (FIGS. 5A-5C), and 1.5 hour (FIGS. 6A-6C). As indicated by FIGS. 3A-3C, 4A-4C, 5A-5C, and 6A-6C, different heat treatment temperatures and durations may be used to achieve the desired color.

Note that, as described herein, processing of the glass compositions to produce the resultant colored glass articles may occur in an isothermal oven. However, a gradient-temperature oven was used in these examples to investigate a range of temperatures simultaneously. A gradient-temperature oven produces similar results as an isothermal oven at the desired temperature.

Table 2 shows examples 31-65, with the analyzed concentration (in terms of mol %) of the resultant colored glass articles.

TABLE 2 Example 31 32 33 34 35 36 SiO₂ 61.09 61.03 61.08 60.99 60.87 60.73 Al₂O₃ 14.51 14.50 14.51 14.49 14.44 14.58 B₂O₃ 6.00 6.00 5.86 5.93 5.91 5.94 Li₂O 9.94 9.94 10.07 10.10 10.01 10.10 Na₂O 4.30 4.33 4.28 4.28 4.25 4.31 K₂O 0.19 0.19 0.19 0.19 0.45 0.19 MgO 2.89 2.90 2.89 2.89 2.89 2.93 ZnO 1.00 1.00 0.99 0.99 0.99 1.05 ZrO₂ 0.22 0.30 0.45 0.50 0.03 0.00 P₂O₅ — — — — — — SnO₂ 0.02 0.03 0.05 0.07 0.11 0.11 Fe₂O₃ 0.02 0.02 0.02 0.02 0.02 0.00 Au 0.0013 0.0015 0.0017 0.0019 0.0013 0.0009 R₂O 14.43 14.46 14.54 14.57 14.71 14.60 MgO + ZnO 3.89 3.90 3.88 3.88 3.88 3.98 R₂O − Al₂O₃ −0.08 −0.04 0.03 0.08 0.27 0.02 5.72*Al₂O₃ − −548.9 −549.8 −550.4 −552.7 −553.6 −555.2 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Example 37 38 39 40 41 42 SiO₂ 61.26 60.71 59.87 60.15 59.28 61.36 Al₂O₃ 14.38 14.65 14.86 15.43 15.07 15.72 B₂O₃ 5.89 5.95 5.95 5.88 5.70 6.00 Li₂O 10.00 10.05 10.14 10.01 9.80 10.21 Na₂O 4.28 4.30 4.31 4.27 6.03 4.34 K₂O 0.19 0.19 0.19 0.19 0.18 0.20 MgO 2.86 2.93 3.11 2.89 2.80 0.97 ZnO 1.01 1.06 1.09 1.02 0.99 1.05 ZrO₂ 0.00 0.00 0.32 0.00 0.00 0.00 P₂O₅ — — — — — — SnO₂ 0.06 0.05 0.05 0.11 0.10 0.11 Fe₂O₃ 0.00 0.07 0.07 0.00 0.00 0.00 Au 0.0007 0.0005 0.0007 0.0008 0.0005 0.0010 R₂O 14.47 14.54 14.64 14.47 16.01 14.75 MgO + ZnO 3.87 3.99 4.20 3.91 3.79 2.02 R₂O − Al₂O₃ 0.09 −0.11 −0.22 −0.96 0.94 −0.97 5.72*Al₂O₃ − −549.0 −553.2 −559.7 −543.8 −573.8 −514.2 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Example 43 44 45 46 47 48 SiO₂ 60.94 59.36 60.40 60.59 60.56 60.64 Al₂O₃ 16.51 16.42 15.52 15.32 15.23 15.08 B₂O₃ 5.89 5.78 6.05 6.04 6.04 6.01 Li₂O 10.05 9.90 10.66 10.65 10.63 10.74 Na₂O 4.27 4.22 4.77 4.79 4.89 4.90 K₂O 0.19 0.19 0.19 0.19 0.20 0.20 MgO 0.97 2.94 0.97 0.97 0.98 0.97 ZnO 1.03 1.03 1.02 1.02 1.05 1.05 ZrO₂ 0.00 0.00 0.31 0.32 0.31 0.32 P₂O₅ — — — — — — SnO₂ 0.10 0.11 0.05 0.06 0.06 0.05 Fe₂O₃ — — — — — — Au 0.0010 0.0006 0.0008 0.0008 0.0008 0.0007 R₂O 14.51 14.31 15.62 15.63 15.72 15.84 MgO + ZnO 2.00 3.97 1.99 1.99 2.03 2.02 R₂O − Al₂O₃ −2.00 −2.11 0.10 0.31 0.49 0.76 5.72*Al₂O₃ − −500.0 −532.7 −541.1 −542.2 −545.4 −549.6 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Example 49 50 51 52 53 54 SiO₂ 60.94 59.36 60.40 60.59 62.14 62.08 Al₂O₃ 16.51 16.42 15.52 15.32 14.95 14.98 B₂O₃ 5.89 5.78 6.05 6.04 6.06 5.93 Li₂O 10.05 9.90 10.66 10.65 10.51 10.69 Na₂O 4.27 4.22 4.77 4.79 4.29 4.31 K₂O 0.19 0.19 0.19 0.19 0.14 0.14 MgO 0.97 2.94 0.97 0.97 0.50 0.50 ZnO 1.03 1.03 1.02 1.02 1.03 1.00 ZrO₂ 0.00 0.00 0.31 0.32 0.29 0.29 P₂O₅ — — — — — — SnO₂ 0.10 0.11 0.05 0.06 0.04 0.04 Fe₂O₃ — — — — 0.04 0.04 Au 0.0008 0.0010 0.0012 0.0015 0.0014 0.0011 R₂O 14.51 14.31 15.62 15.63 14.94 15.14 MgO + ZnO 2.00 3.97 1.99 1.99 1.54 1.51 R₂O − Al₂O₃ −2.00 −2.11 0.10 0.31 −0.01 0.16 5.72*Al₂O₃ − −556.1 −558.4 −557.7 −558.9 −517.8 −521.6 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Example 55 56 57 58 59 60 SiO₂ 62.06 61.95 61.95 61.67 61.01 60.66 Al₂O₃ 14.92 14.87 14.88 14.88 14.96 15.03 B₂O₃ 5.92 5.91 5.92 5.93 6.04 6.06 Li₂O 10.86 11.03 11.04 11.06 11.18 11.21 Na₂O 4.25 4.24 4.24 4.25 4.26 4.28 K₂O 0.14 0.14 0.14 0.14 0.14 0.14 MgO 0.50 0.50 0.49 0.50 0.50 0.50 ZnO 1.01 1.02 1.01 1.02 1.03 1.03 ZrO₂ 0.28 0.28 0.28 0.28 0.28 0.28 P₂O₅ — — — 0.21 0.56 0.76 SnO₂ 0.04 0.04 0.04 0.04 0.04 0.04 Fe₂O₃ 0.02 0.01 — — — — Au 0.0010 0.0010 0.0011 0.0010 0.0010 0.0010 R₂O 15.25 15.41 15.42 15.46 15.58 15.63 MgO + ZnO 1.51 1.52 1.50 1.52 1.53 1.54 R₂O − Al₂O₃ 0.33 0.54 0.55 0.58 0.62 0.60 5.72*Al₂O₃ − −526.5 −532.6 −532.8 −534.9 −541.5 −543.7 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Example 61 62 63 64 65 SiO₂ 60.51 60.49 60.80 60.94 61.47 Al₂O₃ 15.06 15.02 14.76 14.61 14.60 B₂O₃ 6.06 6.07 6.05 5.97 5.91 Li₂O 11.21 11.22 11.20 11.17 11.12 Na₂O 4.30 4.30 4.29 4.29 4.27 K₂O 0.14 0.14 0.14 0.15 0.15 MgO 0.51 0.51 0.51 0.51 0.50 ZnO 1.03 1.04 1.03 1.03 1.04 ZrO₂ 0.28 0.28 0.28 0.48 0.50 P₂O₅ 0.86 0.89 0.90 0.81 0.40 SnO₂ 0.04 0.04 0.04 0.04 0.04 Fe₂O₃ — — — — — Au 0.0009 0.0010 0.0009 0.0011 0.0010 R₂O 15.65 15.67 15.63 15.61 15.53 MgO + ZnO 1.54 1.54 1.53 1.54 1.54 R₂O − Al₂O₃ 0.59 0.65 0.87 1.00 0.93 5.72*Al₂O₃ − −544.2 −545.2 −545.1 −543.6 −539.3 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO

Referring now to Table 3, example glass articles 31-35 having the concentrations shown in Table 2 were subjected to isothermal heat treatment between 600° C. and 660° C. The observable colors of the resultant colored glass articles are shown in Table 3. Heat treating example glass articles 31, 32, and 33 having an analyzed R₂O—Al₂O₃ of −0.08 mol %, −0.04 mol %, and 0.03 mol %, respectively, resulted in observably pink, purple, and red colored glass articles. Heat treating example glass articles 34 and 35, having an analyzed R₂O—Al₂O₃ of 0.08 mol % and 0.27 mol %, respectively, resulted in observably red and orange colored glass articles. As indicated by Tables 2 and 3, the analyzed R₂O—Al₂O₃ of a glass article may be adjusted and the glass article may be subjected to a certain heat treatment to provide a desired colored glass article.

TABLE 3 Example 31 32 33 34 35 Observable colors pink, pink, pink, pink, orange, purple purple purple red, red purple

Referring now to Table 4, example glass articles 36-48 having the analyzed concentrations shown in Table 2 were subjected to heat treatment at the temperature and for the period of time shown in Table 4. The observable colors of the resultant colored glass articles are shown in Table 4.

TABLE 4 550° 575° 600° 625° 650° Heat C. for C. for C. for C. for C. for treatment 2 hrs. 2 hrs. 2 hrs. 2 hrs. 2 hrs. 36 purple purple purple purple — 37 clear, purple purple red — purple 38 pink pink pink pink — 39 red red red red — 40 clear, purple purple purple — purple 41 orange orange orange orange — 42 clear, purple purple purple — purple 43 clear clear purple purple — 44 clear clear purple purple — 45 purple purple purple red red 46 clear, purple purple red red purple 47 purple purple red red red 48 purple purple red red red

Example glass article 41, having an analyzed R₂O—Al₂O₃ of 0.94 mol %, was the only glass article to result in an observably orange colored glass article after heat treatment. Example glass articles 36-40 and 42-48 had an R₂O—Al₂O₃ of 0.76 mol % or less. Heat treating glass article 38, including Fe₂O₃, resulted in an observably pink colored glass article. Heat treating glass articles 39 and 45-48, including ZrO₂, resulted in red colored glass articles. As indicated by Tables 2 and 4, the analyzed R₂O—Al₂O₃ may be adjusted, additional components may be added to the glass composition, and the glass article may be subjected to a certain heat treatment to provide a desired colored glass article.

Table 5 shows examples 66-75, with the analyzed concentration (in terms of mol %) of the resultant colored glass articles.

TABLE 5 Example 66 67 68 69 70 71 SiO₂ 62.15 62.27 62.22 62.19 62.08 61.95 Al₂O₃ 14.93 14.97 14.90 14.95 14.98 14.87 B₂O₃ 6.09 5.98 6.03 6.03 5.93 5.91 Li₂O 10.50 10.45 10.53 10.50 10.69 11.03 Na₂O 4.30 4.30 4.28 4.27 4.31 4.24 K₂O 0.14 0.14 0.14 0.14 0.14 0.14 MgO 0.50 0.50 0.50 0.50 0.50 0.50 ZnO 1.03 1.00 1.03 1.04 1.00 1.02 ZrO₂ 0.28 0.29 0.28 0.29 0.29 0.28 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.04 0.04 0.04 0.04 0.04 0.04 Fe₂O₃ 0.04 0.04 0.04 0.04 0.04 0.01 Au 6.0 × 10⁻⁶ 9.0 × 10⁻⁶ 1.2 × 10⁻⁵ 1.1 × 10⁻⁵ 8.0 × 10⁻⁶ 1.0 × 10⁻⁵ R₂O 14.94 14.89 14.95 14.91 15.14 15.41 MgO + ZnO 1.53 1.50 1.53 1.54 1.50 1.52 R₂O − Al₂O₃ 0.01 −0.08 0.05 −0.04 0.16 0.54 5.72*Al₂O₃ − −518.27 −513.82 −518.03 −516.67 −521.57 −532.56 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Example 72 73 74 75 SiO₂ 61.67 61.47 62.75 61.67 Al₂O₃ 14.88 14.60 14.47 14.88 B₂O₃ 5.93 5.91 5.88 5.93 Li₂O 11.06 11.12 11.07 11.06 Na₂O 4.25 4.27 4.27 4.25 K₂O 0.14 0.15 0.15 0.14 MgO 0.50 0.50 0.29 0.50 ZnO 1.02 1.04 0.47 1.02 ZrO₂ 0.28 0.50 0.52 0.28 P₂O₅ 0.21 0.40 0.08 0.21 SnO₂ 0.04 0.04 0.04 0.04 Fe₂O₃ 0.00 0.00 0.00 0.00 Au 8.3 × 10⁻⁶ 8.3 × 10⁻⁶ 8.3 × 10⁻⁶ 8.3 × 10⁻⁶ R₂O 15.45 15.54 15.49 15.45 MgO + ZnO 1.52 1.54 0.76 1.52 R₂O − Al₂O₃ 0.57 0.94 1.02 0.57 5.72*Al₂O₃ − −534.64 −539.57 −520.76 −534.64 21.4*ZnO − 2.5*1'205 − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO

Referring now to Table 6, example glass articles 66 and 68-75 having the analyzed concentrations shown in Table 5 were subjected to heat treatment at the temperature and for the period of time shown in Table 6. The observable colors of the resultant colored glass articles are shown in Table 6.

TABLE 6 Heat 550° C. for 575° C. for 600° C. for 625° C. for 650° C. for 550° C. for 575° C. for treatment 2 hrs. 2 hrs. 2 hrs. 2 hrs. 2 hrs. 8 hrs. 8 hrs. 66 — blue blue blue — — — 68 — blue blue red — — — 69 — purple purple red — — — 70 red purple blue blue — — — 71 clear, blue blue purple — — — purple 72 clear, purple purple purple — — — purple 73 clear, purple purple purple — — — purple 74 clear, purple purple red red red red purple 75 — — purple red red purple red

Example glass articles 71-75, having an analyzed R₂O—Al₂O₃ of greater than or equal to 0.54 mol %, had a relatively limited achievable color gamut after being subjected to different heat treatments. As indicated by Table 6, a relatively increased R₂O—Al₂O₃ may limit the achievable color gamut of the colored glass article.

Referring now to Table 7, example glass article 66 having the analyzed concentrations shown in Table 5 and the thicknesses shown in Table 7 were subjected to heat treatment at the temperature and for the period of time shown in Table 7. The transmittance color coordinate in the CIELAB color space, as measured at the indicated article thickness under F2 illumination and a 10° standard observer angle, and the observable color of the resultant colored glass articles are shown in Table 7.

TABLE 7 525° C. for 535° C. for 535° C. for 545° C. for 575° C. for Thickness 6 hrs. 6 hrs. 10 hrs. 10 hrs. 2 hrs. L* 96.39 95.09 92.01 91.06 92.75 a* 0.15 1.68 4.21 2.53 −0.60 b* 0.27 −0.12 −2.12 −3.64 −2.62 Observable color clear pink pink purple blue 1.33 mm L* 96.14 94.18 86.80 84.96 87.95 a* 0.31 2.60 8.81 3.50 −1.67 b* 0.42 −0.09 −4.55 −7.99 −5.86 Observable color clear pink pink purple blue 2.06 mm L* 95.69 90.65 83.19 78.95 83.25 a* 0.55 6.37 13.52 6.58 −3.01 b* 0.63 −0.97 −4.53 −11.46 −8.40 Observable color clear pink pink purple blue 600° C. for 625° C. for Thickness 2 hrs. 2 hrs.  0.6 mm L* 93.60 92.21 a* −0.61 −0.12 b* −0.60 −1.91 Observable color blue blue 1.33 mm L* 90.23 87.41 a* −1.34 −0.15 b* −1.72 −4.02 Observable color blue blue 2.06 mm L* 86.49 82.29 a* −2.05 −0.24 b* −2.30 −5.93 Observable color blue blue

Referring now to Table 8, example glass article 68 having the analyzed concentrations shown in Table 5 and the thicknesses shown in Table 8 were subjected to heat treatment at the temperature and for the period of time shown in Table 8. The transmittance color coordinate in the CIELAB color space, as measured at the indicated article thickness under F2 illumination and a 10° standard observer angle, and the observable color of the resultant colored glass articles are shown in Table 8.

TABLE 8 545° C. for 550° C. for 555° C. for 535° C. for 545° C. for Thickness 2 hrs. 2 hrs. 1.5 hrs. 10 hrs. 4 hrs.  0.6 mm L* 93.11 92.14 91.56 91.16 90.79 a* 3.74 4.82 4.74 6.02 5.90 b* −0.62 −1.31 −2.06 −0.27 −1.33 Observable color pink pink pink red pink 1.33 mm L* 89.09 87.26 86.79 85.12 84.78 a* 7.98 9.84 9.46 12.00 11.74 b* −1.42 −2.58 −3.64 −0.72 −2.32 Observable color pink purple pink red pink 2.06 mm L* 84.41 81.51 81.40 79.52 78.50 a* 12.63 15.29 14.09 17.14 17.21 b* −2.25 −4.01 −5.39 −0.26 −3.16 Observable color pink purple pink red red 560° C. for 555° C. for 570° C. for 625° C. for 600° C. for Thickness 0.75 hrs. 4 hrs. 0.75 hrs. 3 hrs. 2 hrs.  0.6 mm L* 92.14 89.13 88.96 88.74 89.18 a* 4.61 5.00 4.90 2.75 −1.05 b*−1.57 −1.57 −3.95 −4.51 −4.49 −4.32 Observable color pink purple purple purple purple 1.33 mm L* 85.56 81.32 79.76 80.41 79.58 a* 10.56 10.79 7.38 5.66 −2.04 b* −4.34 −7.51 −10.45 −9.10 −9.85 Observable color pink purple purple purple purple 2.06 mm L* 77.01 74.55 70.91 71.91 71.33 a* 16.22 16.05 8.60 8.16 −2.76 b* −8.50 −9.19 −15.68 −13.36 −14.14 Observable color pink pink purple purple purple 575° C. for 575° C. for Thickness 2 hrs. 4 hrs.  0.6 mm L* 88.09 88.92 a* −01.8 1.77 b* −5.64 −4.80 Observable color blue blue 1.33 mm L* 78.27 80.57 a* 0.17 3.42 b* −11.89 −9.88 Observable color blue blue 2.06 mm L* 70.17 72.06 a* −0.58 4.74 b* −16.48 −14.79 Observable color blue blue

Referring now to Table 9, example glass article 68 having the analyzed concentrations shown in Table 5 and the thicknesses shown in Table 9 were subjected to heat treatment at the temperature and for the period of time shown in Table 9. The transmittance color coordinate in the CIELAB color space, as measured at the indicated article thickness under F2 illumination and a 10° standard observer angle, and the observable color of the resultant colored glass articles are shown in Table 9.

TABLE 9 530° C. for 535° C. for 545° C. for 550° C. for 555° C. for Thickness 3 hrs. 6 hrs. 2 hrs. 2 hrs. 1.5 hrs.  0.6 mm L* 94.72 90.50 89.99 88.79 88.58 a* 1.96 6.78 7.30 7.58 7.50 b* 0.34 0.18 −0.85 −1.80 −2.57 Observable color pink pink pink pink pink 1.33 mm L* 92.64 84.15 83.50 80.52 79.57 a* 3.99 13.49 14.01 14.51 14.41 b* 0.62 0.67 −0.95 −3.71 −5.60 Observable color pink red red pink pink 2.06 mm L* 90.49 77.92 74.81 72.37 71.79 a* 6.07 19.65 21.74 20.56 21.07 b* 0.97 1.59 −1.98 −5.27 −6.54 Observable color pink red pink pink pink 555° C. for 650° C. for 540° C. for 565° C. for 585° C. for Thickness 4 hrs. 2 hrs. 3 hrs. 1.75 hrs. 2 hrs.  0.6 mm L* 88.59 87.25 88.03 86.62 87.36 a* 6.20 7.01 4.98 3.98 2.37 b* −2.50 −4.14 −4.41 −5.65 −5.52 Observable color purple purple purple purple purple 1.33 mm L* 80.63 77.89 78.78 76.92 77.59 a* 13.13 13.81 10.10 8.92 5.17 b* −3.71 −7.35 −8.78 −10.22 −10.98 Observable color purple purple purple purple purple 2.06 mm L* 71.87 68.47 70.21 67.15 68.17 a* 18.44 19.71 14.96 12.94 7.47 b* −6.46 −10.62 −12.00 −14.54 −15.73 Observable color purple purple purple purple purple 560° C. for 600° C. for Thickness 0.75 hrs. 2 hrs.  0.6 mm L* 87.04 87.56 a* 0.99 1.39 b* −6.09 −5.32 Observable color blue blue 1.33 mm L* 77.03 77.57 a* 3.32 2.56 b* −11.99 −10.84 Observable color blue blue 2.06 mm L* 67.17 68.30 a* 3.12 4.07 b* −17.38 −15.38 Observable color blue blue

As indicated in Tables 7-9, colored glass articles including Au may be subjected to different heat treatment to achieve a desired observable color.

Table 10 shows the surface compressive stress CS, depth of layer DOL, and maximum central tension CT of example glass article 67 after being subjected to heat treatment at 545° C. for 2 hrs. and then being subjected to ion-exchange under the conditions listed in Table 10.

TABLE 10 IOX temp. (° C.) 400 400 400 400 400 400 400 IOX time (hrs.) 5 6 7 8 6 6.5 6.5 KNO₃ in 83.0 83.0 83.0 83.0 83.0 83.0 80.0 IOX bath (wt %) NaNO₃ in 15.4 15.4 15.4 15.4 15.6 15.0 18.0 IOX bath (wt %) LiNO₃ in 1.6 1.6 1.6 1.6 1.4 2.0 2.0 IOX bath (wt %) CS (MPa) 720 643 632 623 657 621 611 DOL (μm) 4.46 4.86 5.36 5.44 5.00 5.04 4.85 CT (MPa) 111.1 117.4 116.3 115.6 119.2 109.1 118.2

Table 11 shows example compositions C1-C26, with the analyzed concentration (in terms of mol %) of the resultant colored glass articles.

TABLE 11 Composition C1 C2 C3 C4 C5 C6 SiO₂ 61.21 61.94 62.86 61.81 61.91 61.36 Al₂O₃ 14.46 14.48 14.52 15.56 15.54 15.75 B₂O₃ 5.84 5.95 5.92 5.88 5.89 5.91 Li₂O 11.79 10.95 11.01 11.05 11.02 11.17 Na₂O 6.34 6.32 5.34 5.34 5.34 5.42 K₂O 0.19 0.19 0.19 0.19 0.19 0.19 MgO 0.01 0.02 0.01 0.02 0.02 0.02 CaO — — — — — — ZnO — — — — — — ZrO₂ — — — — — — SnO₂ 0.11 0.11 0.10 0.11 0.05 0.06 Fe₂O₃ — — — — — 0.07 Cl 0.02 0.03 0.02 0.03 0.02 0.02 Au 0.0005 0.0007 0.0009 0.0008 0.0007 0.0005 R₂O 18.32 17.46 16.54 16.58 16.55 16.78 R₂O − Al₂O₃ 3.86 2.98 2.02 1.02 1.01 1.03 5.72*Al₂O₃ − −578.32 −550.38 −528.71 −523.70 −522.93 −529.18 21.4*ZnO − 2.5*P₂O₃ − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Composition C7 C8 C9 CIO CH C12 SiO₂ 61.24 60.87 60.67 60.54 60.56 60.70 Al₂O₃ 15.66 16.54 16.47 16.52 16.36 16.27 B₂O₃ 5.89 5.85 5.84 5.99 6.04 6.01 Li₂O 11.15 11.08 10.97 11.06 11.13 11.12 Na₂O 5.38 5.34 5.35 5.27 5.28 5.28 K₂O 0.19 0.19 0.19 0.20 0.20 0.19 MgO 0.01 0.02 0.02 0.02 0.02 0.02 CaO — — — — — — ZnO — — — — — — ZrO₂ 0.32 — 0.31 0.32 0.32 0.32 SnO₂ 0.05 0.06 0.05 0.05 0.05 0.05 Fe₂O₃ 0.07 — 0.07 — — — Cl 0.02 0.02 0.02 — — — Au 0.0005 0.0007 0.0005 0.0007 0.0008 0.0008 R₂O 16.72 16.61 16.51 16.53 16.61 16.59 R₂O − Al₂O₃ 1.06 0.07 0.04 0.01 0.25 0.32 5.72*Al₂O₃ − −527.52 −518.65 −515.27 −518.94 −523.37 −522.85 21.4*ZnO − 2.5*P₂O₃ − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Composition C13 C14 C15 C16 C17 C18 SiO₂ 60.64 60.64 63.76 65.01 65.86 67.01 Al₂O₃ 16.07 15.42 14.39 14.29 14.28 13.47 B₂O₃ 6.01 6.04 5.86 5.09 4.36 4.13 Li₂O 11.37 11.50 11.02 10.96 10.95 10.92 Na₂O 5.28 5.76 4.24 4.23 4.22 4.20 K₂O 0.19 0.19 0.14 0.14 0.14 0.14 MgO 0.02 0.02 0.04 0.03 0.02 0.02 CaO — — — — 0.01 0.01 ZnO — — 0.02 — — — ZrO₂ 0.32 0.32 0.48 0.20 0.10 0.04 SnO₂ 0.05 0.05 0.04 0.04 0.04 0.04 Fe₂O₃ — — — — — — Cl — — — — — — Au 0.0008 0.0008 0.0011 0.0010 0.0010 0.0010 R₂O 16.84 17.45 15.41 15.33 15.31 15.26 R₂O − Al₂O₃ 0.77 2.03 1.01 1.04 1.03 1.79 5.72*Al₂O₃ − −532.74 −552.69 −503.22 −488.03 −475.55 −474.86 21.4*ZnO − 2.5*P₂O₃ − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Composition C19 C20 C21 C22 C23 SiO₂ 67.59 67.75 67.84 67.89 67.63 Al₂O₃ 13.13 13.01 12.96 12.99 13.15 B₂O₃ 3.93 3.92 3.92 3.92 3.94 Li₂O 10.94 10.91 10.88 10.77 10.69 Na₂O 4.17 4.17 4.17 4.20 4.21 K₂O 0.14 0.14 0.14 0.14 0.15 MgO 0.02 0.02 0.01 0.01 0.01 CaO 0.01 0.01 0.01 0.01 0.10 ZnO 0.00 0.00 0.00 0.00 0.00 ZrO₂ 0.02 0.02 0.01 0.01 0.02 SnO₂ 0.04 0.04 0.04 0.04 0.04 Fe₂O₃ 0.00 0.00 0.00 0.00 0.00 Cl 0.00 0.00 0.00 0.00 0.00 Au 0.0011 0.0014 0.0016 0.0006 0.0001 R₂O 15.25 15.22 15.20 15.11 15.04 R₂O − Al₂O₃ 2.13 2.21 2.24 2.12 1.90 5.72*Al₂O₃ − −473.41 −473.02 −472.32 −468.73 −468.03 21.4*ZnO − 2.5*P₂O₃ − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO Composition C24 C25 C26 SiO₂ 63.76 65.86 67.59 Al₂O₃ 14.39 14.28 13.13 B₂O₃ 5.86 4.36 3.93 Li₂O 11.02 10.95 10.94 Na₂O 4.24 4.22 4.17 K₂O 0.14 0.14 0.14 MgO 0.04 0.02 0.02 CaO 0.00 0.00 0.00 ZnO 0.02 0.00 0.00 ZrO₂ 0.48 0.10 0.02 SnO₂ 0.04 0.04 0.04 Fe₂O₃ 0.00 0.00 0.00 Cl 0.00 0.00 0.00 Au 8.3 × 10⁻⁶ 7.7 × 10⁻⁶ 8.0 × 10⁻⁶ R₂O 15.40 15.31 15.25 R₂O − Al₂O₃ 1.01 1.03 2.12 5.72*Al₂O₃ − −503.30 −475.27 −473.20 21.4*ZnO − 2.5*P₂O₃ − 35*Li₂O − 16.6*B₂O₃ − 20.5*MgO − 23.3*Na₂O − 27.9*SrO − 18.5*K₂O − 26.3*CaO

Referring now to Table 12, example glass articles A1-A52 were formed from example compositions C2-C9 and C15-C23 shown in Table 11 and were subjected to heat treatment at the temperature and for the period of time shown in Table 12. The transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.33 mm under F2 illumination and a 10° standard observer angle, and the observable color of the resultant colored glass articles are shown in Table 12.

TABLE 12 Glass Article A1 A2 A3 A4 A5 A6 Composition C18 C19 C20 C21 C22 C23 Heat treatment 550 550 550 550 550 550 temp. (° C.) Heat treatment 8 8 8 8 8 8 time (hr.) L* 87.39 88.12 86.98 86.12 91.39 96.68 a* 7.72 7.34 8.39 9.23 4.78 0.00 b* 1.87 4.93 8.07 9.58 3.81 0.80 Observable color orange orange orange orange orange light yellow Glass Article A7 A8 A9 A10 A11 A12 Composition C15 C16 C17 C18 C18 C19 Heat treatment 575 575 575 575 575 575 temp. (° C.) Heat treatment 2 2 2 8 2 8 time (hr.) L* 83.48 92.46 85.94 88.08 91.19 88.2 a* 0.19 0.98 1.68 8.15 3.07 7.80 b* −6.06 −0.93 −4.63 5.71 −0.47 6.51 Observable color blue purple purple orange pink orange Glass Article A13 A14 A15 A16 A17 A18 Composition C19 C20 C20 C21 C22 C22 Heat treatment 575 575 575 575 575 575 temp. (° C.) Heat treatment 2 8 2 8 8 2 time (hr.) L* 89.96 86.7 86.9 85.72 90.59 90.98 a* 4.42 8.49 8.50 8.98 5.51 4.33 b* −0.06 9.06 6.59 10.40 4.77 1.19 Observable color pink orange orange orange orange red Glass Article A19 A20 A21 A22 A23 A24 Composition C23 C23 C15 C16 C17 C18 Heat treatment 575 575 600 600 600 600 temp. (° C.) Heat treatment 2 8 2 2 2 2 time (hr.) L* 96.73 95.89 82.63 83 83.43 88.03 a* 0.03 0.63 3.35 4.27 5.48 8.35 b* 0.75 1.84 −6.62 −6.11 −5.49 4.10 Observable color yellow peach purple purple purple orange Glass Article A25 A26 A27 A28 A29 A30 Composition C19 C20 C22 C23 C2 C3 Heat treatment 600 600 600 600 625 625 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) L* 87.99 86.66 90.23 96.4 89.29 87.6 a* 8.34 8.91 5.53 0.28 5.14 7.22 b* 5.45 8.48 3.52 1.24 9.97 10.51 Observable color orange orange orange light orange red orange Glass Article A31 A32 A33 A34 A35 A36 Composition C4 C5 C6 C7 C8 C9 Heat treatment 625 625 625 625 625 625 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) L* 83 86.74 88.94 87.28 78.03 80.49 a* 11.39 9.76 6.92 9.09 5.04 6.25 b* 2.59 2.60 4.75 3.44 −9.39 −8.92 Observable color red red red red purple purple Glass Article A37 A38 A39 A40 A41 A42 Composition C15 C16 C17 C18 C19 C20 Heat treatment 625 625 625 625 625 625 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) L* 84.25 85.21 85.58 87.5 87.39 86.09 a* 10.89 10.87 10.81 8.98 8.76 9.27 b* −0.89 0.55 0.90 4.56 5.39 8.00 Observable color magenta red red orange orange orange Glass Article A43 A44 A45 A46 A47 A48 Composition C22 C23 C15 C16 C17 C18 Heat treatment 625 625 650 650 650 650 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) L* 90.31 95.7 84.63 85.69 86.23 87.42 a* 5.73 0.89 11.19 11.18 10.85 9.14 b* 3.85 1.49 −0.12 1.22 1.47 4.40 Observable color orange orange magenta red red orange Glass Article A49 A50 A51 A52 Composition C19 C20 C22 C23 Heat treatment 650 650 650 650 temp. (° C.) Heat treatment 2 2 2 2 time (hr.) L* 87.42 86.18 90.14 95.53 a* 8.84 9.28 6.00 1.04 b* 5.24 8.10 3.89 1.42 Observable color orange orange orange orange

Referring now to Table 13, example glass articles A53-A114 were formed from example compositions C1-C14 and C24-C26 shown in Table 11 and were subjected to heat treatment at the temperature and for the period of time shown in Table 13. The observable colors of the resultant colored glass articles are shown in Table 13.

TABLE 13 Glass Article A53 A54 A55 A56 A57 A58 Composition C1 C2 C3 C4 C5 C6 Heat treatment 550 550 550 550 550 550 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color red clear, red clear, red clear clear red Glass Article A59 A60 A61 A62 A63 A64 Composition C7 C8 C9 C10 C11 C12 Heat treatment 550 550 550 550 550 550 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color red clear clear, pink clear clear clear Glass Article A65 A66 A67 A68 A69 A70 Composition C13 C14 C24 C1 C2 C3 Heat treatment 550 550 550 575 575 575 temp. (° C.) Heat treatment 2 2 8 2 2 2 time (hr.) Observable color clear clear, purple orange orange red purple Glass Article A71 A72 A73 A74 A75 A76 Composition C4 C5 C6 C7 C8 C9 Heat treatment 575 575 575 575 575 575 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color purple purple red red clear, red clear, pink Glass Article A77 A78 A79 A80 A81 A82 Composition C10 C11 C12 C13 C14 C24 Heat treatment 575 575 575 575 575 575 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color clear, clear, clear, clear, clear, red purple purple purple purple purple Glass Article A83 A84 A85 A86 A87 A88 Composition C25 C26 C24 C25 C1 C2 Heat treatment 575 575 575 575 600 600 temp. (° C.) Heat treatment 2 2 8 8 2 2 time (hr.) Observable color purple red red red orange orange Glass Article A89 A90 A91 A92 A93 A94 Composition C3 C4 C5 C6 C7 C8 Heat treatment 600 600 600 600 600 600 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color red purple purple red red purple Glass Article A95 A96 A97 A98 A99 A100 Composition C9 C10 C11 C12 C13 C14 Heat treatment 600 600 600 600 600 600 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color purple purple purple purple purple orange Glass Article A101 A102 A103 A104 A105 A106 Composition C24 C25 C26 C24 C25 C26 Heat treatment 600 600 600 625 625 625 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color purple red red red red red Glass Article A107 A108 A109 A110 A111 A112 Composition C10 C11 C12 C13 C14 C24 Heat treatment 650 650 650 650 650 650 temp. (° C.) Heat treatment 2 2 2 2 2 2 time (hr.) Observable color purple purple clear, purple orange red purple Glass Article A113 A114 Composition C25 C26 Heat treatment 650 650 temp. (° C.) Heat treatment 2 2 time (hr.) Observable color red red

Referring now to FIGS. 7 and 8 , plots show the relationship of R₂O—Al₂O₃ and a* and b*, respectively, of example glass articles A29-A44. As shown in FIG. 7 , a* was a positive number, regardless of the R₂O—Al₂O₃ value, thereby resulting in observable colors towards red side of the CIELAB color space. As shown in FIG. 8 , as R₂O—Al₂O₃ increased, b* increased, thereby shifting the observable colors from blue to yellow. For example, example glass articles A35 and A36, formed from example compositions C8 and C9 having an analyzed R₂O—Al₂O₃ of 0.07 mol % and 0.04 mol %, respectively, had a b* of −9.39 and −8.92, respectively, resulting in observably purple glass articles. Example glass articles A29 and A30, formed from example glass compositions C2 and C3 having an analyzed R₂O—Al₂O₃ of 2.98 mol % and 2.02 mol %, respectively, had a b* of 9.97 and 10.51, respectively, resulting in an observably orange glass article and an observably red glass article.

Moreover, example glass articles A33 and A34, formed from example glass compositions C6 and C7 including Fe₂O₃ and ZrO₂, respectively, had an observable red color.

As indicated by Tables 12 and 13 and FIGS. 7 and 8 , the analyzed R₂O—Al₂O₃ may be adjusted, additional components may be added to the glass composition, and the glass article may be subjected to a certain heat treatment to provide a desired colored glass article.

Table 14 shows example glass compositions (in terms of mol %) containing Cr₂O₃ as a colorant and the transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of the resultant colored glass articles.

TABLE 14 Example Cr-1 Cr-2 Cr-3 Cr-4 Cr-5 Cr-6 SiO₂ 58.78 58.30 58.52 58.97 58.26 58.52 Al₂O₃ 16.68 16.35 16.50 16.41 16.38 16.56 B₂O₃ 5.93 5.93 6.01 5.98 5.93 6.04 Li₂O 11.74 9.86 9.93 9.89 9.85 9.89 Na₂O 6.26 4.25 4.27 4.27 4.26 4.30 K₂O 0.48 0.48 0.48 0.49 0.48 0.49 MgO 0.02 2.91 2.95 2.91 2.94 2.93 CaO 0.01 0.01 0.01 0.01 0.01 0.02 ZnO — 1 1.01 1 1 1.05 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 NiO — — 0.023 0.012 0.043 0.089 Co₃O₄ — 0.001 0.002 0.002 0.03 0.048 CuO — 0.83 0.233 0.037 0.785 0.044 Cr₂O₃ 0.098 0.068 0.038 0.002 0.016 0.008 R₂O 18.48 14.59 14.68 14.65 14.59 14.68 R′O 0.03 3.92 3.97 3.92 3.95 4 R₂O + R′O—Al₂O₃ 1.83 2.16 2.15 2.16 2.16 2.12 MgO + ZnO 0.02 3.91 3.96 3.91 3.94 3.98 Al₂O₃ + MgO + ZnO 16.7 20.26 20.46 20.32 20.32 20.54 Transmittance Color Coordinate L* 83.78 77.06 85.88 94.99 66.99 62.17 a* −12.60 −26.24 −9.49 −0.45 −10.12 −2.12 b* 62.26 8.74 6.26 0.17 −14.19 −20.39 Example Cr-7 Cr-8 Cr-9 Cr-10 Cr-11 Cr-12 SiO₂ 57.09 59.21 58.44 58.12 59.20 58.36 Al₂O₃ 16.10 16.64 16.21 16.56 16.58 16.11 B₂O₃ 5.90 5.62 5.70 6.07 5.67 5.69 Li₂O 9.68 11.75 11.56 11.83 11.82 11.6 Na₂O 4.21 6.18 6.09 6.21 6.16 6.07 K₂O 0.47 0.47 0.47 0.48 0.45 0.46 MgO 2.86 0.02 0.02 0.02 0.02 0.02 CaO 0.02 0.01 0.01 0.01 0.01 0.01 ZnO 0.98 — — — — — TiO₂ — 0.01 — 0.01 0.01 — NiO 0.014 0.078 0.039 0.071 — — Co₃O₄ 0.058 0.001 0.001 0.002 0.002 0.038 CuO 2.598 0.002 1.351 0.563 0.086 1.583 Cr₂O₃ 0.006 0.009 0.102 0.051 0.002 0.051 R₂O 14.36 18.4 18.12 18.52 18.43 18.13 R′O 3.86 0.03 0.03 0.03 0.03 0.03 R₂O + R′O—Al₂O₃ 2.12 1.79 1.94 1.99 1.88 2.05 MgO + ZnO 3.84 0.02 0.02 0.02 0.02 0.02 Al₂O₃ + MgO + ZnO 19.94 16.66 16.23 16.58 16.6 16.13 Transmittance Color Coordinate L* 38.41 89.31 89.27 76.84 94.52 41.28 a* −14.36 −0.65 −0.77 −14.83 −1.14 −18.17 b* −13.36 17.15 17.45 11.73 −2.04 −13.89 Example Cr-13 Cr-14 Cr-15 Cr-16 Cr-17 Cr-18 SiO₂ 58.03 58.39 58.48 58.45 58.58 58.71 Al₂O₃ 16.57 16.49 16.53 16.49 16.42 16.54 B₂O₃ 6.03 6.01 6.09 6.04 5.97 5.99 Li₂O 11.93 10.02 10.08 10.04 10.5 10.48 Na₂O 6.23 4.28 4.26 4.25 4.71 4.76 K₂O 0.48 0.48 0.49 0.48 0.48 0.49 MgO 0.02 2.95 2.94 2.94 0.96 0.97 CaO 0.01 0.02 0.01 0.02 0.98 0.98 ZnO — 1.01 1.01 1.01 0.99 1.02 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 NiO 0.093 0.021 — 0.082 0.019 — Co₃O₄ 0.072 0.002 0.002 0.048 0.002 0.002 CuO 0.516 0.278 0.091 0.137 0.339 0.054 Cr₂O₃ 0.012 0.036 0.001 0.006 0.039 0.001 R₂O 18.64 14.78 14.83 14.77 15.69 15.73 R′O 0.03 3.98 3.96 3.97 2.93 2.97 R₂O + R′O-Al₂O₃ 2.1 2.27 2.26 2.25 2.2 2.16 MgO + ZnO 0.02 3.96 3.95 3.95 1.95 1.99 Al₂O₃ + MgO + ZnO 16.59 20.45 20.48 20.44 18.37 18.53 Transmittance Color Coordinate L* 38.93 85.89 95.05 62.68 85.25 95.29 a* 1.10 −9.54 −0.84 −2.13 −10.39 −0.68 b* −44.38 5.68 −0.62 −20.72 6.20 −0.90 Example Cr-19 SiO₂ 58.51 Al₂O₃ 16.49 B₂O₃ 6.06 Li₂O 10.47 Na₂O 4.76 K₂O 0.49 MgO 0.97 CaO 0.99 ZnO 1.01 TiO₂ 0.01 NiO 0.085 Co₃O₄ 0.048 CuO 0.111 Cr₂O₃ 0.005 R₂O 15.72 R′O 2.97 R₂O + R′O—Al₂O₃ 2.2 MgO + ZnO 1.98 Al₂O₃ + MgO + ZnO 18.47 Transmittance Color Coordinate L* 61.08 a* −2.34 b* −22.51

As indicated by the example glass compositions and colored glass articles in Table 14, the glass compositions described herein improve Cr₂O₃ solubility to form colored glass articles having the desired color. For example, example glass composition Cr-1 including 0.098 mol % Cr₂O₃ formed a colored glass article having a transmittance color coordinate in the CIELAB color space of L*=83.78, a*=−12.60, and b*=62.26.

As further indicated by the example glass compositions and colored glass articles in Table 14, adding other colorants in addition to Cr₂O₃ as described herein allows different color gamuts to be achieved. For example, example glass composition Cr-2 including 0.068 mol % Cr₂O₃, 0.001 mol % Co₃O₄, and 0.83 mol % CuO formed a colored glass article have a transmittance color coordinate in the CIELAB color space of L*=77.06, a*=−26.24, and b*=8.74. Example glass composition Cr-3, including 0.038 mol % Cr₂O₃, 0.023 mol % NiO, 0.002 mol % Co₃O₄, and 0.233 mol % CuO formed a colored glass article have a transmittance color coordinate in the CIELAB color space of L*=85.88, a*=−9.40, and b*=6.26.

Referring now to FIGS. 9-32 , projected color gamuts were modeled for glass compositions containing Cr₂O₃ as a colorant. The modeled compositions included Cr₂O₃ as the sole colorant as well as Cr₂O₃ in combination with NiO, Co₃O₄, CuO, and various combinations thereof.

Referring now to FIGS. 9-11 , a projected color gamut for a glass composition including only Cr₂O₃ as a colorant is shown. As illustrated, a single colorant generates a line in the CIELAB color space. The points along the line correspond to different levels of Cr₂O₃ concentration from 0 mol % to 2 mol %. The arrows indicate the directions of increasing concentration. The Cr₂O₃ color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃ may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −18 and less than or equal to 0, and b* greater than or equal to 0 and less than or equal to 82.

Different color gamuts may be achieved by including other colorants in addition to Cr₂O₃. Referring now to FIGS. 12-14 , a projected color gamut for a glass composition including Cr₂O₃ and NiO as colorants is shown. As illustrated, two colorants generate a surface in the CIELAB color space. The Cr₂O₃/NiO color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃ and greater than or equal to 0 mol % and less than or equal to 4 mol % NiO may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −18 and less than or equal to 18, and b* greater than or equal to 0 and less than or equal to 82.

Referring now to FIGS. 15-17 , a projected color gamut for a glass composition including Cr₂O₃ and Co₃O₄ as colorants is shown. As illustrated, two colorants generate a surface in the CIELAB color space. The Cr₂O₃/Co₃O₄ color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃ and greater than or equal to 0 mol % and less than or equal to 2 mol % Co₃O₄ may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −20 and less than or equal to 60, and b* greater than or equal to −90 and less than or equal to 85.

Referring now to FIGS. 18-20 , a projected color gamut for a glass composition including Cr₂O₃ and CuO as colorants is shown. As illustrated, two colorants generate a surface in the CIELAB color space. The Cr₂O₃/CuO color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃ and greater than or equal to 0 mol % and less than or equal to 20 mol % CuO may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −35 and less than or equal to 0, and b* greater than or equal to 0 and less than or equal to 82.

Referring now to FIGS. 21-23 , a projected color gamut for a glass composition including Cr₂O₃, NiO, and CuO as colorants is shown. As illustrated, three colorants create a volume in the CIELAB color space. The Cr₂O₃/NiO/CuO color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃, greater than or equal to 0 mol % and less than or equal to 4 mol % NiO, and greater than or equal to 0 mol % and less than or equal to 20 mol % CuO may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −35 and less than or equal to 20, and b* greater than or equal to 0 and less than or equal to 75.

Referring now to FIGS. 24-26 , a projected color gamut for a glass composition including Cr₂O₃, NiO, and Co₃O₄ as colorants is shown. As illustrated, three colorants create a volume in the CIELAB color space. The Cr₂O₃/NiO/Co₃O₄ color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃, greater than or equal to 0 mol % and less than or equal to 4 mol % NiO, and greater than or equal to 0 mol % and less than or equal to 2 mol % Co₃O₄ may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −15 and less than or equal to 65, and b* greater than or equal to −90 and less than or equal to 80.

Referring now to FIGS. 27-29 , a projected color gamut for a glass composition including Cr₂O₃, CuO, and Co₃O₄ as colorants is shown. As illustrated, three colorants create a volume in the CIELAB color space. The Cr₂O₃/CuO/Co₃O₄ color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃, greater than or equal to 0 mol % and less than or equal to 20 mol % CuO, and greater than or equal to 0 mol % and less than or equal to 2 mol % Co₃O₄ may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −35 and less than or equal to 60, and b* greater than or equal to −90 and less than or equal to 80.

Referring now to FIGS. 30-32 , a projected color gamut for a glass composition including Cr₂O₃, NiO, CuO, and Co₃O₄ as colorants is shown. As illustrated, four colorants create an overlapping volume in the CIELAB color space. The Cr₂O₃/NiO/CuO/Co₃O₄ color gamut projects that a colored glass article having greater than or equal to 0 mol % and less than or equal to 2 mol % Cr₂O₃, greater than or equal to 0 mol % and less than or equal to 4 mol % NiO, greater than or equal to 0 mol % and less than or equal to 20 mol % CuO, and greater than or equal to 0 mol % and less than or equal to 2 mol % Co₃O₄ may have a transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.5 mm under F2 illumination and a 10° standard observer angle, of L* greater than or equal to 0 and less than or equal to 100, a* greater than or equal to −35 and less than or equal to 60, and b* greater than or equal to −90 and less than or equal to 80.

Tables 15 and 16 show example glass compositions (in terms of mol %) containing Ag as a colorant.

TABLE 15 Example (mol %) Ag-1 Ag-2 Ag-3 Ag-4 Ag-5 Ag-6 Ag-7 Ag-8 Ag-9 Ag-10 Ag-11 Ag-12 Ag-13 Ag-14 Ag-15 SiO₂ 59.55 60.05 60.55 60.00 59.95 59.90 60.10 60.00 59.85 60.16 60.09 59.79 59.47 59.45 57.55 Al₂O₃ 16.50 16.50 16.50 16.50 16.50 16.50 16.50 16.50 16.50 15.90 15.93 15.89 15.82 16.50 16.50 B₂O₃ 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.08 6.06 6.04 5.99 6.00 6.00 Li₂O 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 11.99 11.97 11.97 11.92 12.00 12.00 Na₂O 5.70 5.20 4.70 5.20 5.20 5.20 5.20 5.20 5.20 5.41 5.41 5.89 6.37 5.50 6.50 K₂O — — — — — — — — — 0.20 0.20 0.20 0.19 0.20 0.20 SnO₂ 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.11 0.11 0.11 0.10 0.20 0.10 Ag 0.15 0.15 0.15 0.15 0.15 0.15 0.10 0.10 0.25 0.15 0.25 0.12 0.13 0.15 0.15 CeO₂ — — — 0.05 0.10 0.15 — 0.10 0.10 — — — — — — Nd₂O₃ — — — — — — — — — — — — — — 1.00 Er₂O₃ — — — — — — — — — — — — — — — R₂O—Al₂O₃ 1.20 0.70 0.20 0.70 0.70 0.70 0.70 0.70 0.70 1.70 1.64 2.16 2.66 1.20 2.20

TABLE 16 Example (mol %) Ag-16 Ag-17 Ag-18 Ag-19 Ag-20 Ag-21 Ag-22 Ag-23 Ag-24 Ag-25 Ag-26 Ag-27 Ag-28 Ag-29 SiO₂ 57.55 59.1 59.05 59.41 59.31 59.36 59.26 58.91 58.81 59.41 59.01 58.55 58.7 59.7 Al₂O₃ 16.50 16.00 16.00 15.97 15.97 15.97 15.97 15.97 15.97 15.97 15.89 16.5 16.4 16.5 B₂O₃ 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6 6 6 Li₂O 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12 12 12 Na₂O 6.50 6.50 6.50 6.17 6.17 6.17 6.17 6.67 6.67 6.17 6.65 6.5 6.5 5.5 K₂O 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.2 0.2 0.2 SnO₂ 0.10 0.10 0.10 0.10 0.20 0.10 0.20 0.10 0.20 0.10 0.10 0.1 0.1 0.1 Ag 0.15 0.10 0.15 0.15 0.15 0.20 0.20 0.15 0.15 0.15 0.15 0.15 0.15 0.15 CeO₂ — — — — — — — — — — — — — Nd₂O₃ — — — — — — — — — — — — — Er₂O₃ 1.00 — — — — — — — — — — — — R₂O—Al₂O₃ 2.20 2.70 2.70 2.40 2.40 2.40 2.40 2.90 2.90 2.40 2.96 2.2 2.3 1.2

The exemplary glass compositions of Tables 15 and 16 were used to produce glass coupons. These glass coupons were inserted into pre-heated, ambient-air electric ovens, held for a desired amount of time, and cooled in air to produce colored glass coupons. It should be noted that some glasses were heated at a particular ramp rate and/or cooled at a controlled rate; however, it was determined that neither the ramp rate nor cooling rate affected color generation.

Plots of CIELAB spaces of colored glass coupons produced from Examples Ag-1 and Ag-9 are depicted in FIG. 33A (a* vs. L*), FIG. 33B (b* vs. L*), and FIG. 33C (a* vs. b*). Sample sets having thicknesses of 0.6 mm, 1.33 mm, and 2.06 mm were made from each composition and the samples were heat treated at various heat treatment times (575° C., 600° C., 625° C., 650° C.) and various heat treatment times (1 hour, 2 hours) to produce colored glass articles having the CIELAB L*, a*, b* values indicated in FIGS. 33A-33C.

Plots of projected CIELAB spaces of colored glass coupons produced from Examples Ag-10-Ag-12 are depicted in FIG. 34A (a* vs. L*), FIG. 34B (b* vs. L*), and FIG. 34C (a* vs. b*). Sample sets having thicknesses of 0.6 mm, 1.33 mm, and 2.06 mm were made from each composition and the samples were heat treated at various heat treatment times (575° C., 600° C., 625° C., 650° C.) and various heat treatment times (1 hour, 2 hours) to produce colored glass articles having the CIELAB L*, a*, b* values indicated in FIGS. 34A-34C.

FIGS. 35 and 36 depict the absorbance spectra (determined from the transmittance spectra T where the absorbance A=log₁₀(1/T)) of colored glass coupons produced from Examples Ag-1 and Ag-9, respectively. Specifically, the absorbance spectra of glass coupons formed from the compositions of Examples Ag-1 and Ag-9 were collected from coupons in: as-made condition (no heat treatment); after exposure to a heat treatment of 600° C. for 2 hours; after exposure to a heat treatment of 600° C. for 3 hours; after exposure to a heat treatment of 625° C. for 2 hours; after exposure to a heat treatment of 625° C. for 3 hours; and after exposure to a heat treatment of 650° C. for 3 hours. As shown in FIGS. 35 and 36 , the absorbance spectra varied considerably with changes in heat treatment temperature and heat treatment time.

FIGS. 37, 38 and 39 depict the absorbance spectra of colored glass coupons produced from Examples Ag-10-Ag-12, respectively. Specifically, the absorbance spectra of glass coupons formed from the compositions of examples Ag-10-Ag-12 were collected from coupons in: after exposure to a heat treatment of 575° C. for 2 hours; after exposure to a heat treatment of 600° C. for 1 hours; after exposure to a heat treatment of 600° C. for 2 hours; after exposure to a heat treatment of 600° C. for 3 hours; after exposure to a heat treatment of 625° C. for 1 hour; after exposure to a heat treatment of 630° C. for 4 hours; and after exposure to a heat treatment of 650° C. for 0.5 hour. As shown in FIGS. 37-39 , the absorbance spectra varied considerably with changes in heat treatment temperature and heat treatment time.

FIGS. 40A-40C are plots of CIELAB spaces of colored glass coupons produced from Example Ag-16 containing erbium. Specifically FIG. 40A is a plot of a* vs. L*, FIG. 40B is a plot b* vs. L*, and FIG. 40C is a plot of a* vs. b*. Sample sets having thicknesses of ˜0.6 mm, ˜1.33 mm, and ˜2.06 mm were made from the composition and heat treated at various heat treatment temperatures and various heat treatment times (as indicated in Table 17) to produce colored glass articles having the CIELAB L*, a*, b* values indicated in FIGS. 40A-40C. The CIELAB space plots indicate that an entirely new range of colors can be achieved by adding erbium to the composition. FIG. 41 depicts the absorbance spectra of example Ag-16 in as-made condition (prior to heat treatment); after heat treatment at 565° C. for 15 minutes; and after heat treatment at 575° C. after 20 minutes.

TABLE 17 Heat Treatment (Temp (° C.)/ Time (minutes)/ Thickness Example Ramp Rate (° C./min)) (mm) L* a* b* Ag-16 as made 0.60 95.09 4.58 −1.73 Ag-16 575/20/10 0.57 94.76 3.32 1.91 Ag-16 565/15/10 0.60 95 4.26 −0.83 Ag-16 as made 1.34 93.7 8.44 −3.23 Ag-16 575/20/10 1.32 92.03 3.62 13.15 Ag-16 565/15/10 1.32 93.51 7.83 −1.61 Ag-16 as made 2.06 92.66 10.98 −4.12 Ag-16 575/20/10 2.03 91.28 7.96 6.77 Ag-16 565/15/10 2.04 92.25 9.9 −0.62

FIGS. 42A-42C are plots of CIELAB spaces of colored glass coupons produced from Example Ag-13. In particular, coupons of glass formed from the composition of Example Ag-13 includes R₂O—Al₂O₃ values in the range between 2.5 and 3 mol %, specifically 2.66 mol %. The samples were heat treated at various heat treatment temperatures and heat treatment times to produce colored glass articles having a range of colors including green, brown, maroon, purple and pink, as indicated in the CIELAB spaces of FIGS. 42A-42C.

FIG. 43 is the absorbance spectra of Example Ag-13 for heat treatments at 635° C. for 20 minutes; 635° C. for 30 minutes; and 635° C. for 40 minutes. The heat treatment conditions produced a colored glass article that was green in color. As shown in FIG. 43 the absorbance spectra had two distinct peaks arising from the formation of anisotropic silver particles that support two distinct plasmon resonances. FIGS. 44A-44C are TEM micrographs of the anisotropic silver particles in the green glass formed from Example Ag-13 and show the random orientation of the anisotropic particles (FIG. 44A) and that the silver particles have an aspect ratio greater than 1 (FIGS. 44B and 44C).

As discussed herein, the R₂O—Al₂O₃ value of a composition influences both isotropic and anisotropic particle formation during heat treatment and hence the color of the resultant glass. When R₂O—Al₂O₃<<1 (i.e., 0.2 mol % or less), virtually no color is formed in the glass upon heat treatment. This is demonstrated by Example Ag-3, which has an R₂O—Al₂O₃ value of 0.2 mol %. Irrespective of heat treatment, the glass of Example Ag-3 remained nearly colorless and transparent after heat treatment. However, when the R₂O—Al₂O₃ value is increased to 0.7 mol % (as with glasses formed from Example Ag-2) and then to 1.2 mol % (as with glasses formed from Example Ag-1), a progressively broader and more saturated range of colors were produced by heat treatment.

Referring now to FIG. 45 , a transmittance spectrum is shown for 1.3 mm coupons of glass formed from Example Ag-1 and heat treated at the same heat treatment temperature (600° C.) for different heat treatment times (1, 2, or 3 hours). The different heat treatment conditions yielded colored glass articles of different colors (yellow (solid line in FIG. 45 ), orange (dotted line in FIG. 45 ), and red (dashed line in FIG. 45 ), respectively), each of which had different transmittance spectra over the visible light range, as indicated in FIG. 45 , with yellow samples being the most transparent and the red samples the least.

Referring now to FIG. 46 , a transmittance spectrum is shown for a 1.3 mm coupon of glass formed from Example Ag-1 and heat treated at a heat treatment temperature of 650° C. for a heat treatment time of 1 hour, producing a colored glass article that was brown in color. As noted herein, colored glass articles that are brown in color can be produced by heat treatment at temperatures between 640° C. and 660° C. for heat treatment times between 30 and 90 minutes.

Referring now to FIG. 47 , a transmittance spectrum is shown for a 1.3 mm coupon of glass formed from Example Ag-21 and heat treated with an initial heat treatment of 450° C. for 1 our followed by a second heat treatment of 635° C. for 1 hour, producing a colored glass article that was purple in color. It was determined that the initial heat treatment was not needed to produce color in the sample. As noted herein, colored glass articles that are purple in color can be produced by heat treatment at temperatures between 625° C. and 650° C. for heat treatment times between 30 and 90 minutes.

Referring now to Table 18 and FIG. 48 , colored glass articles in the form of glass coupons were produced from the glass compositions of Tables 15 and 16. The glass coupons had thicknesses from ˜0.5 mm to ˜1.4 mm and were heat treated at various times and temperatures (as specified in Table 18) to produce colored glass articles with different color hues. PHCFR means that the glass coupon was placed directly into a pre-heated furnace, held for the indicated time, at which point the furnace was switched off and the glass coupon was cooled in the furnace at the cooling rate of the furnace (typically 2-3° C./minute). PHAC means that the glass coupon was placed directly into a pre-heated furnace, held for the indicated time, then removed and allowed to cool back to room temperature in ambient air. The CIELAB L*, a*, and b* coordinates of each colored glass article were determined and the a*, b* color coordinates were plotted as depicted in FIG. 48 , where the x-axis is the a* coordinate and the y-axis is the b* coordinate. For reference, the L* coordinate (not depicted) is along an axis orthogonal to both the x-axis and the y-axis of FIG. 48 and extends through the point a*=0 and b*=0.

TABLE 18 Heat Treatment (Temp (° C.)/ Time (hours)/ Thickness Example Ramp Rate (° C./min)) (mm) L* a* b* Ag-10 600/3/10 1.33 88.3 −2.26 65.85 Ag-10 600/3/10 1.29 90.44 −3.88 51.15 Ag-11 575/2/10 1.29 80.43 5.3 94.46 Ag-11 575/2/10 1.32 81.29 3.96 93.62 Ag-10 600/2/10 1.31 92.72 −2.81 29.07 Ag-10 600/2/10 1.28 92.55 −3.22 30.79 Ag-10 625/2/10 1.32 83.97 7.32 53.78 Ag-10 625/2/10 1.32 79.43 12.07 62 Ag-27 600/0.5/PHCFR 1.26 89.41 −8.22 57.36 Ag-27 600/0.75/PHCFR 1.35 83.95 −2.24 85.2 Ag-27 600/1/PHCFR 1.32 79.51 4.83 96 Ag-9 600/1/PHAC 1.31 77.86 12.16 106.74 Ag-9 600/2/PHAC 1.31 73.48 18.67 108.37 Ag-1 600/1/10 1.29 78.31 13 104.03 Ag-13 635/0.3/10 0.61 78.07 16.01 101.22 Ag-11 635/0.5/10 0.59 76.1 18.64 111.37 Ag-23 625/0.5/10 1.28 86.72 −2.66 91.23 Ag-23 450/1/10 1.25 81.15 6.31 103.91 Ag-21 575/2/10 1.16 90.82 −7.55 56.94 Ag-23 575/2/10 1.23 90.94 −9.74 52.14 Ag-23 575/3/10 1.35 83.93 −2.13 87.35 Ag-23 600/1/10 1.33 88.97 −7.73 76.89 Ag-23 625/0.75/10 1.37 77.37 13.14 107.83 Ag-23 650/0.3/10 1.32 83.6 3.6 98.53 Ag-23 615/0.5/10 1.33 90.72 −11.12 66.64 Ag-23 615/1/10 1.29 78.19 13.1 108.41 Ag-23 640/0.5/10 1.25 73.27 21.82 101.59 Ag-23 650/0.5/10 1.29 77.89 7.06 92.68 Ag-22 575/3/10 1.34 78.23 13.57 100.58 Ag-24 575/3/10 1.34 89.53 1.16 40.46 Ag-20 625/2/10 1.37 83.21 9.05 39.01 Ag-19 575/4/10 1.35 83.86 10.63 45.29 Ag-22 600/1/10 1.31 83.83 10.63 46.05 Ag-21 615/0.5/10 1.35 63.83 21.26 79.15 Ag-23 635/0.6/10 1.26 69.96 24.92 104.44 Ag-27 600/1.25/PHCFR 1.31 69.76 24.11 109.37 Ag-21 575/3/10 1.35 75.48 20.79 106.6 Ag-11 600/1/10 1.32 71.5 21.65 110.29 Ag-11 600/1/10 1.33 70.48 23.07 110.67 Ag-9 625/1/PHAC 1.31 79.96 15.43 62.16 Ag-22 575/2/10 1.20 91.99 −4.71 37.28 Ag-11 650/0.5/10 1.35 93.59 −10.87 39.72 Ag-1 600/2/PHAC 1.31 81.94 14.76 45.2 Ag-12 600/2/10 1.34 82.02 14.23 39.93 Ag-12 600/2/10 1.31 82.6 12.96 41.47 Ag-27 600/0.25/PHCFR 1.31 93.01 −7.93 33.76 Ag-11 600/3/10 1.34 53.38 36.16 89.47 Ag-12 600/3/10 1.32 71.89 26.88 63.17 Ag-12 600/3/10 1.33 72.44 26.28 61.16 Ag-11 600/2/10 1.30 61.58 30.81 101 Ag-11 600/2/10 1.32 60.37 32.13 100.26 Ag-11 625/1/10 1.33 56.78 40.08 95.88 Ag-11 625/1/10 1.35 58.43 38.04 98.02 Ag-1 600/3/PHAC 1.32 60.97 36.89 57.26 Ag-9 625/2/PHAC 1.32 61.72 41.44 100.95 Ag-9 650/1/PHAC 1.32 57.39 33.25 43.5 Ag-1 600/2/10 1.33 54.05 46.56 90.95 Ag-1 600/3/10 1.32 57.71 37.75 53.96 Ag-9 600/3/10 1.32 49.88 47.94 84.03 Ag-11 635/0.3/10 1.36 63.67 36.89 105.88 Ag-11 635/0.5/10 1.32 60 39.32 100.53 Ag-11 630/0.6/10 0.59 67.2 32.97 110.25 Ag-11 650/0.5/10 0.56 61.12 27.94 74.46 Ag-21 600/1/10 1.33 74.55 21.53 41.51 Ag-22 625/1/10 1.35 57.25 32.53 43.57 Ag-22 625/2/10 1.35 39.71 34.72 46.35 Ag-22 575/4/10 1.37 66.13 32.1 107.91 Ag-23 575/4/10 1.37 61.84 37.63 102.88 Ag-22 600/2/10 1.28 64.47 34.95 82.43 Ag-23 600/2/10 1.25 58.86 39.89 98.15 Ag-22 600/3/10 1.24 62.11 37.06 96.27 Ag-22 635/1/10 1.27 54.92 30.14 34.44 Ag-22 635/2/10 1.28 42.76 29.96 47.39 Ag-22 650/30/10 1.31 47.96 24.34 42.2 Ag-11 600/3/10 1.32 43.41 41.48 73.52 Ag-9 600 0.5/10 1.33 72.32 25.62 43.19 Ag-24 575/4/10 1.35 73.2 19.64 35.14 Ag-11 625/2/10 1.31 21.62 46.36 36.66 Ag-11 625/2/10 1.30 28.68 48.69 48.74 Ag-27 600/1.5/PHCFR 1.31 46.01 53.51 77.81 Ag-9 600/3/PHAC 1.31 37.09 48.11 62.4 Ag-9 625/3/PHAC 1.29 27.58 50.33 46.01 Ag-11 650/0.5/10 1.35 34.47 49.12 57.71 Ag-21 600/2/10 1.27 25.15 38.39 41.98 Ag-23 600/3/10 1.23 35.28 29.5 16.99 Ag-23 635/1/10 1.27 29.58 37.33 46.53 Ag-9 600/2/10 1.31 40.56 48.66 68.35 Ag-21 575/4/10 1.36 46 51.36 75.97 Ag-11 630/0.6/10 1.35 43.57 50.81 73.87 Ag-22 615/1/10 1.31 45.53 48.19 73.96 Ag-23 625/1/10 1.35 32.52 37.79 42.15 Ag-12 625/2/10 1.31 40.9 42.34 45.72 Ag-12 625/2/10 1.31 40.92 34.87 38.77 Ag-10 575/2/10 1.28 95.61 −2.57 10.47 Ag-10 575/2/10 1.33 95.5 −2.51 10.73 Ag-12 575/2/10 1.30 95.46 −4.72 15.2 Ag-12 575/2/10 1.31 95.21 −4.78 16.2 Ag-10 600/1/10 1.29 94.06 −0.93 15.68 Ag-10 600/1/10 1.29 95.27 −1.08 9.58 Ag-1 575/1/PHAC 1.30 96.33 −2.88 7.92 Ag-9 575/1/PHAC 1.33 96.22 −1.88 6.36 Ag-13 635/0.5/10 0.59 65.97 −1.78 6.53 Ag-11 635/0.5/10 1.34 95.37 −0.8 8.8 Ag-11 635/0.5/10 0.61 95.46 −0.63 8.11 Ag-11 630/0.7/10 1.36 94.65 −1.36 13.6 Ag-11 630/0.7/10 0.57 96.13 −0.64 4.96 Ag-13 630/0.7/10 1.34 17.64 −0.13 9.52 Ag-10 650/0.5/10 0.57 93.1 −2.63 16.08 Ag-11 650/0.5/10 0.58 95.83 −6.92 18.3 Ag-13 635/0.6/10 0.50 68.86 −5.21 8.63 Ag-13 635/0.6/10 0.50 69.02 −4.23 10.36 Ag-19 625/0.6/10 1.28 91.48 −0.24 1.94 Ag-19 575/2/10 1.19 96.2 −1.67 5.92 Ag-20 575/2/10 1.18 96.23 −1.37 6.17 Ag-20 575/3/10 1.36 95.79 −1.76 8.63 Ag-20 575/4/10 1.35 94.03 −2.99 21.48 Ag-20 600/2/10 1.28 95.38 −0.5 8.66 Ag-20 635/2/10 1.29 93.27 −5.41 22.51 Ag-24 650/0.5/10 1.29 62.01 −3.99 25.51 Ag-24 645/0.5/10 1.22 53.04 −2.71 16.67 Ag-1 600/1/PHAC 1.30 94.18 −1.61 17.89 Ag-20 650/0.5/10 1.31 93.44 −5.26 21.04 Ag-24 575/2/10 1.21 94.46 −5.08 22.99 Ag-20 635/2/10 1.29 93.27 −5.41 22.51 Ag-19 575/3/10 1.33 94.25 −5.38 25.07 Ag-12 625/1/10 1.34 65.54 23.63 19.56 Ag-12 625/1/10 1.32 71.17 21.05 19.63 Ag-12 635/0.5/10 1.35 71.32 13.82 13.62 Ag-1 625/3/PHAC 1.32 65.21 24.02 22.49 Ag-12 635/0.5/10 1.35 64.18 18.22 17.04 Ag-12 635/0.3/10 1.35 79.6 9.04 7.31 Ag-13 635/0.3/10 1.34 38.54 15.27 11 Ag-12 635/0.5/10 1.34 80.09 10.51 7.99 Ag-12 630/0.7/10 1.37 72.96 14.97 10.44 Ag-12 630/0.7/10 0.57 87.75 6.18 4.56 Ag-13 650/0.5/10 1.36 4.61 15.13 5.16 Ag-22 625/0.5/10 1.29 74.16 17.2 20.72 Ag-21 (450/1/10) + 1.26 60.75 10.74 2.34 (635/0.6/10) Ag-24 (450/1/10) + 1.26 81.63 5.11 0.83 (635/0.6/10) Ag-21 625/1/10 1.33 21.04 16.09 2.81 Ag-24 625/1/10 1.35 69.03 7.33 0.15 Ag-20 635/0.6/10 1.28 89.93 6.67 9.6 Ag-21 635/0.6/10 1.28 51.58 13.43 4.69 Ag-24 635/0.6/10 1.27 78.17 7.73 2.76 Ag-21 600/3/10 1.27 24.57 12.39 7.72 Ag-19 635/1/10 1.28 84.58 3.58 3.24 Ag-21 635/1/10 1.26 40.14 10.14 −0.13 Ag-24 635/1/10 1.29 78.27 4.37 −0.11 Ag-20 640/0.5/10 1.27 89.29 7.12 9.32 Ag-21 640/0.5/10 1.28 39.19 13.64 0.14 Ag-22 640/0.5/10 1.26 67.68 20.56 21.8 Ag-13 650/0.5/10 0.55 50.65 20.25 15.66

As indicated in FIG. 48 , the resultant colored glass articles may be grouped into regions of the a*-b* plot according to the hue of the colored glass article. That is, colored glass articles having similar color hues have combinations of discrete a* and b* values that fall within the same region of the a*-b* plot. In particular, colored glass articles that appear yellow have a*, b* values that fall within the region defined by the intersection of four lines: b*=0.2879·a*+27.818 (line A); b*=7.0833·a*−94.5 (line B); b*=0.45·a*+104.5 (line C); and b*=15.3·a*+253 (line D). The region defined by the intersection lines A, B, C, and D can be referred to as the “yellow region” and colored glass articles having combinations of discrete a* and b* values falling within this region will generally appear yellow.

Similarly, colored glass articles that appear orange have a*, b* values that fall within the region defined by the intersection of four lines: b*=7.0833·a*−94.5 (line B); b*=−0.9583·a*+146.75 (line E); b*=2.6957·a*−50.565 (line F); and b*=33 (line G). The region defined by the intersection lines B, E, F, and G can be referred to as the “orange region” and colored glass articles having combinations of discrete a* and b* values falling within this region will generally appear orange.

Still referring to FIG. 48 , colored glass articles that appear red have a*, b* values that fall within the region defined by the intersection of four lines: b*=2.6957·a*−50.565 (line F); a*=54 (line H); b*=1.0769·a*−17.154 (line I); and b*=6.6667·a*−173.67 (line J). The region defined by the intersection lines F, H, I, and J can be referred to as the “red region” and colored glass articles having combinations of discrete a* and b* values falling within this region will generally appear red.

Colored glass articles that appear green have a*, b* values that fall within the region defined by the intersection of four lines: b*=0.2879·a*+27.818 (line A); a*=0 (line K); b*=−1.375·a*+1 (line L); and b*=9.333·a*+86.667 (line M), exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5. The region defined by the intersection lines A, L, K, and M can be referred to as the “green region” and colored glass articles having combinations of discrete a* and b* values falling within this region will generally appear green.

Colored glass articles that appear pink/purple have a*, b* values that fall within the region defined by the intersection of four lines: b*=0.0833·a*+20.833 (line N); b*=2.1182·a*−32.073 (line O); b*=−0.3 (line P); and b*=1.5929·a*−0.3 (line Q), exclusive of a* greater than −0.3 and less than 0.3 and exclusive of b* greater than −0.5 and less than 0.5. The region defined by the intersection lines N, O, P, and Q can be referred to as the “pink/purple region” and colored glass articles having combinations of discrete a* and b* values falling within this region will generally appear pink/purple.

Referring now to Table 19, colored glass articles in the form of glass coupons were produced from the glass compositions of Tables 15 and 16. The glass coupons had thicknesses from ˜0.5 mm to ˜1.4 mm and were heat treated at various times and temperatures (as specified in Table 19) to produce colored glass articles with different color hues. PHCFR means that the glass coupon was placed directly into a pre-heated furnace, held for the indicated time, at which point the furnace was switched off and the glass coupon was cooled in the furnace at the cooling rate of the furnace (typically 2-3° C./minute). PHAC means that the glass coupon was placed directly into a pre-heated furnace, held for the indicated time, then removed and allowed to cool back to room temperature in ambient air. The CIELAB L*, a*, and b* coordinates of each colored glass article were determined. The average transmittance (%) for each sample over the wavelength range from 380 nm to 750 nm was also determined. The results are reported in Table 19.

TABLE 19 Heat Treatment (Temp (° C.)/Time Average Visible (hours)/Ramp Rate Thickness Transmittance Example (° C./min)) (mm) % (380-750 nm) L* a* b* Ag-10 575/2/10 1.28 86.1 95.61 −2.57 10.47 Ag-10 575/2/10 1.33 85.8 95.5 −2.51 10.73 Ag-12 575/2/10 1.30 83.4 95.46 −4.72 15.2 Ag-12 575/2/10 1.31 82.5 95.21 −4.78 16.2 Ag-10 600/1/10 1.29 82.6 94.06 −0.93 15.68 Ag-10 600/1/10 1.29 86.2 95.27 −1.08 9.58 Ag-11 600/1/10 1.32 44.0 71.5 21.65 110.29 Ag-11 600/1/10 1.33 43.1 70.48 23.07 110.67 Ag-12 600/2/10 1.34 62.0 82.02 14.23 39.93 Ag-12 600/2/10 1.31 62.3 82.6 12.96 41.47 Ag-10 600/3/10 1.33 64.4 88.3 −2.26 65.85 Ag-10 600/3/10 1.29 69.5 90.44 −3.88 51.15 Ag-11 600/3/10 1.32 24.6 43.41 41.48 73.52 Ag-11 600/3/10 1.34 30.5 53.38 36.16 89.47 Ag-12 600/3/10 1.32 49.3 71.89 26.88 63.17 Ag-12 600/3/10 1.33 50.0 72.44 26.28 61.16 Ag-11 575/2/10 1.29 51.8 80.43 5.3 94.46 Ag-11 575/2/10 1.32 52.6 81.29 3.96 93.62 Ag-12 600/1/10 1.36 76.5 89.88 5.59 16.84 Ag-12 600/1/10 1.30 76.2 90.36 4.53 20.01 Ag-10 600/2/10 1.31 77.1 92.72 −2.81 29.07 Ag-10 600/2/10 1.28 76.4 92.55 −3.22 30.79 Ag-11 600/2/10 1.30 36.2 61.58 30.81 101 Ag-11 600/2/10 1.32 35.4 60.37 32.13 100.26 Ag-10 625/1/10 1.33 74.6 90.4 3.5 27.63 Ag-10 625/1/10 1.34 70.9 88.67 5.26 33.93 Ag-11 625/1/10 1.33 34.4 56.78 40.08 95.88 Ag-11 625/1/10 1.35 35.2 58.43 38.04 98.02 Ag-12 625/1/10 1.34 45.9 65.54 23.63 19.56 Ag-12 625/1/10 1.32 52.4 71.17 21.05 19.63 Ag-10 635/0.5/10 1.32 76.2 89.49 7.4 15.81 Ag-12 635/0.5/10 1.35 50.0 71.32 13.82 13.62 Ag-10 625/2/10 1.32 59.4 83.97 7.32 53.78 Ag-10 625/2/10 1.32 53.9 79.43 12.07 62 Ag-11 625/2/10 1.31 16.8 21.62 46.36 36.66 Ag-11 625/2/10 1.30 19.2 28.68 48.69 48.74 Ag-12 625/2/10 1.31 24.2 40.92 34.87 38.77 Ag-12 625/2/10 1.31 26.3 40.9 42.34 45.72 Ag-16 as made 0.60 88.7 95.09 4.58 −1.73 Ag-16 575/0.33/10 0.57 86.5 94.76 3.32 1.91 Ag-16 565/0.25/10 0.60 88.1 95 4.26 −0.83 Ag-16 as made 1.34 86.3 93.7 8.44 −3.23 Ag-16 575/0.33/10 1.32 77.1 92.03 3.62 13.15 Ag-16 565/0.25/10 1.32 85.2 93.51 7.83 −1.61 Ag-16 as made 2.06 84.4 92.66 10.98 −4.12 Ag-16 575/0.33/10 2.03 77.6 91.28 7.96 6.77 Ag-16 565/0.25/10 2.04 82.1 92.25 9.9 −0.62 Ag-28 600/0.5/ 1.26 63.2 89.41 −8.22 57.36 PHCFR Ag-28 600/0.25/ 1.31 72.2 93.01 −7.93 33.76 PHCFR Ag-28 600/0.75/ 1.35 54.9 83.95 −2.24 85.2 PHCFR Ag-28 600/1/ 1.32 50.1 79.51 4.83 96 PHCFR Ag-28 600/1.25/ 1.31 42.4 69.76 24.11 109.37 PHCFR Ag-28 600/1.5/ 1.31 31.2 46.01 53.51 77.81 PHCFR Ag-1 600/1/PHAC 1.30 81.9 94.18 −1.61 17.89 Ag-9 600/1/PHAC 1.31 49.3 77.86 12.16 106.74 Ag-1 600/2/PHAC 1.31 61.0 81.94 14.76 45.2 Ag-9 600/2/PHAC 1.31 45.5 73.48 18.67 108.37 Ag-1 600/3/PHAC 1.32 41.6 60.97 36.89 57.26 Ag-9 600/3/PHAC 1.31 22.8 37.09 48.11 62.4 Ag-1 625/1/PHAC 1.27 68.7 84.18 6.08 9.04 Ag-9 625/1/PHAC 1.31 56.5 79.96 15.43 62.16 Ag-1 625/2/PHAC 1.33 26.8 43.55 32.19 26.91 Ag-9 625/2/PHAC 1.32 39.5 61.72 41.44 100.95 Ag-1 625/3/PHAC 1.32 45.8 65.21 24.02 22.49 Ag-9 625/3/PHAC 1.29 20.9 27.58 50.33 46.01 Ag-9 650/1/PHAC 1.32 37.5 57.39 33.25 43.5 Ag-1 650/1/PHAC 1.31 44.7 72.34 1.09 29.03 Ag-9 as made 1.30 92.2 96.88 −0.02 −0.01 Ag-1 as made 1.31 92.2 96.92 −0.01 0.09 Ag-1 575/1/PHAC 1.30 86.9 96.33 −2.88 7.92 Ag-9 575/1/PHAC 1.33 87.9 96.22 −1.88 6.36 Ag-1 600/0.5/10 1.32 80.0 92.34 2.78 16.14 Ag-9 600/0.5/10 1.33 52.2 72.32 25.62 43.19 Ag-1 600/1/10 1.29 50.2 78.31 13 104.03 Ag-9 600/1/10 1.31 70.1 86.43 9.77 25.5 Ag-1 600/2/10 1.33 33.9 54.05 46.56 90.95 Ag-9 600/2/10 1.31 25.0 40.56 48.66 68.35 Ag-1 600/3/10 1.32 39.4 57.71 37.75 53.96 Ag-9 600/3/10 1.32 31.1 49.88 47.94 84.03 Ag-12 635/0.5/10 1.35 41.5 64.18 18.22 17.04 Ag-13 635/0.5/10 0.59 41.4 65.97 −1.78 6.53 Ag-10 635/0.33/10 1.34 74.0 87.67 9.78 15.76 Ag-10 635/0.33/10 0.62 84.3 93.14 3.83 6.38 Ag-11 635/0.33/10 1.36 39.5 63.67 36.89 105.88 Ag-11 635/0.33/10 0.59 50.1 69.96 15.42 24.46 Ag-29 635/0.33/10 1.34 85.1 94.52 0.48 9.73 Ag-29 635/0.33/10 0.61 87.4 95.33 0.21 6.61 Ag-12 635/0.33/10 1.35 61.6 79.6 9.04 7.31 Ag-12 635/0.33/10 0.61 78.5 89.9 3.47 3.3 Ag-13 635/0.33/10 1.34 20.6 38.54 15.27 11 Ag-13 635/0.33/10 0.61 50.9 78.07 16.01 101.22 Ag-10 635/0.5/10 1.34 74.7 88.54 8.59 17.4 Ag-10 635/0.5/10 0.59 80.1 91.15 5.96 10.8 Ag-11 635/0.5/10 1.32 36.8 60 39.32 100.53 Ag-11 635/0.5/10 0.59 48.5 76.1 18.64 111.37 Ag-29 635/0.5/10 1.34 86.7 95.37 −0.8 8.8 Ag-29 635/0.5/10 0.61 87.2 95.46 −0.63 8.11 Ag-12 635/0.5/10 1.34 63.3 80.09 10.51 7.99 Ag-12 635/0.5/10 0.60 80.3 90.61 4.01 3.43 Ag-10 630/0.66/10 1.35 72.0 87.8 8.65 22.02 Ag-10 630/0.66/10 0.59 76.8 89.84 7.04 15.34 Ag-11 630/0.66/10 1.35 27.9 43.57 50.81 73.87 Ag-11 630/0.66/10 0.59 42.0 67.2 32.97 110.25 Ag-29 630/0.66/10 1.36 83.9 94.65 −1.36 13.6 Ag-29 630/0.66/10 0.57 89.2 96.13 −0.64 4.96 Ag-12 630/0.66/10 1.37 53.7 72.96 14.97 10.44 Ag-12 630/0.66/10 0.57 75.6 87.75 6.18 4.56 Ag-13 630/0.66/10 1.34 3.2 17.64 −0.13 9.52 Ag-13 630/0.66/10 0.57 18.2 48.85 1.57 10.55 Ag-10 650/0.5/10 1.35 65.2 85.98 3.06 28.27 Ag-10 650/0.5/10 0.57 77.8 93.1 −2.63 16.08 Ag-11 650/0.5/10 1.35 24.5 34.47 49.12 57.71 Ag-11 650/0.5/10 0.56 38.4 61.12 27.94 74.46 Ag-29 650/0.5/10 1.35 71.1 93.59 −10.87 39.72 Ag-29 650/0.5/10 0.58 80.9 95.83 −6.92 18.3 Ag-12 650/0.5/10 1.33 35.2 61.52 12.86 25.33 Ag-12 650/0.5/10 0.57 59.8 80.08 6.11 13.24 Ag-13 650/0.5/10 1.36 2.1 4.61 15.13 5.16 Ag-13 650/0.5/10 0.55 26.0 50.65 20.25 15.66 Ag-13 635/0.6/10 0.50 39.8 68.86 −5.21 8.63 Ag-13 635/0.6/10 0.50 38.1 69.02 −4.23 10.36 Ag-19 625/0.5/10 1.28 81.6 91.48 −0.24 1.94 Ag-20 625/0.5/10 1.28 89.1 95.5 1.16 2.16 Ag-21 625/0.5/10 1.28 18.7 40.92 11.24 24.65 Ag-22 625/0.5/10 1.29 55.2 74.16 17.2 20.72 Ag-23 625/0.5/10 1.28 58.9 86.72 −2.66 91.23 Ag-24 625/0.5/10 1.27 75.7 89.09 2.7 2.71 Ag-19 (450/1 + 635/ 1.25 66.2 85.08 1.93 7.48 0.6)/10 Ag-20 (450/1 + 635/ 1.23 80.2 90.59 5.45 5.91 0.6)/10 Ag-21 (450/1 + 635/ 1.26 34.5 60.75 10.74 2.34 0.6)/10 Ag-22 (450/1 + 635/ 1.26 29.2 48.41 27.84 24.6 0.6)/10 Ag-23 (450/1 + 635/ 1.25 52.3 81.15 6.31 103.91 0.6)/10 Ag-24 (450/1 + 635/ 1.26 64.8 81.63 5.11 0.83 0.6)/10 Ag-19 575/2/10 1.19 88.5 96.2 −1.67 5.92 Ag-20 575/2/10 1.18 88.8 96.23 −1.37 6.17 Ag-21 575/2/10 1.16 67.3 90.82 −7.55 56.94 Ag-22 575/2/10 1.20 73.4 91.99 −4.71 37.28 Ag-23 575/2/10 1.23 65.7 90.94 −9.74 52.14 Ag-24 575/2/10 1.21 80.3 94.46 −5.08 22.99 Ag-19 575/3/10 1.33 79.0 94.25 −5.38 25.07 Ag-20 575/3/10 1.36 87.2 95.79 −1.76 8.63 Ag-21 575/3/10 1.35 48.1 75.48 20.79 106.6 Ag-22 575/3/10 1.34 50.3 78.23 13.57 100.58 Ag-23 575/3/10 1.35 54.8 83.93 −2.13 87.35 Ag-24 575/3/10 1.34 69.8 89.53 1.16 40.46 Ag-19 600/1/10 1.31 87.2 94.83 1.61 4.63 Ag-20 600/1/10 1.32 88.3 95.72 −0.04 5.54 Ag-21 600/1/10 1.33 54.1 74.55 21.53 41.51 Ag-22 600/1/10 1.31 62.5 83.83 10.63 46.05 Ag-23 600/1/10 1.33 61.7 88.97 −7.73 76.89 Ag-24 600/1/10 1.31 81.0 91.25 4.02 7.41 Ag-19 625/0.75/10 1.35 67.6 83.95 3.26 8.39 Ag-20 625/0.75/10 1.37 83.2 93.23 2.8 9.89 Ag-21 625/0.75/10 1.37 7.7 14.26 16.11 14.63 Ag-22 625/0.75/10 1.37 54.0 73.76 18.6 26.67 Ag-23 625/0.75/10 1.37 49.0 77.37 13.14 107.83 Ag-24 625/0.75/10 1.36 76.2 89.09 3.18 2.61 Ag-19 625/1/10 1.34 71.6 86.86 3.84 2.74 Ag-20 625/1/10 1.34 81.7 91.97 4.78 9 Ag-21 625/1/10 1.33 6.9 21.04 16.09 2.81 Ag-22 625/1/10 1.35 37.4 57.25 32.53 43.57 Ag-23 625/1/10 1.35 17.4 32.52 37.79 42.15 Ag-24 625/1/10 1.35 46.9 69.03 7.33 0.15 Ag-19 625/2/10 1.36 56.7 77.84 3.78 3.15 Ag-20 625/2/10 1.37 61.3 83.21 9.05 39.01 Ag-21 625/2/10 1.36 1.7 6.03 5.89 6.3 Ag-22 625/2/10 1.35 24.2 39.71 34.72 46.35 Ag-23 625/2/10 1.37 1.0 0.84 1.4 −0.02 Ag-24 625/2/10 1.37 20.6 49.68 7.22 18.91 Ag-19 635/0.6/10 1.27 78.4 90.97 0.85 2.76 Ag-20 635/0.6/10 1.28 78.5 89.93 6.67 9.6 Ag-21 635/0.6/10 1.28 24.9 51.58 13.43 4.69 Ag-22 635/0.6/10 1.28 47.7 67.94 22.47 27.95 Ag-23 635/0.6/10 1.26 44.4 69.96 24.92 104.44 Ag-24 635/0.6/10 1.27 58.0 78.17 7.73 2.76 Ag-19 650/0.33/10 1.31 48.7 75.06 5.45 37.69 Ag-20 650/0.33/10 1.32 69.6 86.53 4.09 15.65 Ag-21 650/0.33/10 1.31 15.4 40.77 8.5 13.14 Ag-22 650/0.33/10 1.32 38.6 61.55 16.07 24.77 Ag-23 650/0.33/10 1.32 55.2 83.6 3.6 98.53 Ag-24 650/0.33/10 1.31 60.4 79.86 1.57 0.06 Ag-19 575/4/10 1.35 62.5 83.86 10.63 45.29 Ag-20 575/4/10 1.35 80.8 94.03 −2.99 21.48 Ag-21 575/4/10 1.36 31.9 46 51.36 75.97 Ag-22 575/4/10 1.37 40.8 66.13 32.1 107.91 Ag-23 575/4/10 1.37 38.5 61.84 37.63 102.88 Ag-24 575/4/10 1.35 53.1 73.2 19.64 35.14 Ag-19 600/2/10 1.27 65.2 81.77 8.74 17.89 Ag-20 600/2/10 1.28 86.8 95.38 −0.5 8.66 Ag-21 600/2/10 1.27 19.1 25.15 38.39 41.98 Ag-22 600/2/10 1.28 41.8 64.47 34.95 82.43 Ag-23 600/2/10 1.25 37.3 58.86 39.89 98.15 Ag-24 600/2/10 1.27 67.2 83.23 7.5 10.6 Ag-19 600/3/10 1.26 52.0 71.68 13.7 17.07 Ag-20 600/3/10 1.29 84.2 94.77 −1.5 14.51 Ag-21 600/3/10 1.27 9.3 24.57 12.39 7.72 Ag-22 600/3/10 1.24 39.5 62.11 37.06 96.27 Ag-23 600/3/10 1.23 21.5 35.28 29.5 16.99 Ag-24 600/3/10 1.27 61.5 79.25 9.59 9.6 Ag-19 615/0.5/10 1.33 86.3 94.4 1.3 5.3 Ag-20 615/0.5/10 1.31 88.3 95.29 1.21 3.5 Ag-21 615/0.5/10 1.35 40.0 63.83 21.26 79.15 Ag-22 615/0.5/10 1.34 65.7 82.74 12.56 22.42 Ag-23 615/0.5/10 1.33 64.2 90.72 −11.12 66.64 Ag-24 615/0.5/10 1.36 83.7 92.44 1.04 2.52 Ag-19 615/1/10 1.27 80.4 90.96 0.89 3.45 Ag-20 615/1/10 1.28 87.9 95.27 1.06 4.77 Ag-21 615/1/10 1.30 25.5 48.52 11.08 17.34 Ag-22 615/1/10 1.31 30.2 45.53 48.19 73.96 Ag-23 615/1/10 1.29 50.1 78.19 13.1 108.41 Ag-24 615/1/10 1.28 79.9 90.88 2.5 3.31 Ag-19 635/1/10 1.28 67.1 84.58 3.58 3.24 Ag-20 635/1/10 1.30 80.7 91.4 5.14 8.57 Ag-21 635/1/10 1.26 17.2 40.14 10.14 −0.13 Ag-22 635/1/10 1.27 35.1 54.92 30.14 34.44 Ag-23 635/1/10 1.27 15.8 29.58 37.33 46.53 Ag-24 635/1/10 1.29 59.5 78.27 4.37 −0.11 Ag-19 635/2/10 1.27 36.9 65.94 −0.53 17.41 Ag-20 635/2/10 1.29 76.6 93.27 −5.41 22.51 Ag-21 635/2/10 1.26 0.4 1.28 1.76 1.45 Ag-22 635/2/10 1.28 25.2 42.76 29.96 47.39 Ag-23 635/2/10 1.27 1.4 3.97 1.91 −0.02 Ag-24 635/2/10 1.30 44.3 71.69 3.05 12.22 Ag-19 640/0.5/10 1.30 49.2 72.62 5.98 9.06 Ag-20 640/0.5/10 1.27 77.5 89.29 7.12 9.32 Ag-21 640/0.5/10 1.28 14.4 39.19 13.64 0.14 Ag-22 640/0.5/10 1.26 47.6 67.68 20.56 21.8 Ag-23 640/0.5/10 1.25 47.4 73.27 21.82 101.59 Ag-24 640/0.5/10 1.28 71.6 86.14 4.05 0.38 Ag-19 650/0.5/10 1.31 59.2 81.01 3.36 10.21 Ag-20 650/0.5/10 1.31 76.7 93.44 −5.26 21.04 Ag-21 650/0.5/10 1.32 5.3 20.93 4.42 17.31 Ag-22 650/0.5/10 1.31 27.8 47.96 24.34 42.2 Ag-23 650/0.5/10 1.29 48.8 77.89 7.06 92.68 Ag-24 650/0.5/10 1.29 29.3 62.01 −3.99 25.51 Ag-24 645/0.5/10 1.22 22.6 53.04 −2.71 16.67

Tables 20A-20D show example glass compositions (in terms of mol %) containing transition metal oxides and/or rare earth oxides as colorant(s), including the total amount of transition metal oxides and/or rare earth oxides present (i.e., Sum “TM+RE”).

TABLE 20A Example (mol %) TM-1 TM-2 TM-3 TM-4 TM-5 TM-6 TM-7 TM-8 TM-9 TM-10 SiO₂ 61.74 60.04 61.06 61.24 61.2 60.38 59.54 61.59 61.62 61.34 Al₂O₃ 15.04 15.86 15.39 15.39 15.42 15.51 15.98 15.28 15.09 15.32 B₂O₃ 6.06 6.19 6.05 5.95 5.9 5.93 5.9 6.01 5.94 5.94 Li₂O 9.03 8.93 8.94 9.93 9.95 8.65 8.69 9.28 9.3 9.39 Na₂O 1.41 1.4 1.4 1.5 1.5 1.41 1.52 1.38 1.47 1.46 K₂O 0.2 0.2 0.2 0.2 0.2 0.2 0.19 0.2 0.2 0.2 CaO 5.25 6.12 3.84 1.32 2.53 3.83 1.88 4.16 4.19 4.25 MgO 0.99 1 2.88 4.24 3.08 2.88 5.05 1.89 1.9 1.93 NiO 0.0154 0.0178 0.0170 0.0161 0.0154 0.0000 0.0000 0.0163 0.0000 0.0234 Co₃O₄ 0.0001 0.0001 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0023 0.0094 Cr₂O₃ 0.0297 0.0287 0.0272 0.0280 0.0266 0.0008 0.0008 0.0256 0.0000 0.0000 CuO 0.2207 0.1959 0.1906 0.1750 0.1758 0.0008 0.0000 0.1638 0.2810 0.1165 CeO₂ 0.0000 0.0000 0.0000 0.0000 0.0000 0.2100 0.2100 0.0000 0.0000 0.0000 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.99 1.02 0.01 0.01 0.01 Sum 0.2759 0.2525 0.2449 0.2291 0.2278 1.2016 1.2308 0.2157 0.2933 0.1593 TM + RE

TABLE 20B Example (mol %) TM-11 TM-12 TM-13 TM-14 TM-15 TM-16 TM-17 TM-18 TM-19 TM-20 SiO₂ 61.06 61.24 61.14 61.48 61.47 61.13 61.11 61.32 61.1 61.18 Al₂O₃ 15.39 15.39 15.41 15.58 14.54 14.65 15.75 15.29 14.87 14.65 B₂O₃ 6.05 5.95 5.91 6.03 5.92 5.9 5.79 5.84 5.95 6.14 Li₂O 8.94 9.93 9.96 9.69 9.92 10 9.24 9.35 9.96 10.05 Na₂O 1.4 1.5 1.49 1.48 1.83 1.83 1.36 1.47 1.86 1.86 K₂O 0.2 0.2 0.2 0.2 0.19 0.19 0.17 0.2 0.2 0.19 CaO 3.84 1.32 3.74 1.31 1.99 2.03 4.31 4.23 2.06 2.02 MgO 2.88 4.24 1.92 4.22 1.92 1.94 2.01 1.99 1.98 1.94 NiO 0.0170 0.0161 0.0164 0.0000 0.0000 0.0000 0.0215 0.0000 0.0000 0.0000 Co₃O₄ 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0025 0.0000 0.0000 Cr₂O₃ 0.0272 0.0280 0.0269 0.0000 0.0000 0.0000 0.0270 0.0000 0.0000 0.0000 CuO 0.1906 0.1750 0.1693 0.0000 0.0000 0.0000 0.1761 0.2642 0.0000 0.0000 CeO₂ 0.0000 0.0000 0.0000 0.0000 0.2000 0.2100 0.0000 0.0000 0.4200 0.4100 TiO₂ 0.01 0.01 0.01 0.01 0.99 0.99 0.01 0.05 1.01 1 Sum 0.2449 0.2291 0.2226 0.0100 1.1900 1.2000 0.2346 0.3167 1.4300 1.4100 TM + RE

TABLE 20C Example TM-21 TM-22 TM-23 SiO₂ 61.42 61.39 61.04 Al₂O₃ 14.92 14.87 14.73 B₂O₃ 5.62 5.78 5.8 Li₂O 9.91 9.85 9.94 Na₂O 1.87 1.86 1.84 K₂O 0.2 0.2 0.19 CaO 2.06 2.06 2.03 MgO 1.99 1.97 1.95 NiO 0.0000 0.0000 0.0000 Co₃O₄ 0.0000 0.0000 0.0000 Cr₂O₃ 0.0000 0.0000 0.0000 CuO 0.0000 0.0000 0.0000 CeO₂ 0.4200 0.4200 0.4200 TiO₂ 1.02 1.02 1.01 Sum 1.4400 1.4400 1.4300 TM + RE

TABLE 20D Example (mol %) TM-24 TM-25 TM-26 TM-27 TM-28 TM-29 TM-30 TM-31 TM-32 TM-33 TM-34 SiO₂ 58.63 59.17 58.78 58.51 58.74 59.71 60.28 58.31 60.15 59.03 61.64 Al₂O₃ 16.38 16.61 16.52 16.52 16.30 16.46 16.48 16.41 15.79 16.35 15.05 B₂O₃ 6.05 5.71 5.95 6.06 6.09 5.95 6.08 5.94 6.14 5.85 5.87 Li₂O 9.95 11.13 10.91 10.50 10.05 10.45 10.24 9.70 8.95 11.86 12.03 Na₂O 4.28 5.76 5.23 4.77 4.27 4.78 4.29 4.24 1.41 6.32 3.93 K₂O 0.20 0.19 0.19 0.20 0.19 0.20 0.20 0.20 0.20 0.19 0.39 MgO 0.04 0.02 0.03 0.04 0.05 0.03 0.03 0.04 1.98 0.08 0.02 ZnO 3.96 0.99 2.00 3.01 3.92 1.99 2.00 3.96 5.01 0.00 0.75 SnO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.98 0.01 0.00 0.01 Fe₂O₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.01 0.00 NiO 0.00 0.01 0.01 0.01 0.01 0.01 0.01 0.00 0.02 0.01 0.01 Co₃O₄ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Cr₂O₃ 0.00 0.03 0.03 0.03 0.03 0.03 0.03 0.00 0.03 0.03 0.02 CuO 0.33 0.22 0.19 0.21 0.20 0.23 0.22 0.00 0.20 0.17 0.17 Sum 0.34 0.27 0.24 0.26 0.25 0.27 0.26 0.00 0.25 0.21 0.20 TM + RE

Tables 21A-21C show the dielectric constant (calculated) and dielectric constant (as measured at 10 GHz) for select examples from Tables 20A-20D. When calculated, the dielectric constant was calculated according to the formula: Dk=3.802946+0.01747*B₂O₃ (mol %)+0.058769*Al₂O₃ (mol %)+0.080876*Li₂O (mol %)+0.148433*Na₂O (mol %)+0.153264*K₂O (mol %)+0.045179*MgO (mol %)+0.080113*CaO (mol %). Where measured, the dielectric constant was measured using a split post dielectric resonator (SPDR at a frequency of 10 GHz. Tables 21A-21C also show the CIELAB L*, a*, and b* coordinates for select examples from Tables 20A-2D at the indicated thickness.

TABLE 21A Example TM-1 TM-2 TM-3 TM-4 TM-5 TM-6 TM-7 TM-8 TM-9 TM-10 Dk 6.2283 6.3393 6.2123 6.1651 6.2121 6.1945 6.1815 6.2106 6.2161 6.2415 Relationship (calculated) Dk 6.13 6.23 6.18 6.15 6.19 6.29 6.21 6.22 (measured at 10 GHz) L* 90.61 92.48 88.24 a* −8.02 −4.39 −1.61 b* 4.61 −3.85 −4.42 Thickness 1.32 1.38 1.36 (mm)

TABLE 21B Example TM-11 TM-12 TM-13 TM-14 TM-15 TM-16 TM-17 TM-18 TM-19 TM-20 Dk 6.2123 6.1651 6.2555 6.1535 6.1101 6.1268 6.2410 6.2374 6.1475 6.1387 Relationship (calculated) Dk (measured at 10 GHz) L* 90.14 90.81 90.81 96.81 96.68 96.63 89.23 92.76 96.11 96.11 a* −8.48 −7.43 −7.6 −0.02 −0.4 −0.39 −7.87 −4.26 −1.36 −1.36 b* 4.91 4.98 4.79 0.2 1.28 1.47 3.88 −3.53 4.76 4.76 Thickness 1.38 1.34 1.34 1.32 1.34 1.34 1.32 1.37 1.34 1.34 (mm)

TABLE 21C Example TM-21 TM-22 TM-23 TM-24 TM-28 TM-31 Dk 6.1426 6.1352 6.1268 Relationship (calculated) Dk 6.42 6.52 6.67 (measured at 10 GHz) L* 96.11 96.11 96.22 a* −1.36 −1.36 −1.3 b* 4.76 4.76 4.44 Thickness 1.34 1.34 1.36 (mm)

Tables 22A and 22B show the ion exchange characteristic (CS, DOL, and CT) for select glass articles from Tables 20A-20D at different thicknesses and ion exchange conditions (temperature, time, and ion exchange bath compositions).

TABLE 22A Thickness Temp Time KNO₃ NaNO₃ LiNO₃ CS DOL CT Example (mm) (° C.) (hrs.) (wt. %) (wt. %) (wt. %) (MPa) (μm) (MPa) TM-24 0.6 440 6.5 79.2 19.4 1.4 599 5.62 104.67 TM-25 0.6 430 4 79 19.4 1.6 633 6.02 129.51 TM-26 0.6 430 4 79 19.4 1.6 661 5.03 124.41 TM-27 0.6 430 4 79 19.4 1.6 700 3.83 119.67 TM-28 0.6 430 4 79 19.4 1.6 684 3.97 117.14 TM-28 0.6 430 8 79 19.4 1.6 615 4.79 131.67 TM-28 0.6 430 16 79 19.4 1.6 559 6.82 97.64 TM-28 0.6 440 6 79 19.4 1.6 600 5.29 109.95 TM-28 0.6 440 6 79.2 19.4 1.4 651 4.67 108.80 TM-28 0.6 440 7 79.2 19.4 1.4 600 5.40 110.20 TM-28 0.6 440 6.5 79.2 19.4 1.4 589 5.56 105.80 TM-29 0.6 430 4 79 19.4 1.6 643 5.56 142.52 TM-30 0.6 430 4 79 19.4 1.6 681 5.24 127.46 TM-31 0.6 440 6 79 19.4 1.6 657 4.51 116.22 TM-31 0.6 440 6 79.2 19.4 1.4 613 5.10 124.20 TM-31 0.6 440 7 79.2 19.4 1.4 633 5.00 120.90 TM-31 0.6 440 6.5 79.2 19.4 1.4 640 5.17 124.90 TM-32 0.6 450 4 90 10 0 902 3.52 110 TM-32 0.6 450 8 90 10 0 832 4.52 160 TM-32 0.6 450 12 90 10 0 758 5.62 191 TM-32 0.6 450 8 89 10 1 773 3.54 110 TM-32 0.6 450 12 89 10 1 673 4.65 138 TM-32 0.6 450 8 88.5 10 1.5 695 3.64 96 TM-32 0.6 450 12 88.5 10 1.5 639 4.17 109 TM-13 0.6 450 4 90 10 0 900 3.99 133 TM-13 0.6 450 8 90 10 0 786 5.61 187 TM-13 0.6 450 12 90 10 0 721 7.55 174 TM-13 0.6 450 8 89 10 1 721 4.89 139 TM-13 0.6 450 12 89 10 1 661 5.76 143 TM-13 0.6 450 8 88.5 10 1.5 704 4.39 114 TM-13 0.6 450 12 88.5 10 1.5 636 5.69 113

TABLE 22B Thickness Temp Time KNO₃ NaNO₃ LiNO₃ CS DOL CT Example (mm) (° C.) (hrs.) (wt. %) (wt. %) (wt. %) (MPa) (μm) (MPa) TM-33 1.33 400 16 89 10 1 672 9.1 72 TM-33 1.33 400 24 89 10 1 627 11.2 78 TM-33 1.33 430 8 80 20 0 518 11.6 97 TM-33 0.6 380 8 79 18.7 2.3 641 4.1 100 TM-33 0.6 380 10 79 18.7 2.3 612 4.7 102 TM-33 0.6 380 12 79 18.7 2.3 599 5.2 100 TM-33 0.6 410 4 79 19.5 1.5 633 5.3 109 TM-33 0.6 410 5 79 19.5 1.5 612 5.9 108 TM-33 0.6 410 6 79 19.5 1.5 601 6.1 107 TM-33 0.6 400 5 79 19.8 1.2 695 5.0 112 TM-33 0.6 400 5 79 20.1 0.9 671 5.3 116 TM-33 0.6 400 5 79 19.4 1.6 645 5.0 107 TM-33 0.6 430 2.5 79 19.4 1.6 591 6.0 101 TM-33 0.6 430 3 79 19.4 1.6 569 6.1 98 TM-33 0.6 430 3.5 79 19.4 1.6 557 6.8 96 TM-33 0.6 430 2.5 75.6 24 0.4 609 6.41 126 TM-33 0.6 430 2.5 76 24 0 602 7.57 129 TM-33 0.55 400 3 79 19.8 1.2 749 3.69 108 TM-8 0.6 450 4 89.8 10 0.2 693 5.54 139 TM-8 0.6 450 4 89.8 10 0.2 637 7.54 134 TM-8 0.6 450 8 89.5 10 0.5 664 5.56 134 TM-8 0.6 450 8 88.5 11 0.5 661 5.59 138 TM-8 0.6 450 8 87.5 12 0.5 645 5.69 142 TM-8 0.6 450 8 86.5 13 0.5 636 5.74 145 TM-8 0.6 450 8 89.5 10 0.5 667 5.52 136 TM-8 0.55 450 6.75 87.3 12.5 0.2 668 5.64 140 TM-8 0.55 450 6.75 87.5 12.5 0 686 5.63 157 TM-8 0.6 440 8 88 11 1 667 4.32 121 TM-8 0.6 440 10 88 11 1 638 5.10 127 TM-8 0.6 440 12 88 11 1 614 5.64 129

Table 23 shows the fracture toughness (K_(IC)) for select examples from Tables 20A-20D and a comparative example of a non-colored glass article comprising 58.41 mol % SiO₂, 6.07 mol % B₂O₃, 17.84 mol % Al₂O₃, 1.73 mol % Na₂O, 0.20 mol % K₂O, 4.43 mol % MgO, 0.57 mol % CaO, 0.01 mol % SnO₂, and 10.71 mol % Li₂O. The fracture toughness was measured using the chevron notch short bar method and the dual cantilever beam method.

TABLE 23 K_(IC) CNSB K_(IC) DCB Example (MPa · m^(1/2)) (MPa · m¹²) TM-33 0.774 0.816 TM-8 0.8 0.839 TM-34 0.794 0.813 Comparative 0.786 0.877 Example

FIG. 50 shows the results of an incremental face drop on sandpaper (i.e., a “drop test”) for two different sandpaper conditions (180 grit) and (80 grit) for select examples from Tables 20A-20D and a comparative example of a non-colored glass article comprising 58.41 mol % SiO₂, 6.07 mol % B₂O₃, 17.84 mol % Al₂O₃, 1.73 mol % Na₂O, 0.20 mol % K₂O, 4.43 mol % MgO, 0.57 mol % CaO, 0.01 mol % SnO₂, and 10.71 mol % Li₂O. Prior to performing the drop test, the TM-33 samples were ion exchanged in a molten salt batch comprising 89.3 wt % KNO₃, 10 wt. % NaNO₃, and 0.7 wt. % LiNO₃ at 440° C. for 9 hours. The TM-8 samples were ion exchanged in a molten salt batch comprising 79 wt % KNO₃, 19.9 wt. % NaNO₃, and 1.6 wt. % LiNO₃ at 400° C. for 5 hours. The comparative examples were ion exchanged in a molten salt batch comprising 90.3 wt % KNO₃, 9 wt. % NaNO₃, and 0.7 wt. % LiNO₃ at 450° C. for 5 hours.

A typical drop test is schematically shown in FIG. 51 . Each sample 1310 was affixed to a standard test vehicle 1320, which approximates the size, mass, and balance of a generic “smart” phone, and dropped from a drop height h onto a sheet of sandpaper 1330 having an abrasive surface 1335. The drop height h ranged from about 0.2 meter to 2.2 meters in incremental heights of 0.1 meter. Drop testing was carried out using a 180-grit silicon carbide sandpaper surface and an 80 grit silicon carbide sandpaper surface. The drop performance is reported in terms of the maximum drop height in cm before failure of the colored glass article.

Tables 24A and 24B show example glass compositions (in terms of mol %) containing transition metal oxides and/or rare earth oxides as colorant(s) Tables 24A and 24B also show the dielectric constant (Dk, as measured at 10 GHz) for the example compositions.

TABLE 24A Example (mol %) TM-35 TM-36 TM-37 TM-38 TM-39 TM-40 TM-41 TM-42 TM-43 SiO₂ 58.5 59.5 59.6 59.2 59.1 61.1 61.5 59.1 59.3 Al₂O₃ 16.4 16.4 16.3 16.4 16.5 15.6 15.2 16.4 16.5 B₂O₃ 5.8 5.8 5.6 5.9 5.9 5.8 6.0 6.0 5.7 P₂O₅ 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Li₂O 11.8 9.2 8.7 9.4 9.0 9.3 8.2 9.4 8.8 Na₂O 6.1 3.8 3.3 3.8 3.3 3.8 1.2 3.7 3.3 K₂O 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 MgO 0.0 0.0 0.1 0.9 1.9 0.0 0.1 0.1 0.1 CaO 0.0 4.9 5.9 3.9 4.0 4.0 7.4 4.9 6.0 TiO₂ 1.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Fe₂O₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 CeO₂ 0.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NiO 0.00 0.02 0.01 0.02 0.02 0.02 0.02 0.03 0.03 Co₃O₄ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.01 Cr₂O₃ 0.00 0.03 0.03 0.03 0.03 0.03 0.03 0.00 0.00 CuO 0.00 0.16 0.16 0.16 0.16 0.16 0.16 0.12 0.13 Cl 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 Dk 6.7 6.44 6.44 6.43 6.39 6.37 6.23 6.47 6.46 (measured at 10 GHz)

TABLE 24B Example (mol %) TM-44 TM-45 TM-46 TM-47 TM-48 TM-49 TM-50 TM-51 TM-52 SiO₂ 59.7 58.9 61.1 61.8 62.5 62.5 62.5 62.1 60.2 Al₂O₃ 16.3 16.7 15.5 15.2 14.8 14.7 14.8 15.2 15.9 B₂O₃ 5.8 5.9 5.9 5.6 6.0 6.0 6.0 5.9 6.0 P₂O₅ 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Li₂O 9.3 8.9 9.4 8.3 8.9 8.9 9.0 8.9 8.8 Na₂O 3.7 3.3 3.8 1.2 1.4 1.4 1.4 1.4 1.4 K₂O 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 MgO 0.9 1.9 0.0 0.1 1.9 2.9 3.9 5.1 0.1 CaO 3.9 4.0 3.9 7.5 4.1 3.1 2.1 1.1 7.2 TiO₂ 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Fe₂O₃ 0.00 0.00 0.00 0.01 0.00 0.00 0.01 0.00 0.01 CeO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NiO 0.03 0.03 0.03 0.03 0.02 0.02 0.02 0.02 0.02 Co₃O₄ 0.01 0.01 0.01 0.01 0.00 0.00 0.00 0.00 0.00 Cr₂O₃ 0.00 0.00 0.00 0.00 0.03 0.03 0.03 0.03 0.03 CuO 0.12 0.12 0.12 0.13 0.18 0.17 0.18 0.20 0.19 Cl 0.01 0.01 0.01 0.01 0.00 0.00 0.00 0.00 0.00 Dk (measured 6.44 6.38 6.34 6.18 6.44 6.44 6.43 6.39 6.37 at 10 GHz)

Tables 25A-25C show example glass compositions (in terms of mol %) containing gold (Au) as a colorant.

TABLE 25A Ex. (mol %) SPR-1 SPR-2 SPR-3 SPR-4 SPR-5 SPR-6 SPR-7 SPR-8 SPR-9 SiO₂ 60.610 60.886 60.779 60.735 60.801 59.984 59.847 60.214 60.910 Al₂O₃ 14.400 14.464 14.443 14.430 14.427 14.765 14.715 14.608 14.544 B₂O₃ 5.896 5.974 5.969 5.829 5.899 6.133 6.082 6.027 5.850 P₂O₅ 0.031 0.027 0.027 0.031 0.031 0.000 0.000 0.000 0.000 Li₂O 10.074 9.955 9.947 10.047 10.037 10.424 10.479 10.415 9.760 Na₂O 4.254 4.283 4.315 4.259 4.249 4.239 4.235 4.224 4.274 K₂O 0.189 0.188 0.190 0.188 0.454 0.197 0.199 0.195 0.204 MgO 2.872 2.881 2.891 2.874 2.890 2.959 2.975 2.917 3.006 CaO 0.034 0.034 0.033 0.034 0.031 0.016 0.017 0.016 0.014 ZnO 0.985 0.999 0.993 0.985 0.994 1.045 1.020 1.012 1.015 TiO₂ 0.006 0.006 0.006 0.006 0.004 0.007 0.007 0.007 0.006 ZrO₂ 0.501 0.223 0.300 0.448 0.027 0.000 0.000 0.000 0.000 SnO₂ 0.071 0.016 0.035 0.054 0.105 0.053 0.052 0.052 0.050 Fe₂O₃ 0.024 0.024 0.024 0.024 0.025 0.146 0.096 0.047 0.048 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.233 0.229 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.002 0.000 HfO₂ 0.006 0.003 0.006 0.006 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.019 0.000 0.000 0.021 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.002 0.001 0.001 0.002 0.001 0.000 0.000 0.000 0.001 Au 0.000000 0.004966 0.004973 0.000000 0.000000 0.001997 0.001770 0.001802 0.000677 SO₃ 0.000 0.003 0.008 0.000 0.000 0.000 0.010 0.005 0.005 Cl 0.025 0.027 0.029 0.027 0.025 0.029 0.030 0.029 0.314

TABLE 25B Ex. (mol %) SPR-10 SPR-11 SPR-12 SPR-13 SPR-14 SPR-15 SPR-16 SPR-17 SPR-18 SiO₂ 60.874 61.382 60.006 61.945 62.849 61.812 61.880 61.363 61.235 Al₂O₃ 14.545 14.424 14.896 14.480 14.514 15.558 15.478 15.755 15.656 B₂O₃ 5.794 5.826 5.882 5.946 5.984 5.879 5.985 5.914 5.887 P₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Li₂O 8.957 9.890 10.033 10.946 10.972 11.048 10.969 11.170 11.146 Na₂O 4.264 4.299 4.326 6.323 5.323 5.337 5.379 5.421 5.382 K₂O 0.200 0.193 0.194 0.191 0.196 0.193 0.196 0.194 0.194 MgO 2.941 2.862 3.102 0.016 0.011 0.018 0.016 0.018 0.014 CaO 0.014 0.015 0.016 0.007 0.007 0.006 0.008 0.006 0.006 ZnO 1.990 1.011 1.074 0.000 0.000 0.000 0.000 0.000 0.000 TiO₂ 0.007 0.007 0.008 0.007 0.006 0.006 0.006 0.006 0.008 ZrO₂ 0.000 0.000 0.316 0.001 0.000 0.001 0.001 0.001 0.320 SnO₂ 0.051 0.057 0.052 0.109 0.110 0.108 0.056 0.055 0.054 Fe₂O₃ 0.048 0.004 0.068 0.003 0.004 0.003 0.004 0.069 0.069 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.001 0.001 0.001 0.000 0.001 0.001 0.001 0.000 0.001 Au 0.000488 0.000357 0.000000 0.001297 0.000261 0.001960 0.000000 0.000327 0.000655 SO₃ 0.000 0.009 0.000 0.000 0.000 0.002 0.000 0.007 0.003 Cl 0.312 0.020 0.025 0.025 0.022 0.025 0.022 0.022 0.020

TABLE 25C Ex. (mol %) SPR-19 SPR-20 SPR-21 SPR-22 SiO₂ 60.872 60.616 62.173 61.281 Al₂O₃ 16.544 16.474 14.974 14.343 B₂O₃ 5.853 5.964 5.722 5.820 P₂O₅ 0.000 0.000 0.000 0.018 Li₂O 11.078 10.927 9.237 6.759 Na₂O 5.336 5.358 2.332 7.465 K₂O 0.193 0.195 0.182 0.589 MgO 0.019 0.016 2.433 2.027 CaO 0.007 0.008 1.555 0.542 ZnO 0.000 0.000 0.976 0.973 TiO₂ 0.007 0.007 0.010 0.006 ZrO₂ 0.001 0.309 0.302 0.000 SnO₂ 0.055 0.054 0.042 0.104 Fe₂O₃ 0.003 0.047 0.043 0.044 NiO 0.000 0.000 0.000 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.001 0.000 0.000 Au 0.000987 0.000157 0.000563 0.002166 SO₃ 0.006 0.002 0.006 0.005 Cl 0.024 0.022 0.011 0.020

Referring now to Table 26, colored glass articles in the form of glass coupons were produced from the glass compositions of Tables 25A-25C. The glass coupons had the indicated thicknesses and were heat treated at various times and temperatures (as indicated) to produce colored glass articles with different color hues. The CIELAB L*, a*, and b* coordinates of each colored glass article were determined. The average transmittance (%) for each sample over the wavelength range from 380 nm to 750 nm was also determined. The results are reported in Table 26.

TABLE 26 Average transmittance Thickness Temp Time (380 nm− Example (mm) (° C.) (Hr.) L* a* b* 750 nm) SPR-1 1.32 620 10 80.8 15 10.88 62.083 SPR-2 1.31 632 0.25 69.7 1.33 −15.5 53.986 SPR-2 1.35 545 2 88 8.84 −1.45 77.737 SPR-2 1.36 553 1.5 88.9 7.79 −1.3 79.081 SPR-2 1.36 630 6 77.1 19.7 2.28 61.052 SPR-2 1.42 603 1.5 69.1 9.07 −12.3 54.353 SPR-2 1.39 632 0.5 69.7 6.74 −12.2 54.045 SPR-2 1.29 705 0.25 73.7 20 −5.76 60.047 SPR-2 1.35 655 1.5 75.2 20.5 −1.62 60.186 SPR-2 1.38 630 6 76.9 20.1 2.43 60.776 SPR-2 1.34 545 1 88.3 8.75 −1.28 78.270 SPR-2 1.36 553 2 89.2 7.76 −1.14 79.523 SPR-2 1.36 630 1.5 77.2 20 2.26 61.288 SPR-2 1.4 632 6 69.5 7.02 −12.4 54.092 SPR-2 1.43 603 0.5 69 9.22 −12.6 54.475 SPR-2 1.32 632 0.25 69.4 1.26 −15.9 53.842 SPR-2 1.29 705 0.25 73.9 20 −5.92 60.530 SPR-2 1.35 655 1.5 75.2 20.6 −1.95 60.438 SPR-2 1.37 630 6 77 20.2 2.07 61.092 SPR-2 1.29 560 0.25 91.9 4.36 −0.78 83.484 SPR-2 1.29 580 0.25 92 4.2 −0.87 83.677 SPR-2 1.22 600 0.25 76.4 8.13 −12.5 65.670 SPR-2 1.22 560 0.50 91.4 5 −0.94 82.705 SPR-2 1.21 580 0.50 75.5 11.5 −12.3 64.875 SPR-2 1.2 600 0.50 70.9 2.8 −15.7 57.149 SPR-2 1.26 560 0.75 87.3 9 −2.33 77.093 SPR-2 1.28 580 0.75 70.3 10.9 −14.8 58.437 SPR-2 1.3 600 0.75 70.3 4.83 −13.4 55.255 SPR-2 1.27 560 2 75.2 15.9 −4.84 61.011 SPR-2 1.47 620 0.25 66.7 −1.17 −19 51.231 SPR-2 1.45 630 0.25 66.6 −1.27 −18.7 50.691 SPR-2 1.45 640 0.25 66.3 −0.3 −18.2 50.110 SPR-2 1.48 650 0.25 66.3 1.82 −16.9 49.961 SPR-2 1.48 660 0.25 67.4 4.84 −14.3 51.179 SPR-2 1.49 670 0.25 67.9 6.81 −13 51.865 SPR-2 1.33 680 0.25 70.7 8.42 −11.5 55.644 SPR-2 1.3 690 0.25 72.3 13.3 −9.69 58.346 SPR-2 1.3 700 0.25 72.7 14.9 −8.33 58.842 SPR-2 1.32 710 0.25 74.9 18 −3.59 60.103 SPR-2 1.29 620 0.50 70.7 4.6 −12.7 55.193 SPR-2 1.31 640 0.50 70.7 10.4 −11.8 56.589 SPR-2 0.9 660 0.50 81.5 13.6 −2.27 68.459 SPR-2 0.87 680 0.50 83 14.2 0 69.595 SPR-2 0.86 700 0.50 83.3 13.9 0.36 69.916 SPR-2 0.81 620 0.75 79.8 5.56 −7.92 67.047 SPR-2 0.69 640 0.75 83.7 9.69 −3.81 72.165 SPR-2 0.72 660 0.75 85.4 11.4 −0.42 73.325 SPR-2 1.28 680 0.75 78.3 17.9 0.24 62.902 SPR-2 1.29 700 0.75 78.4 17.6 0.44 62.728 SPR-2 1.29 620 2.00 75.3 17.7 −3.72 60.833 SPR-2 1.42 580 2 89.9 5.08 −1.36 80.246 SPR-2 1.3 600 2 70.6 11.1 −12 56.982 SPR-2 1.34 640 2 76.3 20.2 0.48 60.676 SPR-2 1.35 660 2 76.6 19.3 0.15 60.827 SPR-2 1.18 680 2 79.4 17.7 1.36 64.066 SPR-2 1.35 550 1 85.4 11.2 −2.58 74.328 SPR-2 1.34 550 1.25 80 16.2 −4.65 67.893 SPR-2 1.27 540 1.25 92.1 4.47 −0.39 83.614 SPR-2 1.27 710 2.5 78.8 19.2 3.29 62.662 SPR-2 1.34 625 1.25 72.1 15.3 −8.48 58.196 SPR-2 1.39 540 1.5 87 9.82 −1.71 76.314 SPR-2 1.35 590 0.917 70.8 8.23 −10.7 55.681 SPR-2 1.34 555 1 92.7 4.09 −0.34 84.664 SPR-2 1.335 635 1 70 11.7 −12.7 56.278 SPR-2 1.365 595 1 70.9 9.62 −10.6 56.159 SPR-2 1.279 615 1 70.9 6.71 −12.2 55.936 SPR-2 1.331 580 0.5 68.7 3.09 −17.4 55.139 SPR-2 0.641 525 2 94.3 2.41 −0.16 87.417 SPR-2 2.077 525 2 89 7.39 −0.62 78.548 SPR-2 0.64 545 2 94.5 2.23 −0.11 87.779 SPR-2 2.06 545 2 89.7 6.76 −0.51 79.648 SPR-3 1.3 630 6 77.6 18.6 1.33 61.990 SPR-3 1.31 575 1 74 16.2 −7.99 61.103 SPR-3 1.29 632 0.5 72.7 7.67 −9.49 57.240 SPR-3 1.25 603 1.5 73.2 8.79 −9.7 58.809 SPR-3 1.26 655 1.5 77.1 18.5 −0.67 62.079 SPR-3 1.37 575 1 73.3 17.7 −8.38 60.550 SPR-3 1.33 635 1 72.5 13.9 −8.58 58.373 SPR-3 1.37 615 1 70.7 8.26 −11.1 55.575 SPR-3 1.34 595 1 72.6 9.35 −8.15 57.204 SPR-3 1.27 555 1 93.2 3.16 −0.23 85.431 SPR-3 1.367 575 1 73 17.5 −8.56 60.095 SPR-3 1.33 635 1 72.7 14.9 −7.76 58.572 SPR-3 1.336 595 1 72.6 9.13 −8.28 57.195 SPR-3 1.242 603 1.5 73.1 8.86 −9.73 58.626 SPR-3 1.293 632 0.5 72.7 7.74 −9.49 57.192 SPR-3 1.356 615 1 70.8 8.14 −11.1 55.630 SPR-3 0.565 632 0.5 85.6 4.05 −4.57 74.432 SPR-3 1.512 632 0.5 69.3 8.38 −10.7 53.145 SPR-4 1.33 580 0.25 91.1 4.08 −1.11 82.311 SPR-4 1.34 600 0.25 73.9 9.69 −11.7 61.448 SPR-4 1.32 560 0.50 91.9 3.7 −0.66 83.379 SPR-4 1.34 580 0.50 73.1 12.9 −10.7 60.597 SPR-4 1.23 600 0.50 73.6 3.67 −11.4 58.393 SPR-4 1.23 560 0.75 88.4 6.93 −1.86 78.551 SPR-4 1.24 580 0.75 74.3 9.95 −8.94 60.566 SPR-4 1.23 600 0.75 74.4 5.31 −8.99 58.880 SPR-4 1.3 560 2.00 77.7 13.3 −0.84 62.143 SPR-4 1.3 580 2.00 74.4 10.8 −6.76 59.556 SPR-4 1.32 600 2.00 74.7 13.4 −5.8 60.238 SPR-4 1.28 560 0.25 72.4 10.6 −9.29 57.846 SPR-4 1.28 620 2 78.8 17.2 1.61 63.224 SPR-4 1.32 640 2 78.8 17.6 4.07 62.054 SPR-4 1.32 660 2 78.7 17.7 3.8 62.119 SPR-4 1.2 680 2 80.6 16.3 4.42 64.227 SPR-4 1.342 660 6 76.9 18.6 1.38 60.789 SPR-4 1.389 600 1 72.8 9.91 −6.88 56.945 SPR-4 1.285 600 10 79.1 17.3 3.94 62.620 SPR-4 1.289 620 10 78.7 17.7 3.31 62.257 SPR-4 1.295 640 10 78.3 17.9 2.64 62.079 SPR-4 1.308 660 2 77.6 18.3 1.83 61.500 SPR-4 0.528 710 2.5 89.7 7.57 2.52 78.250 SPR-4 2.043 710 2.5 73.1 22.9 9.92 53.254 SPR-5 1.348 660 6 83.1 9.17 10.21 64.324 SPR-5 1.32 600 10 82.4 9.71 9.07 63.785 SPR-5 1.293 620 10 82.8 9.49 8.88 64.444 SPR-5 1.35 640 10 82.6 9.48 9.53 63.931 SPR-5 1.315 660 2 82.8 9.65 9.27 64.280 SPR-6 1.31 600 1 64.6 24.8 −4.62 48.155 SPR-7 1.36 600 1 64.1 23.1 23.31 44.240 SPR-8 1.27 600 1 69.2 13.3 34.5 45.285 SPR-9 1.33 600 1 87.3 10.2 −3.02 77.166 SPR-10 1.303 600 1 88.1 6.56 −4.17 78.834 SPR-11 1.302 625 2 81.4 15.7 6.6 65.169 SPR-12 1.307 600 2 84.2 12.7 1.32 69.833 SPR-13 1.306 625 2 89.3 5.14 9.97 74.122 SPR-14 1.291 575 2 87.4 9.35 8.2 72.514 SPR-14 1.321 625 2 87.6 7.22 10.51 71.412 SPR-14 0.502 625 2 92.7 3.39 4.56 82.163 SPR-14 1.304 625 2 85.3 9.75 11.19 67.746 SPR-14 2.015 625 2 82.9 10.7 15.3 62.880 SPR-14 0.612 625 2 92.1 3.93 12.8 78.141 SPR-14 2.063 625 2 85.8 8.06 34.2 62.357 SPR-15 1.298 625 2 83 11.4 2.59 68.255 SPR-16 1.327 625 2 86.7 9.76 2.6 73.863 SPR-16 0.6 625 2 90 6.98 1.73 79.393 SPR-16 1.97 625 2 79.4 13.9 1.64 63.678 SPR-16 0.62 625 2 90.3 6.77 1.82 79.780 SPR-16 2.039 625 2 80.4 15.3 3.72 64.446 SPR-16 0.623 625 2 91.5 6.22 7.06 79.380 SPR-16 2.089 625 2 81.6 17.2 20.79 60.538 SPR-17 1.325 625 2 88.9 6.92 4.75 75.258 SPR-18 1.318 625 2 87.3 9.09 3.44 73.391 SPR-19 1.308 625 2 78 5.04 −9.39 63.809 SPR-20 1.332 625 2 80.5 6.25 −8.92 68.187 SPR-20 0.632 625 2 87.7 2.61 −5.06 77.726 SPR-20 1.353 625 2 79 5.44 −9.99 65.901 SPR-20 0.632 625 2 69 8.35 −14.9 53.661 SPR-20 0.622 625 2 88.1 1.98 −5.62 78.812 SPR-20 2.058 625 2 68 6.29 −18 53.414 SPR-14 1.291 575 2 87.4 9.35 8.2 72.514 SPR-14 1.321 625 2 87.6 7.22 10.51 71.412 SPR-14 0.502 625 2 92.7 3.39 4.56 82.163 SPR-14 1.304 625 2 85.3 9.75 11.19 67.746 SPR-14 2.015 625 2 82.9 10.7 15.3 62.880 SPR-14 0.612 625 2 92.1 3.93 12.8 78.141 SPR-14 2.063 625 2 85.8 8.06 34.2 62.357 SPR-14 1.291 575 2 87.4 9.35 8.2 72.514 SPR-14 1.321 625 2 87.6 7.22 10.51 71.412 SPR-14 0.502 625 2 92.7 3.39 4.56 82.163 SPR-14 1.304 625 2 85.3 9.75 11.19 67.746 SPR-14 2.015 625 2 82.9 10.7 15.3 62.880 SPR-14 0.612 625 2 92.1 3.93 12.8 78.141 SPR-14 2.063 625 2 85.8 8.06 34.2 62.357 SPR-16 1.327 625 2 86.7 9.76 2.6 73.863 SPR-16 0.6 625 2 90 6.98 1.73 79.393 SPR-16 1.97 625 2 79.4 13.9 1.64 63.678 SPR-16 0.62 625 2 90.3 6.77 1.82 79.780 SPR-16 2.039 625 2 80.4 15.3 3.72 64.446 SPR-16 0.623 625 2 91.5 6.22 7.06 79.380 SPR-16 2.089 625 2 81.6 17.2 20.79 60.538 SPR-20 1.332 625 2 80.5 6.25 −8.92 68.187 SPR-20 0.632 625 2 87.7 2.61 −5.06 77.726 SPR-20 1.353 625 2 79 5.44 −9.99 65.901 SPR-20 0.632 625 2 69 8.35 −14.9 53.661 SPR-20 0.622 625 2 88.1 1.98 −5.62 78.812 SPR-20 2.058 625 2 68 6.29 −18 53.414 SPR-16 1.327 625 2 86.7 9.76 2.6 73.863 SPR-16 0.6 625 2 90 6.98 1.73 79.393 SPR-16 1.97 625 2 79.4 13.9 1.64 63.678 SPR-16 0.62 625 2 90.3 6.77 1.82 79.780 SPR-16 2.039 625 2 80.4 15.3 3.72 64.446 SPR-16 0.623 625 2 91.5 6.22 7.06 79.380 SPR-16 2.089 625 2 81.6 17.2 20.79 60.538 SPR-20 1.332 625 2 80.5 6.25 −8.92 68.187 SPR-20 0.632 625 2 87.7 2.61 −5.06 77.726 SPR-20 1.353 625 2 79 5.44 −9.99 65.901 SPR-20 0.632 625 2 69 8.35 −14.9 53.661 SPR-20 0.622 625 2 88.1 1.98 −5.62 78.812 SPR-20 2.058 625 2 68 6.29 −18 53.414 SPR-21 1.381 620 8 84.2 −3.45 −7.17 70.463 SPR-22 3.069 640 8 72.6 16.9 68.63 40.945 SPR-22 3.085 660 8 71.9 17.5 66.16 40.588 SPR-22 3.1 680 8 71 17.9 65.27 39.780 SPR-22 3.15 700 8 72.3 17.5 64.89 41.003 SPR-22 3.4 620 2 72 18.4 67.51 40.834 SPR-22 3.07 640 2 71 18.5 66.03 40.098

Tables 27A-27NN show example glass compositions (in terms of mol %) containing transition metal oxides and/or rare earth oxides as colorants.

TABLE 27A Ex. (mol %) ORA-1 ORA-2 ORA-3 ORA-4 ORA-5 ORA-6 ORA-6 ORA-7 ORA-8 SiO₂ 60.93 61.53 58.99 57.22 57.78 58.75 58.75 59.03 58.53 Al₂O₃ 16.20 15.91 16.99 18.71 17.54 16.67 16.67 16.52 16.50 B₂O₃ 5.66 5.59 6.15 5.68 5.96 5.92 5.92 5.86 5.58 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.49 10.61 11.02 10.75 10.92 11.78 11.78 11.65 11.55 Na₂O 1.67 1.68 1.74 1.71 1.68 6.26 6.26 6.22 6.17 K₂O 0.30 0.30 0.30 0.29 0.29 0.48 0.48 0.48 0.47 MgO 3.78 3.65 3.98 4.67 4.31 0.02 0.02 0.02 0.02 CaO 0.52 0.50 0.55 0.61 0.57 0.01 0.01 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.005 0.005 0.006 0.005 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.127 0.042 0.153 0.243 0.206 0.000 0.000 0.177 0.000 Co₃O₄ 0.055 0.068 0.025 0.049 0.001 0.000 0.000 0.001 0.001 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.098 0.098 0.000 0.000 CuO 0.247 0.104 0.088 0.034 0.724 0.000 0.000 0.000 1.151 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.001 0.000 0.001 0.001 0.001 0.001 0.001 0.001 0.001 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.002 0.002 0.000 0.000 0.002 0.000 Cl 0.007 0.007 0.009 0.007 0.007 0.011 0.011 0.011 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27B Ex. (mol %) ORA-9 ORA-10 ORA-11 ORA-11 ORA-12 ORA-14 ORA-15 ORA-16 SiO₂ 58.95 60.10 57.65 57.65 56.77 58.04 59.63 57.80 Al₂O₃ 16.55 15.85 16.16 16.16 16.65 17.65 16.71 17.65 B₂O₃ 5.97 5.74 5.95 5.95 5.90 6.20 6.16 5.87 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.70 9.81 11.61 11.61 9.84 11.04 10.94 10.85 Na₂O 6.22 4.23 6.10 6.10 4.24 1.68 1.67 1.69 K₂O 0.48 0.47 0.47 0.47 0.48 0.29 0.29 0.29 MgO 0.02 2.69 0.02 0.02 2.98 4.34 3.95 4.35 CaO 0.01 0.02 0.01 0.01 0.02 0.57 0.54 0.58 ZnO 0.02 0.96 0.00 0.00 1.04 0.00 0.00 0.00 TiO₂ 0.01 0.01 1.91 1.91 1.95 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.005 0.004 0.004 0.004 0.006 0.005 0.005 CeO₂ 0.000 0.000 0.100 0.100 0.102 0.000 0.000 0.000 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.058 0.048 Co₃O₄ 0.046 0.001 0.001 0.001 0.001 0.001 0.011 0.013 Cr₂O₃ 0.000 0.098 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.000 0.010 0.000 0.000 0.000 0.155 0.020 0.845 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.001 0.001 0.001 0.001 0.000 0.001 0.001 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.015 0.009 0.002 0.000 Cl 0.011 0.007 0.011 0.011 0.011 0.007 0.007 0.007 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27C Ex. (mol %) ORA-17 ORA-18 ORA-21 ORA-22 ORA-23 ORA-24 ORA-25 SiO₂ 56.37 58.62 58.27 58.49 58.94 58.49 57.45 Al₂O₃ 18.99 17.25 16.34 16.49 16.40 16.55 18.22 B₂O₃ 6.02 5.97 5.92 6.01 5.98 6.04 5.91 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.02 10.73 9.89 9.97 9.93 9.93 10.77 Na₂O 1.69 1.68 4.25 4.26 4.26 4.30 1.69 K₂O 0.28 0.29 0.48 0.48 0.49 0.49 0.29 MgO 4.81 4.17 2.91 2.95 2.90 2.93 4.45 CaO 0.61 0.59 0.01 0.01 0.01 0.02 0.60 ZnO 0.00 0.00 1.00 1.01 1.00 1.05 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.006 0.005 0.004 0.005 0.005 0.005 0.006 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.141 0.108 0.000 0.023 0.012 0.089 0.053 Co₃O₄ 0.029 0.001 0.001 0.002 0.002 0.048 0.013 Cr₂O₃ 0.000 0.000 0.068 0.038 0.002 0.008 0.000 CuO 0.006 0.576 0.829 0.233 0.037 0.044 0.525 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.001 0.001 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.001 0.006 0.003 0.000 0.000 Cl 0.007 0.009 0.011 0.011 0.011 0.009 0.005 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27D Ex. (mol %) ORA-26 ORA-27 ORA-28 ORA-29 ORA-30 ORA-31 ORA-32 ORA-33 ORA-34 SiO₂ 57.72 57.57 57.20 56.72 56.18 59.18 58.40 58.81 58.08 Al₂O₃ 17.62 17.48 17.51 17.36 17.14 16.63 16.20 16.54 16.54 B₂O₃ 6.01 5.97 5.91 5.90 5.81 5.62 5.70 5.76 6.07 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.85 10.80 10.79 10.68 10.55 11.79 11.60 11.86 11.87 Na₂O 1.67 1.67 1.67 1.68 1.65 6.18 6.09 6.17 6.20 K₂O 0.29 0.29 0.29 0.28 0.28 0.46 0.47 0.47 0.48 MgO 4.25 4.22 4.23 4.19 4.15 0.02 0.02 0.02 0.02 CaO 0.58 0.58 0.58 0.58 0.56 0.01 0.01 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.00 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.006 0.006 0.006 0.006 0.006 0.004 0.003 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.057 0.057 0.053 0.052 0.052 0.077 0.039 0.127 0.071 Co₃O₄ 0.012 0.012 0.012 0.011 0.012 0.001 0.001 0.032 0.002 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.009 0.101 0.000 0.051 CuO 0.905 1.330 1.735 2.536 3.586 0.002 1.350 0.176 0.563 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.005 0.004 0.006 0.004 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.005 0.004 0.006 0.000 0.000 0.001 0.011 0.000 0.000 Cl 0.005 0.005 0.004 0.005 0.004 0.009 0.009 0.013 0.015 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27E Ex. (mol %) ORA-35 ORA-36 ORA-37 ORA-38 ORA-39 ORA-40 ORA-41 ORA-42 ORA-43 SiO₂ 59.17 58.32 58.74 57.99 57.84 58.16 58.35 58.45 58.41 Al₂O₃ 16.57 16.10 16.54 16.56 17.76 17.85 16.48 16.52 16.48 B₂O₃ 5.67 5.69 5.75 6.03 6.08 6.00 6.00 6.09 6.04 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.86 11.64 11.91 11.97 11.03 10.89 10.06 10.12 10.07 Na₂O 6.16 6.07 6.13 6.22 1.69 1.69 4.28 4.26 4.25 K₂O 0.45 0.46 0.46 0.48 0.29 0.29 0.48 0.49 0.48 MgO 0.02 0.02 0.02 0.02 4.35 4.37 2.94 2.94 2.93 CaO 0.01 0.01 0.01 0.01 0.58 0.58 0.02 0.01 0.02 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 1.01 1.01 1.01 TiO₂ 0.01 0.00 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.003 0.004 0.004 0.005 0.005 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.000 0.242 0.093 0.252 0.051 0.021 0.000 0.082 Co₃O₄ 0.002 0.038 0.068 0.072 0.053 0.001 0.002 0.002 0.048 Cr₂O₃ 0.002 0.051 0.000 0.012 0.001 0.001 0.036 0.001 0.006 CuO 0.086 1.582 0.092 0.515 0.022 0.066 0.278 0.091 0.137 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.006 0.005 0.004 0.007 0.006 0.005 0.004 0.005 0.004 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.003 0.000 0.010 0.012 0.002 0.005 0.014 Cl 0.009 0.007 0.013 0.015 0.009 0.009 0.013 0.013 0.013 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27F Ex. (mol %) ORA-44 ORA-45 ORA-46 ORA-47 ORA-48 ORA-49 ORA-50 ORA-51 ORA-52 SiO₂ 58.30 58.71 58.54 58.67 58.47 58.47 58.61 58.63 57.36 Al₂O₃ 16.45 16.46 16.41 16.53 16.48 16.43 16.48 16.55 17.09 B₂O₃ 6.08 5.98 5.96 5.99 6.05 6.03 6.04 6.10 6.18 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.10 10.05 10.53 10.51 10.50 10.52 10.53 9.94 10.16 Na₂O 4.26 4.24 4.71 4.75 4.76 4.74 4.76 4.29 4.32 K₂O 0.48 0.48 0.48 0.49 0.49 0.48 0.49 0.29 0.49 MgO 2.91 2.93 0.96 0.97 0.97 0.98 0.97 2.93 3.12 CaO 0.02 0.02 0.98 0.98 0.99 0.99 0.99 0.02 0.02 ZnO 1.00 1.01 0.99 1.02 1.01 1.01 1.01 1.02 1.08 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.005 0.005 0.005 0.005 0.005 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.250 0.053 0.019 0.000 0.085 0.250 0.053 0.086 0.025 Co₃O₄ 0.053 0.001 0.002 0.002 0.048 0.053 0.001 0.049 0.010 Cr₂O₃ 0.001 0.000 0.039 0.001 0.005 0.000 0.000 0.005 0.001 CuO 0.058 0.036 0.339 0.054 0.111 0.010 0.036 0.060 0.103 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.006 0.005 0.005 0.004 0.006 0.005 0.004 0.003 0.000 As₂O₃ 0.000 0.001 0.001 0.001 0.001 0.001 0.001 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.001 0.002 0.006 0.002 0.007 0.000 0.009 0.000 0.005 Cl 0.013 0.011 0.011 0.015 0.013 0.013 0.013 0.013 0.013 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27G Ex. (mol %) ORA-53 ORA-54 ORA-56 ORA-57 ORA-58 ORA-59 ORA-60 ORA-61 ORA-62 SiO₂ 57.87 58.57 58.46 58.81 57.89 59.54 59.30 54.94 61.12 Al₂O₃ 17.10 16.44 16.41 16.50 16.88 16.00 16.52 18.22 15.01 B₂O₃ 5.76 5.80 5.84 5.78 5.98 6.02 5.63 6.53 5.46 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.89 9.90 9.84 9.82 10.00 10.04 9.71 10.84 9.12 Na₂O 4.33 4.22 4.21 4.22 4.30 4.23 4.27 4.68 3.84 K₂O 0.49 0.47 0.47 0.47 0.49 0.29 0.29 0.31 0.26 MgO 3.08 2.90 2.91 2.93 3.05 2.75 2.86 3.21 2.66 CaO 0.02 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZnO 1.06 0.99 0.99 1.03 1.06 0.95 1.00 1.10 0.90 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.084 0.048 0.049 0.037 0.097 0.023 0.090 0.049 0.050 Co₃O₄ 0.048 0.002 0.035 0.016 0.053 0.010 0.046 0.002 0.032 Cr₂O₃ 0.001 0.001 0.001 0.001 0.001 0.000 0.000 0.000 0.000 CuO 0.241 0.633 0.735 0.336 0.172 0.114 0.245 0.084 1.500 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.003 0.007 0.000 0.002 0.005 0.000 0.002 Cl 0.013 0.007 0.009 0.013 0.013 0.011 0.011 0.011 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27H Ex. (mol %) ORA-63 ORA-64 ORA-65 ORA-66 ORA-67 ORA-68 ORA-69 ORA-70 ORA-71 SiO₂ 56.53 55.78 58.58 58.56 57.21 57.93 58.24 57.46 58.16 Al₂O₃ 17.59 17.97 16.59 16.88 16.96 17.01 16.43 16.92 16.96 B₂O₃ 6.17 6.34 5.92 5.97 6.16 5.96 6.05 6.19 5.86 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.10 10.32 9.82 9.88 9.97 9.92 9.84 10.02 9.82 Na₂O 4.35 4.34 4.27 4.29 4.30 4.31 4.24 4.32 4.35 K₂O 0.29 0.29 0.48 0.29 0.29 0.29 0.29 0.29 0.30 MgO 3.25 3.42 2.94 2.98 3.04 3.03 2.93 3.02 3.02 CaO 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 ZnO 1.07 1.11 1.02 1.03 1.05 1.06 1.02 1.04 1.05 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.005 0.005 0.004 0.005 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.037 0.112 0.034 0.063 0.476 0.000 0.063 0.057 0.232 Co₃O₄ 0.017 0.057 0.002 0.002 0.018 0.005 0.033 0.039 0.057 Cr₂O₃ 0.000 0.000 0.030 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.548 0.232 0.260 0.008 0.487 0.444 0.824 0.595 0.145 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.003 0.001 0.000 0.002 0.001 0.003 0.002 As₂O₃ 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.006 0.000 0.012 0.000 0.006 0.000 0.000 0.000 0.005 Cl 0.013 0.013 0.011 0.011 0.011 0.009 0.009 0.011 0.013 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 271 Ex. (mol %) ORA-72 ORA-73 ORA-74 ORA-75 ORA-76 ORA-77 ORA-78 ORA-79 ORA-80 SiO₂ 57.12 59.37 58.01 55.88 59.19 55.91 57.08 59.16 59.23 Al₂O₃ 17.20 16.56 16.75 17.76 16.28 17.42 17.50 16.52 16.54 B₂O₃ 6.36 5.79 6.24 6.48 5.92 5.76 6.14 5.82 5.86 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.08 9.75 10.06 10.29 9.77 9.68 9.98 11.85 11.83 Na₂O 4.35 4.27 4.31 4.36 4.24 4.26 4.37 6.18 6.21 K₂O 0.29 0.29 0.29 0.29 0.29 0.29 0.29 0.19 0.20 MgO 3.11 2.90 2.90 3.39 2.79 3.37 3.20 0.02 0.02 CaO 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.01 0.01 ZnO 1.06 1.02 1.02 1.17 1.00 1.25 1.13 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.49 2.04 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.004 0.004 0.005 0.004 0.005 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.106 0.015 0.291 0.200 0.000 0.000 0.000 0.083 0.000 Co₃O₄ 0.047 0.001 0.057 0.050 0.001 0.001 0.054 0.048 0.001 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 0.000 CuO 0.238 0.000 0.013 0.077 0.000 0.000 0.215 0.093 0.061 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.002 0.000 0.004 0.002 0.000 0.001 0.001 0.003 0.005 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.003 0.000 0.005 Cl 0.011 0.009 0.013 0.011 0.009 0.009 0.011 0.011 0.015 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27J Ex. (mol %) ORA-81 ORA-82 ORA-83 ORA-84 ORA-85 ORA-86 ORA-87 ORA-88 ORA-89 SiO₂ 59.07 59.29 59.35 59.18 59.52 59.10 58.23 58.92 58.45 Al₂O₃ 16.48 16.51 16.56 16.41 16.38 16.53 16.16 16.40 16.34 B₂O₃ 5.81 5.83 5.82 6.00 5.84 5.96 5.74 6.02 6.02 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.88 11.80 11.84 11.95 11.82 11.88 11.68 11.83 11.82 Na₂O 6.19 6.18 6.19 6.18 6.17 6.19 6.05 6.20 6.19 K₂O 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 MgO 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 CaO 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 1.91 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.036 0.025 0.003 0.004 0.004 0.058 CeO₂ 0.000 0.000 0.001 0.001 0.003 0.099 0.002 0.000 0.000 NiO 0.249 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Co₃O₄ 0.053 0.010 0.001 0.001 0.001 0.001 0.001 0.015 0.035 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.009 0.106 0.000 0.000 0.000 0.000 0.000 0.370 0.791 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.004 0.005 0.001 0.000 0.001 0.000 0.001 0.001 0.004 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.001 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.011 0.011 0.007 0.009 0.007 0.011 0.007 0.011 0.013 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27K Ex. (mol %) ORA-90 ORA-91 ORA-92 ORA-93 ORA-94 ORA-95 ORA-96 ORA-97 ORA-98 SiO₂ 58.93 58.59 58.63 58.78 58.92 58.98 58.92 59.17 58.67 Al₂O₃ 16.35 16.35 16.56 16.41 16.34 16.42 16.52 16.45 16.52 B₂O₃ 5.98 6.07 6.13 6.10 5.99 6.04 6.01 5.97 5.92 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.84 11.80 11.87 11.82 11.77 11.87 11.87 11.88 11.85 Na₂O 6.20 6.21 6.24 6.21 6.18 6.22 6.24 6.21 6.24 K₂O 0.20 0.20 0.20 0.20 0.19 0.20 0.19 0.19 0.19 MgO 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.01 CaO 0.00 0.01 0.00 0.01 0.00 0.00 0.00 0.00 0.02 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.04 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.005 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.061 0.006 0.013 0.014 0.011 0.014 0.018 0.000 Co₃O₄ 0.031 0.034 0.035 0.035 0.034 0.002 0.001 0.000 0.000 Cr₂O₃ 0.016 0.000 0.048 0.029 0.015 0.055 0.037 0.047 0.000 CuO 0.411 0.628 0.229 0.364 0.504 0.147 0.142 0.015 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.007 0.004 0.004 0.004 0.003 0.004 0.004 0.005 0.000 As₂O₃ 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.001 0.000 0.000 0.000 0.005 0.002 0.000 0.006 0.000 Cl 0.011 0.013 0.013 0.015 0.011 0.013 0.013 0.013 0.015 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.517 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27L Ex. (mol %) ORA-99 ORA-100 ORA-101 ORA-102 ORA-103 ORA-104 ORA-105 ORA-106 ORA-107 SiO₂ 58.51 57.81 58.00 57.88 57.74 57.52 57.60 57.57 58.73 Al₂O₃ 16.39 16.21 16.25 16.11 16.08 16.33 16.37 16.07 16.47 B₂O₃ 5.84 5.81 5.60 5.69 5.76 5.83 5.74 5.99 6.09 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.76 11.72 11.62 11.74 11.79 11.78 11.76 10.97 11.98 Na₂O 6.21 6.11 6.08 6.05 6.04 5.19 4.27 4.23 6.24 K₂O 0.19 0.19 0.18 0.19 0.18 0.19 0.19 0.19 0.19 MgO 0.00 0.00 0.00 0.00 0.00 0.00 0.93 1.85 0.02 CaO 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.01 ZnO 0.01 0.00 0.00 0.00 0.00 1.01 1.03 1.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.006 0.009 0.009 0.009 0.009 0.009 0.009 0.009 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.000 0.112 0.214 0.306 0.000 0.000 0.000 0.015 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 CuO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.200 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.003 0.000 0.005 0.008 0.000 0.000 0.001 0.000 Cl 0.017 0.018 0.014 0.016 0.014 0.016 0.016 0.016 0.013 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 1.042 2.094 2.105 2.077 2.055 2.101 2.069 2.087 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27M Ex. (mol %) ORA-108 ORA-109 ORA-110 ORA-111 ORA-112 ORA-113 ORA-114 ORA-115 ORA-116 SiO₂ 59.04 58.88 59.31 59.45 60.14 60.08 60.58 59.80 59.18 Al₂O₃ 16.49 16.45 16.59 16.60 16.68 16.98 16.85 17.22 15.95 B₂O₃ 5.75 5.91 6.10 5.88 6.10 6.18 6.08 6.24 5.89 P₂O₅ 0.03 0.02 0.02 0.02 0.02 0.02 0.04 0.00 0.00 Li₂O 11.98 12.01 12.09 12.08 12.25 12.27 12.27 12.29 12.01 Na₂O 6.18 5.68 5.27 4.78 4.34 3.87 3.86 3.89 6.27 K₂O 0.18 0.19 0.19 0.19 0.19 0.19 0.20 0.19 0.20 MgO 0.02 0.02 0.02 0.02 0.03 0.02 0.02 0.02 0.02 CaO 0.03 0.02 0.02 0.02 0.02 0.02 0.03 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.00 0.01 0.00 0.01 0.00 0.01 0.00 0.01 0.01 ZrO₂ 0.00 0.51 0.00 0.51 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.027 0.016 0.016 0.016 0.016 0.016 0.028 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.018 0.017 0.019 0.014 0.016 0.017 0.000 0.018 0.001 Co₃O₄ 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.028 0.029 0.030 0.031 0.029 0.030 0.000 0.030 0.001 CuO 0.181 0.219 0.294 0.343 0.160 0.284 0.000 0.271 0.002 HfO₂ 0.000 0.006 0.000 0.006 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.024 0.015 0.012 0.012 0.016 0.013 0.022 0.001 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.001 0.004 0.000 0.000 0.000 0.004 0.000 0.002 Cl 0.011 0.013 0.011 0.011 0.009 0.009 0.009 0.007 0.009 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.451

TABLE 27N Ex. (mol %) ORA-117 ORA-118 ORA-119 ORA-120 ORA-121 ORA-122 ORA-123 ORA-124 ORA-125 SiO₂ 58.83 59.12 58.95 58.94 59.09 58.96 59.27 58.89 59.84 Al₂O₃ 14.57 15.93 15.90 15.16 15.91 17.23 17.31 17.36 17.03 B₂O₃ 5.97 5.83 6.03 5.96 5.95 6.10 6.00 6.03 6.00 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 12.20 12.10 12.16 12.16 12.02 10.39 10.34 11.33 11.12 Na₂O 6.31 6.23 6.22 6.28 6.27 2.80 2.79 2.82 2.81 K₂O 0.20 0.19 0.20 0.20 0.20 0.10 0.10 0.10 0.10 MgO 0.02 0.02 0.02 0.02 0.02 0.99 0.99 1.00 0.98 CaO 0.01 0.01 0.01 0.01 0.01 2.03 2.04 1.02 0.99 ZnO 0.00 0.00 0.00 0.00 0.00 1.04 1.06 1.06 1.02 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.005 0.005 0.004 0.005 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.010 0.086 0.040 0.053 0.003 0.000 0.000 0.000 0.000 Co₃O₄ 0.000 0.009 0.002 0.000 0.012 0.037 0.048 0.038 0.047 Cr₂O₃ 0.003 0.001 0.001 0.002 0.001 0.049 0.000 0.052 0.000 CuO 0.015 0.002 0.001 0.009 0.025 0.253 0.024 0.271 0.037 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.002 0.000 0.002 0.004 0.005 0.007 0.004 As₂O₃ 0.002 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.007 0.000 0.000 0.011 0.000 0.000 0.000 0.004 Cl 0.016 0.009 0.013 0.014 0.013 0.011 0.009 0.011 0.009 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 1.850 0.447 0.453 1.168 0.460 0.000 0.000 0.000 0.000

TABLE 270 Ex. (mol %) ORA-126 ORA-127 ORA-128 ORA-129 ORA-130 ORA-131 ORA-132 ORA-133 ORA-134 SiO₂ 58.98 58.50 58.20 58.36 58.82 58.06 58.50 58.41 58.97 Al₂O₃ 16.66 17.08 16.22 16.36 16.60 16.27 16.29 16.43 16.39 B₂O₃ 6.03 6.12 5.98 6.00 5.85 5.92 5.96 6.08 5.91 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.18 11.27 12.14 12.00 12.03 12.10 12.08 12.33 12.05 Na₂O 2.79 2.80 6.09 6.11 6.18 6.09 6.14 6.17 6.15 K₂O 0.10 0.10 0.19 0.20 0.19 0.19 0.20 0.20 0.19 MgO 0.95 0.97 0.01 0.02 0.01 0.01 0.02 0.01 0.01 CaO 1.94 2.00 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZnO 1.01 1.03 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.95 0.01 0.01 0.96 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.005 0.002 0.048 0.004 0.001 0.051 0.004 0.004 CeO₂ 0.000 0.000 0.200 0.002 0.000 0.400 0.000 0.002 0.004 NiO 0.000 0.000 0.000 0.000 0.037 0.000 0.000 0.000 0.000 Co₃O₄ 0.035 0.047 0.000 0.001 0.000 0.001 0.000 0.000 0.002 Cr₂O₃ 0.049 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.246 0.042 0.000 0.182 0.232 0.000 0.000 0.044 0.279 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.001 0.007 0.000 0.687 0.000 0.000 0.737 0.000 0.001 As₂O₃ 0.001 0.001 0.000 0.001 0.000 0.001 0.001 0.001 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.299 0.000 SO₃ 0.007 0.000 0.000 0.000 0.010 0.000 0.001 0.000 0.000 Cl 0.009 0.011 0.007 0.009 0.009 0.009 0.009 0.011 0.009 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27P Ex. (mol %) ORA-135 ORA-136 ORA-137 ORA-138 ORA-139 ORA-140 ORA-141 ORA-142 ORA-143 SiO₂ 58.37 58.70 57.48 58.61 56.91 57.48 58.88 58.26 58.47 Al₂O₃ 16.51 16.37 16.31 16.26 16.71 16.60 16.55 16.75 16.46 B₂O₃ 6.14 6.07 5.90 5.88 5.94 5.97 5.98 6.09 5.98 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 12.18 12.14 11.91 11.83 11.83 11.87 11.96 12.09 11.59 Na₂O 6.19 6.20 6.08 6.11 6.16 6.17 6.19 6.25 6.18 K₂O 0.19 0.20 0.20 0.19 0.20 0.22 0.19 0.20 0.19 MgO 0.02 0.01 0.02 0.01 0.01 0.02 0.02 0.02 0.01 CaO 0.01 0.01 0.01 0.00 0.01 0.01 0.01 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 1.98 0.99 2.00 0.01 0.01 0.01 0.98 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.003 0.003 0.002 0.107 0.099 0.101 0.003 CeO₂ 0.000 0.002 0.101 0.103 0.214 0.000 0.103 0.212 0.106 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.006 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.359 0.269 0.000 0.000 0.000 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.001 0.000 0.001 1.514 0.003 0.000 0.000 As₂O₃ 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.012 0.000 0.000 0.008 0.000 0.005 0.000 Cl 0.013 0.011 0.013 0.009 0.013 0.013 0.011 0.015 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27Q Ex. (mol %) ORA-144 ORA-145 ORA-146 ORA-147 ORA-148 ORA-149 ORA-150 ORA-151 ORA-152 SiO₂ 58.78 58.63 59.36 59.68 60.20 60.62 61.26 61.65 59.16 Al₂O₃ 16.19 16.39 16.55 16.53 16.44 16.49 16.37 16.41 16.55 B₂O₃ 5.92 5.87 5.78 5.78 5.85 5.88 5.89 5.93 5.92 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.60 11.58 11.67 11.82 11.81 11.82 11.78 11.80 11.85 Na₂O 6.11 6.15 6.20 5.69 5.22 4.74 4.25 3.77 6.17 K₂O 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 MgO 0.01 0.01 0.01 0.02 0.02 0.01 0.02 0.02 0.02 CaO 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.97 0.98 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.002 0.003 0.004 0.004 0.004 0.004 0.004 0.004 0.004 CeO₂ 0.199 0.161 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.000 0.019 0.020 0.018 0.020 0.020 0.020 0.105 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.028 0.034 0.030 0.030 0.028 0.029 0.000 CuO 0.000 0.000 0.158 0.196 0.192 0.154 0.163 0.157 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.001 As₂O₃ 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.011 0.011 0.009 0.009 0.009 0.009 0.007 0.007 0.009 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27R Ex. (mol %) ORA-153 ORA-154 ORA-155 ORA-156 ORA-157 ORA-158 ORA-159 ORA-160 ORA-161 SiO₂ 59.09 59.33 58.93 59.20 59.10 58.51 59.65 58.74 58.81 Al₂O₃ 16.57 16.52 16.51 16.48 16.68 16.44 16.41 16.72 16.49 B₂O₃ 5.93 5.85 6.02 5.92 5.87 6.05 5.91 6.00 6.01 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.95 11.83 12.04 11.94 11.67 11.97 11.68 11.98 11.85 Na₂O 6.17 6.19 6.20 6.16 6.20 6.18 6.10 6.28 6.20 K₂O 0.19 0.19 0.20 0.19 0.19 0.19 0.19 0.20 0.19 MgO 0.02 0.02 0.02 0.01 0.01 0.02 0.01 0.02 0.01 CaO 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.058 0.033 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.001 0.000 0.004 0.019 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.014 0.030 0.000 CuO 0.000 0.010 0.058 0.046 0.244 0.617 0.000 0.000 0.402 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.006 0.000 0.000 0.007 0.000 Cl 0.009 0.009 0.011 0.009 0.009 0.011 0.007 0.013 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27S Ex. (mol %) ORA-162 ORA-163 ORA-164 ORA-165 ORA-166 ORA-167 ORA-168 ORA-169 ORA-170 SiO₂ 58.68 58.44 58.49 58.71 59.24 58.85 58.57 58.74 59.78 Al₂O₃ 16.47 16.41 16.39 16.49 16.63 16.54 16.54 16.51 16.48 B₂O₃ 6.01 5.89 5.79 6.02 5.72 5.96 6.07 6.02 5.96 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.98 11.80 11.83 9.89 11.15 10.92 10.51 9.98 10.47 Na₂O 6.21 6.11 6.12 4.28 5.77 5.24 4.77 4.28 4.78 K₂O 0.20 0.21 0.21 0.20 0.19 0.20 0.20 0.20 0.20 MgO 0.02 0.02 0.02 0.04 0.02 0.03 0.04 0.05 0.03 CaO 0.01 0.01 0.01 4.00 1.00 2.00 3.01 3.99 1.99 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.072 0.071 0.004 0.004 0.004 0.004 0.005 0.004 CeO₂ 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.000 0.000 0.000 0.014 0.015 0.015 0.016 0.015 Co₃O₄ 0.000 0.000 0.000 0.003 0.002 0.002 0.002 0.002 0.002 Cr₂O₃ 0.000 0.000 0.000 0.000 0.026 0.027 0.027 0.027 0.026 CuO 0.410 0.000 0.000 0.338 0.224 0.195 0.213 0.185 0.231 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 1.030 1.031 0.001 0.000 0.000 0.000 0.001 0.000 As₂O₃ 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.002 0.000 0.000 0.000 0.000 0.000 0.006 Cl 0.011 0.009 0.013 0.009 0.007 0.009 0.009 0.009 0.007 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27T Ex. (mol %) ORA-171 ORA-172 ORA-173 ORA-174 ORA-175 ORA-176 ORA-177 ORA-178 ORA-179 SiO₂ 60.35 59.09 59.09 59.24 58.84 58.90 59.35 58.51 58.20 Al₂O₃ 16.50 16.38 16.40 16.33 16.50 16.51 16.27 16.30 16.50 B₂O₃ 6.09 5.92 5.97 5.95 5.98 5.97 5.91 5.92 5.89 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.25 9.97 9.90 9.91 10.02 9.95 9.92 9.72 9.77 Na₂O 4.29 4.26 4.25 4.25 4.25 4.25 4.24 4.22 4.22 K₂O 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.21 0.21 MgO 0.03 0.04 0.04 0.04 0.04 0.05 0.04 0.05 0.05 CaO 2.00 3.93 3.95 3.92 4.00 3.98 3.89 3.92 3.97 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.074 0.075 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.015 0.029 0.029 0.000 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.002 0.009 0.009 0.006 0.006 0.006 0.006 0.000 0.000 Cr₂O₃ 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.219 0.132 0.129 0.132 0.130 0.160 0.155 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.001 0.001 0.000 0.000 0.000 0.000 1.056 1.081 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.004 0.000 0.000 0.000 0.006 Cl 0.007 0.009 0.009 0.011 0.009 0.011 0.009 0.009 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27U Ex. (mol %) ORA-180 ORA-181 ORA-182 ORA-183 ORA-184 ORA-185 ORA-186 ORA-187 ORA-188 SiO₂ 58.69 58.89 58.60 58.69 57.79 57.28 57.43 57.09 57.38 Al₂O₃ 16.22 16.37 16.48 16.37 17.33 17.18 17.16 17.37 17.30 B₂O₃ 5.96 6.02 6.05 6.08 6.04 6.31 6.21 6.13 6.17 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.10 10.06 10.15 10.20 9.91 10.07 9.97 10.08 10.17 Na₂O 4.22 4.31 4.30 4.28 4.32 4.34 4.32 4.34 4.31 K₂O 0.21 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 MgO 0.05 0.04 0.04 0.04 0.05 0.05 0.05 0.05 0.05 CaO 3.88 3.94 3.98 3.95 4.31 4.22 4.26 4.27 4.26 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.57 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.075 0.004 0.004 0.004 0.005 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.029 0.030 0.028 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.001 0.009 0.009 0.009 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.000 0.000 0.015 0.015 0.010 0.010 0.005 CuO 0.001 0.113 0.120 0.119 0.001 0.321 0.370 0.420 0.135 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.002 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.008 0.000 0.000 0.000 0.000 0.000 0.006 Cl 0.011 0.013 0.015 0.013 0.011 0.009 0.009 0.011 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27V Ex. (mol %) ORA-189 ORA-190 ORA-191 ORA-192 ORA-193 ORA-194 ORA-195 ORA-196 ORA-197 SiO₂ 58.03 58.38 58.51 57.61 59.47 59.58 59.21 59.10 61.08 Al₂O₃ 16.91 16.78 16.62 17.18 16.37 16.35 16.41 16.46 15.56 B₂O₃ 6.14 6.05 6.18 6.16 5.81 5.65 5.93 5.93 5.79 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.13 10.06 10.08 10.16 9.22 8.75 9.38 8.95 9.29 Na₂O 4.30 4.28 4.28 4.35 3.76 3.28 3.77 3.27 3.79 K₂O 0.20 0.20 0.20 0.20 0.19 0.20 0.20 0.20 0.20 MgO 0.04 0.05 0.05 0.05 0.05 0.06 0.95 1.91 0.05 CaO 4.11 4.07 3.99 4.19 4.89 5.91 3.94 3.95 4.01 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.005 0.004 0.005 0.005 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.000 0.004 0.000 0.000 0.016 0.015 0.016 0.017 0.016 Co₃O₄ 0.008 0.009 0.004 0.004 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.019 0.039 0.019 0.039 0.030 0.029 0.028 0.028 0.029 CuO 0.090 0.053 0.045 0.028 0.162 0.164 0.157 0.162 0.160 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.007 0.002 0.001 0.004 0.003 0.004 0.001 0.004 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.002 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.000 Cl 0.009 0.009 0.009 0.011 0.007 0.007 0.009 0.007 0.009 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27W Ex. (mol %) ORA-198 ORA-199 ORA-200 ORA-201 ORA-202 ORA-203 ORA-204 ORA-205 ORA-206 SiO₂ 61.52 59.08 59.30 59.66 58.87 61.10 61.75 58.14 58.87 Al₂O₃ 15.16 16.42 16.47 16.33 16.67 15.45 15.23 16.87 16.53 B₂O₃ 5.98 5.95 5.73 5.77 5.85 5.89 5.57 6.08 5.91 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.02 Li₂O 8.24 9.44 8.83 9.31 8.94 9.43 8.33 9.92 9.92 Na₂O 1.20 3.75 3.26 3.74 3.29 3.77 1.20 4.34 4.29 K₂O 0.20 0.19 0.19 0.19 0.20 0.20 0.20 0.20 0.19 MgO 0.07 0.05 0.06 0.93 1.94 0.05 0.07 0.05 0.05 CaO 7.41 4.92 5.96 3.89 4.05 3.95 7.46 4.19 3.99 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.005 0.005 0.004 0.005 0.005 0.005 0.004 0.025 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.016 0.031 0.030 0.032 0.033 0.034 0.030 0.029 0.030 Co₃O₄ 0.000 0.008 0.008 0.008 0.008 0.008 0.008 0.009 0.009 Cr₂O₃ 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.160 0.122 0.132 0.116 0.124 0.117 0.128 0.146 0.124 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.004 0.000 0.004 0.000 0.002 0.002 0.000 0.020 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.005 0.000 0.000 0.000 0.000 0.005 0.000 0.000 Cl 0.007 0.009 0.007 0.007 0.009 0.009 0.005 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27X Ex. (mol %) ORA-207 ORA-208 ORA-209 ORA-210 ORA-211 ORA-211 ORA-212 ORA-213 ORA-214 SiO₂ 58.64 58.03 58.01 59.08 59.03 59.03 58.05 59.09 62.20 Al₂O₃ 16.67 16.82 16.91 16.49 16.44 16.44 16.96 16.53 14.80 B₂O₃ 5.97 6.11 6.09 5.87 5.90 5.90 6.03 6.09 6.05 P₂O₅ 0.02 0.00 0.00 0.03 0.02 0.02 0.00 0.00 0.00 Li₂O 9.82 10.05 10.04 9.96 9.94 9.94 9.97 11.78 8.89 Na₂O 4.29 4.36 4.35 4.24 4.28 4.28 4.36 6.21 1.41 K₂O 0.19 0.20 0.20 0.19 0.19 0.19 0.20 0.19 0.20 MgO 0.05 0.04 0.05 0.05 0.05 0.05 0.05 0.01 0.06 CaO 4.13 4.17 4.22 3.95 4.02 4.02 4.23 0.01 6.18 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.020 0.020 0.005 0.025 0.019 0.019 0.020 0.004 0.005 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.034 0.030 0.018 0.018 0.017 0.017 0.017 0.019 0.016 Co₃O₄ 0.009 0.009 0.002 0.002 0.002 0.002 0.002 0.002 0.000 Cr₂O₃ 0.000 0.000 0.027 0.026 0.026 0.026 0.029 0.026 0.029 CuO 0.141 0.136 0.061 0.038 0.045 0.045 0.079 0.028 0.157 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.015 0.002 0.003 0.022 0.014 0.014 0.002 0.001 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27Y Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 215 216 217 218 219 220 221 222 223 SiO₂ 61.74 62.49 62.52 62.48 62.06 60.17 60.04 60.22 61.06 Al₂O₃ 15.04 14.77 14.73 14.78 15.15 15.89 15.86 15.81 15.39 B₂O₃ 6.06 5.96 5.99 5.99 5.88 6.03 6.19 6.14 6.05 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.03 8.90 8.91 8.96 8.90 8.81 8.93 8.96 8.94 Na₂O 1.41 1.40 1.41 1.40 1.41 1.40 1.40 1.41 1.40 K₂O 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 MgO 0.99 1.94 2.92 3.90 5.06 0.07 1.00 1.98 2.88 CaO 5.25 4.10 3.08 2.06 1.07 7.19 6.12 5.02 3.84 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.015 0.017 0.018 0.021 0.018 0.017 0.018 0.018 0.017 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.030 0.028 0.029 0.028 0.029 0.029 0.029 0.029 0.027 CuO 0.221 0.181 0.172 0.181 0.197 0.193 0.196 0.199 0.191 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.001 0.001 0.000 0.000 0.001 0.001 0.001 0.002 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27Z Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 224 225 226 227 228 229 230 231 232 SiO₂ 60.16 60.87 58.66 59.73 61.24 61.20 61.14 59.00 59.98 Al₂O₃ 15.99 15.63 17.75 16.64 15.39 15.42 15.41 17.77 16.87 B₂O₃ 5.99 5.96 6.06 6.05 5.95 5.90 5.91 5.86 6.19 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 8.89 8.88 10.62 10.31 9.93 9.95 9.96 10.51 9.96 Na₂O 1.43 1.42 1.58 1.54 1.50 1.50 1.49 1.60 1.51 K₂O 0.20 0.20 0.20 0.19 0.20 0.20 0.20 0.20 0.20 MgO 4.06 4.91 4.28 4.32 4.24 3.08 1.92 4.28 4.31 CaO 2.99 1.86 0.61 0.97 1.32 2.53 3.74 0.62 0.97 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.005 0.004 0.004 0.005 0.004 0.005 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 NiO 0.017 0.017 0.017 0.018 0.016 0.015 0.016 0.033 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 0.000 Cr₂O₃ 0.029 0.028 0.028 0.027 0.028 0.027 0.027 0.000 0.000 CuO 0.230 0.212 0.187 0.175 0.175 0.176 0.169 0.123 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.003 0.000 0.001 0.001 0.001 0.001 0.001 0.001 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27AA Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 233 234 235 236 237 238 239 240 241 SiO₂ 61.48 60.82 61.59 60.38 59.54 58.78 58.67 58.87 58.93 Al₂O₃ 15.58 15.90 15.28 15.51 15.98 16.53 16.55 16.50 16.41 B₂O₂₃ 6.03 5.95 6.01 5.93 5.90 6.31 6.19 6.27 6.25 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.69 9.52 9.28 8.65 8.69 9.66 9.62 9.59 9.69 Na₂O 1.48 1.44 1.38 1.41 1.52 1.45 1.46 1.46 1.45 K₂O 0.20 0.20 0.20 0.20 0.19 0.19 0.19 0.19 0.19 MgO 4.22 3.17 1.89 2.88 5.05 2.18 2.16 2.17 2.16 CaO 1.31 2.86 4.16 3.83 1.88 4.75 4.78 4.78 4.78 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.99 1.02 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.003 0.003 0.005 0.005 0.006 0.005 CeO₂ 0.004 0.001 0.000 0.209 0.213 0.000 0.000 0.000 0.000 NiO 0.000 0.008 0.016 0.000 0.000 0.009 0.039 0.040 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.001 0.004 0.004 0.004 Cr₂O₃ 0.000 0.013 0.026 0.001 0.001 0.014 0.036 0.024 0.035 CuO 0.000 0.098 0.164 0.001 0.000 0.106 0.281 0.101 0.091 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.003 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.005 0.007 0.005 0.009 0.007 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27BB Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 242 243 244 245 246 247 248 249 250 SiO₂ 58.94 59.48 58.54 58.48 58.76 60.53 60.31 61.47 60.28 Al₂O₃ 16.76 16.21 16.48 16.62 16.48 15.05 15.08 14.54 15.16 B₂O₃ 5.90 6.16 6.32 6.27 6.24 5.91 6.02 5.92 5.81 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.32 9.56 9.85 9.80 9.71 10.04 10.08 9.92 9.95 Na₂O 1.47 1.47 1.45 1.45 1.45 1.84 1.86 1.83 1.86 K₂O 0.19 0.20 0.19 0.19 0.19 0.20 0.20 0.19 0.20 MgO 2.20 2.07 2.17 2.18 2.16 2.03 2.02 1.92 2.02 CaO 4.89 4.69 4.73 4.76 4.74 2.09 2.11 1.99 2.13 ZnO 0.00 0.00 0.00 0.00 0.00 1.07 1.07 1.01 1.10 TiO₂ 0.01 0.01 0.01 0.01 0.01 1.01 1.02 0.99 1.02 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.005 0.005 0.005 0.005 0.005 0.003 0.004 0.004 0.002 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.216 0.218 0.201 0.424 NiO 0.000 0.036 0.022 0.021 0.019 0.000 0.000 0.000 0.000 Co₃O₄ 0.001 0.001 0.003 0.003 0.002 0.000 0.000 0.000 0.000 Cr₂O₃ 0.025 0.034 0.029 0.030 0.031 0.000 0.000 0.000 0.000 CuO 0.279 0.101 0.212 0.193 0.187 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.004 0.001 0.000 0.000 0.001 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cl 0.000 0.000 0.000 0.000 0.000 0.011 0.009 0.007 0.007 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27CC Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 251 252 253 254 255 256 257 258 259 SiO₂ 61.13 60.99 60.54 60.74 59.21 59.45 61.01 61.36 60.91 Al₂O₃ 14.65 14.71 15.08 14.92 15.59 15.65 14.78 15.14 14.73 B₂O₃ 5.90 5.86 5.89 5.89 6.10 6.05 5.95 5.25 5.98 P₂O₅ 0.00 0.05 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.00 9.98 9.98 9.98 10.15 9.94 9.81 9.59 9.90 Na₂O 1.83 1.84 1.87 1.86 1.81 1.83 1.76 1.80 1.81 K₂O 0.19 0.19 0.19 0.19 0.18 0.18 0.18 0.18 0.19 MgO 1.94 1.96 2.01 1.49 2.23 2.24 2.09 2.01 2.01 CaO 2.03 2.05 2.11 2.09 2.29 2.26 2.14 2.12 2.09 ZnO 1.02 1.03 1.07 1.59 1.19 1.11 1.07 1.07 1.05 TiO₂ 0.99 1.00 1.02 1.01 1.03 1.04 0.99 1.03 1.00 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.10 0.10 0.00 0.00 0.00 0.00 0.00 0.00 0.10 Fe₂O₃ 0.004 0.004 0.004 0.003 0.004 0.004 0.004 0.002 0.003 CeO₂ 0.206 0.208 0.214 0.208 0.219 0.218 0.209 0.427 0.210 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.021 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.009 0.000 0.000 0.000 0.007 0.000 0.000 0.002 Cl 0.007 0.009 0.007 0.007 0.007 0.005 0.005 0.007 0.007 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27DD Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 260 261 262 263 264 265 266 267 268 SiO₂ 60.80 59.47 60.46 64.70 64.67 64.27 64.56 64.76 64.07 Al₂O₃ 14.64 15.69 15.29 12.99 13.00 12.89 13.02 12.96 12.95 B₂O₃ 5.98 6.03 5.99 5.83 5.81 5.72 5.83 5.74 5.64 P₂O₅ 0.05 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.99 9.95 9.67 11.98 12.02 11.71 12.07 10.02 9.96 Na₂O 1.74 1.80 1.82 2.81 2.80 2.73 2.82 1.84 1.82 K₂O 0.17 0.18 0.18 0.19 0.20 0.19 0.20 0.20 0.20 MgO 2.05 2.21 1.56 0.01 0.01 0.01 0.01 0.03 0.03 CaO 2.13 2.23 2.16 0.01 0.01 0.01 0.01 2.93 2.98 ZnO 1.13 1.15 1.62 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.99 1.04 1.03 0.98 0.98 0.97 0.98 0.98 0.98 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.10 0.00 0.00 0.05 0.05 0.04 0.05 0.05 0.05 Fe₂O₃ 0.003 0.004 0.003 0.002 0.002 0.002 0.002 0.003 0.003 CeO₂ 0.212 0.223 0.219 0.201 0.205 0.200 0.207 0.200 0.203 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Cl 0.007 0.007 0.005 0.012 0.014 1.019 0.016 0.011 0.012 F 0.000 0.000 0.000 0.231 0.231 0.230 0.231 0.266 1.093 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27EE Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 269 270 271 272 273 274 275 276 277 SiO₂ 63.99 63.75 63.77 61.32 60.98 63.28 62.41 63.31 62.35 Al₂O₃ 12.94 12.77 12.78 15.29 15.41 14.67 14.80 14.64 15.09 B₂O₃ 5.78 5.72 5.55 5.84 6.08 5.87 5.93 5.67 5.93 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.95 9.65 9.67 9.35 9.57 8.88 8.87 8.78 8.95 Na₂O 1.82 1.78 1.78 1.47 1.42 1.35 1.36 1.36 1.36 K₂O 0.20 0.19 0.19 0.20 0.20 0.00 0.00 0.00 0.00 MgO 0.03 0.03 0.03 1.99 1.96 2.78 2.80 2.75 2.89 CaO 2.96 2.92 2.93 4.23 4.22 1.91 1.94 1.91 2.00 ZnO 0.00 0.00 0.00 0.00 0.00 0.95 0.98 0.97 1.01 TiO₂ 0.98 0.97 0.96 0.05 0.01 0.01 0.59 0.29 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.05 0.04 0.04 0.00 0.00 0.00 0.00 0.00 0.10 Fe₂O₃ 0.003 0.003 0.003 0.005 0.005 0.002 0.002 0.002 0.002 CeO₂ 0.206 0.195 0.198 0.000 0.000 0.299 0.303 0.305 0.308 NiO 0.000 0.000 0.000 0.000 0.022 0.000 0.000 0.000 0.000 Co₃O₄ 0.000 0.000 0.000 0.002 0.009 0.000 0.000 0.000 0.000 Cr₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CuO 0.000 0.000 0.000 0.264 0.113 0.000 0.000 0.000 0.000 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.000 Cl 0.011 1.011 1.064 0.000 0.009 0.004 0.004 0.005 0.005 F 1.094 0.989 1.022 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27FF Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 278 279 280 281 282 283 285 286 SiO₂ 61.95 63.09 58.67 60.98 61.10 60.60 58.94 60.54 Al₂O₃ 15.17 15.05 17.01 17.21 14.87 14.93 14.50 15.63 B₂O₃ 5.83 5.88 5.55 4.81 5.95 5.82 5.75 6.08 P₂O₅ 0.51 0.50 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 8.90 8.97 8.83 8.11 9.96 10.04 13.39 9.65 Na₂O 1.36 1.36 1.41 1.45 1.86 1.86 1.39 1.47 K₂O 0.00 0.00 0.19 0.20 0.20 0.19 0.19 0.20 MgO 2.92 2.87 2.22 2.19 1.98 1.99 1.79 1.96 CaO 2.00 0.96 4.90 4.90 2.06 2.07 3.99 4.38 ZnO 1.02 1.00 0.00 0.00 0.00 1.04 0.00 0.00 TiO₂ 0.01 0.01 1.08 0.01 1.01 1.02 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.57 0.00 0.00 0.00 Fe₂O₃ 0.003 0.002 0.005 0.005 0.002 0.002 0.005 0.005 CeO₂ 0.316 0.309 0.116 0.122 0.416 0.425 0.000 0.000 NiO 0.000 0.000 0.000 0.000 0.000 0.000 0.003 0.005 Co₃O₄ 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.001 Cr₂O₃ 0.000 0.000 0.001 0.001 0.000 0.000 0.000 0.000 CuO 0.000 0.000 0.000 0.000 0.000 0.000 0.045 0.071 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.002 0.000 0.000 0.022 0.000 0.000 0.000 Cl 0.005 0.004 0.007 0.007 0.005 0.007 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27GG Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 287 288 289 290 291 292 293 294 295 SiO₂ 60.42 61.34 59.26 59.32 59.30 59.57 59.31 59.28 58.55 Al₂O₃ 15.76 15.32 16.06 16.19 16.14 16.03 16.28 16.36 16.45 B₂O₃ 6.15 5.94 6.27 6.18 6.25 6.16 6.03 6.10 6.20 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.52 9.39 9.69 9.52 9.61 9.59 9.45 9.36 9.72 Na₂O 1.46 1.46 1.48 1.47 1.47 1.47 1.49 1.48 1.46 K₂O 0.20 0.20 0.19 0.19 0.19 0.19 0.19 0.19 0.19 MgO 1.99 1.93 2.17 2.21 2.18 2.15 2.25 2.26 2.34 CaO 4.43 4.25 4.63 4.67 4.60 4.59 4.73 4.74 4.80 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.006 0.023 0.018 0.018 0.018 0.017 0.017 0.018 0.021 Co₃O₄ 0.001 0.009 0.002 0.002 0.002 0.002 0.002 0.002 0.002 Cr₂O₃ 0.000 0.000 0.030 0.030 0.031 0.029 0.029 0.026 0.028 CuO 0.053 0.116 0.179 0.185 0.190 0.188 0.193 0.188 0.219 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.001 0.001 0.002 0.001 0.000 0.001 0.003 0.000 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27HH Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 296 297 298 299 300 301 302 303 304 SiO₂ 59.81 60.62 59.28 59.05 59.84 60.24 60.81 61.20 61.86 Al₂O₃ 15.83 15.58 16.34 16.45 15.99 15.84 14.91 14.79 14.33 B₂O₃ 6.23 6.09 5.99 6.02 6.09 6.04 6.13 6.11 6.06 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.63 9.44 11.71 11.72 9.46 10.42 10.64 12.51 10.59 Na₂O 1.50 1.55 6.22 6.25 1.59 2.57 2.57 2.59 4.49 K₂O 0.20 0.19 0.19 0.20 0.20 0.20 0.19 0.20 0.20 MgO 2.07 1.99 0.02 0.02 2.11 0.05 0.05 0.03 0.03 CaO 4.48 4.26 0.01 0.01 4.40 4.33 4.39 2.28 2.17 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.006 0.007 0.003 0.003 0.005 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.016 0.008 0.011 0.008 0.009 0.009 0.011 0.008 0.010 Co₃O₄ 0.002 0.003 0.000 0.001 0.002 0.001 0.002 0.001 0.001 Cr₂O₃ 0.029 0.027 0.024 0.027 0.028 0.028 0.029 0.028 0.027 CuO 0.189 0.222 0.173 0.219 0.243 0.239 0.249 0.235 0.219 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.003 0.001 0.004 0.000 0.003 0.004 0.001 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.010 0.000 0.000 0.000 0.002 Cl 0.000 0.000 0.011 0.011 0.009 0.013 0.011 0.009 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 2711 Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 305 306 307 308 309 310 311 312 313 SiO₂ 61.95 61.15 60.57 61.14 61.00 60.47 60.78 60.81 61.72 Al₂O₃ 14.34 14.82 14.66 14.53 14.33 14.61 14.55 14.61 14.54 B₂O₃ 6.01 6.02 6.06 5.91 6.04 6.02 6.01 5.97 5.97 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 10.57 10.62 11.00 12.82 11.15 11.14 11.10 11.03 11.15 Na₂O 2.53 2.57 2.88 2.88 4.80 2.91 2.88 2.87 2.84 K₂O 1.17 0.20 0.19 0.19 0.19 1.18 0.20 0.48 0.19 MgO 0.04 2.07 0.05 0.03 0.03 0.04 1.98 1.69 1.06 CaO 3.12 2.27 4.33 2.24 2.17 3.30 2.23 2.26 2.25 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.008 0.008 0.009 0.008 0.008 0.009 0.008 0.008 0.007 Co₃O₄ 0.001 0.002 0.001 0.002 0.001 0.001 0.002 0.001 0.002 Cr₂O₃ 0.027 0.028 0.028 0.027 0.026 0.027 0.027 0.027 0.027 CuO 0.219 0.238 0.209 0.208 0.222 0.260 0.212 0.212 0.219 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.003 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.011 0.000 0.000 0.000 0.000 Cl 0.011 0.007 0.009 0.011 0.009 0.013 0.007 0.009 0.009 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27JJ Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 314 315 316 317 318 319 320 321 322 SiO₂ 61.88 61.90 59.24 58.96 58.61 59.56 58.58 58.78 58.94 Al₂O₃ 14.54 14.59 16.01 16.03 16.22 16.07 16.18 16.41 16.13 B₂O₃ 6.00 5.90 6.00 6.26 6.25 5.89 6.25 5.95 6.12 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 11.95 11.43 10.10 10.11 10.07 9.74 10.08 9.86 10.05 Na₂O 2.87 3.34 1.47 1.47 1.47 1.48 1.47 1.47 1.49 K₂O 0.19 0.19 0.19 0.19 0.19 0.20 0.19 0.19 0.19 MgO 0.03 0.03 2.15 2.15 2.24 2.16 2.31 2.30 2.22 CaO 2.25 2.28 4.55 4.57 4.67 4.62 4.67 4.78 4.62 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.006 0.006 0.006 0.006 0.006 0.006 0.006 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.010 0.009 0.020 0.020 0.019 0.017 0.020 0.016 0.018 Co₃O₄ 0.001 0.001 0.002 0.002 0.002 0.002 0.002 0.002 0.002 Cr₂O₃ 0.027 0.028 0.030 0.029 0.031 0.029 0.030 0.023 0.029 CuO 0.203 0.262 0.214 0.187 0.197 0.203 0.191 0.193 0.183 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.000 0.003 0.001 0.002 0.002 0.002 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.009 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27KK Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 323 324 325 326 327 328 329 330 331 SiO₂ 60.45 60.59 60.02 60.41 59.73 60.46 60.17 60.03 61.68 Al₂O₃ 15.53 15.42 15.80 15.59 16.01 15.63 15.79 15.79 15.01 B₂O₃ 5.89 5.98 6.00 6.00 6.01 6.00 6.00 5.99 5.96 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 9.95 9.47 9.51 9.51 9.52 9.50 9.51 9.49 9.44 Na₂O 1.45 1.41 1.30 1.42 1.40 1.40 1.26 1.40 1.38 K₂O 0.19 0.18 0.18 0.19 0.19 0.19 0.18 0.19 0.19 MgO 1.98 2.14 2.22 2.12 2.22 2.07 2.19 2.18 1.95 CaO 4.28 4.57 4.71 4.52 4.67 4.52 4.65 4.67 4.16 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.018 0.018 0.018 0.017 0.019 0.012 0.019 0.015 0.017 Co₃O₄ 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 Cr₂O₃ 0.028 0.030 0.031 0.030 0.030 0.029 0.029 0.029 0.028 CuO 0.209 0.180 0.185 0.181 0.187 0.182 0.185 0.185 0.173 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.002 0.002 0.003 0.001 0.001 0.001 0.000 0.001 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27LL Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 332 333 334 335 336 337 338 339 340 SiO₂ 61.47 61.47 61.51 61.27 61.46 61.87 61.25 61.30 61.64 Al₂O₃ 15.03 15.11 15.06 15.13 15.05 14.90 15.13 15.02 14.94 B₂O₃ 5.96 5.99 5.97 5.97 5.98 5.92 6.04 5.90 5.84 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 12.21 12.11 12.06 12.22 12.23 12.02 12.17 12.35 12.33 Na₂O 3.92 3.95 3.94 3.95 3.92 3.93 3.95 3.93 3.90 K₂O 0.39 0.39 0.39 0.39 0.39 0.40 0.39 0.39 0.39 MgO 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 CaO 0.77 0.77 0.77 0.77 0.77 0.75 0.77 0.77 0.75 ZnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.014 0.007 0.005 0.005 0.004 0.019 0.021 0.024 0.023 Co₃O₄ 0.002 0.001 0.001 0.002 0.002 0.001 0.001 0.002 0.002 Cr₂O₃ 0.025 0.023 0.029 0.024 0.027 0.023 0.030 0.023 0.028 CuO 0.181 0.154 0.234 0.232 0.137 0.134 0.209 0.251 0.136 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.000 0.000 0.002 0.000 0.000 0.000 0.001 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cl 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27MM Ex. ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- ORA- (mol %) 341 342 343 344 345 346 347 348 349 SiO₂ 61.24 58.93 58.82 58.94 58.90 61.76 62.65 63.64 64.54 Al₂O₃ 15.06 16.47 16.44 16.45 16.45 15.01 15.08 14.99 15.05 B₂O₃ 6.06 5.91 5.95 5.92 5.92 5.81 4.87 3.93 2.96 P₂O₅ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Li₂O 12.33 10.13 10.23 12.25 12.30 12.33 12.32 12.36 12.30 Na₂O 3.92 4.26 4.26 6.19 6.19 3.78 3.78 3.79 3.82 K₂O 0.39 0.29 0.29 0.20 0.20 0.39 0.38 0.39 0.39 MgO 0.02 2.98 2.97 0.02 0.02 0.03 0.03 0.03 0.04 CaO 0.76 0.03 0.03 0.01 0.01 0.61 0.62 0.62 0.64 ZnO 0.00 0.99 0.99 0.00 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.003 0.003 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 NiO 0.018 0.000 0.000 0.000 0.000 0.019 0.022 0.022 0.021 Co₃O₄ 0.002 0.000 0.000 0.000 0.000 0.002 0.002 0.002 0.002 Cr₂O₃ 0.025 0.000 0.000 0.000 0.000 0.021 0.021 0.022 0.022 CuO 0.145 0.000 0.000 0.000 0.000 0.206 0.199 0.184 0.203 HfO₂ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 As₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 SO₃ 0.000 0.000 0.000 0.000 0.000 0.021 0.000 0.002 0.000 Cl 0.000 0.011 0.011 0.014 0.014 0.007 0.007 0.007 0.011 F 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000

TABLE 27NN Ex. (mol %) ORA-350 ORA-351 ORA-352 ORA-353 ORA-354 SiO₂ 65.24 66.43 61.57 61.66 61.64 Al₂O₃ 15.13 15.10 15.07 15.16 15.12 B₂O₃ 2.02 1.03 5.87 5.82 5.81 P₂O₅ 0.00 0.00 0.00 0.00 0.00 Li₂O 12.43 12.27 12.38 12.29 12.38 Na₂O 3.81 3.82 3.82 3.79 3.78 K₂O 0.41 0.40 0.39 0.39 0.38 MgO 0.04 0.03 0.03 0.03 0.03 CaO 0.64 0.64 0.63 0.65 0.67 ZnO 0.00 0.00 0.00 0.00 0.00 TiO₂ 0.01 0.01 0.01 0.01 0.01 ZrO₂ 0.00 0.00 0.00 0.00 0.00 WO₃ 0.00 0.00 0.00 0.00 0.00 SnO₂ 0.00 0.00 0.00 0.00 0.00 Fe₂O₃ 0.004 0.004 0.004 0.004 0.004 CeO₂ 0.000 0.000 0.000 0.000 0.000 NiO 0.020 0.022 0.023 0.023 0.022 Co₃O₄ 0.002 0.002 0.002 0.002 0.001 Cr₂O₃ 0.022 0.022 0.021 0.022 0.021 CuO 0.219 0.212 0.174 0.137 0.123 HfO₂ 0.000 0.000 0.000 0.000 0.000 MnO₂ 0.001 0.000 0.004 0.000 0.001 As₂O₃ 0.000 0.000 0.000 0.000 0.000 Sb₂O₃ 0.000 0.000 0.000 0.000 0.000 V₂O₅ 0.000 0.000 0.000 0.000 0.000 SO₃ 0.004 0.000 0.000 0.007 0.000 Cl 0.011 0.011 0.009 0.007 0.007 F 0.000 0.000 0.000 0.000 0.000 Nd₂O₃ 0.000 0.000 0.000 0.000 0.000 Er₂O₃ 0.000 0.000 0.000 0.000 0.000

Referring now to Table 28, colored glass articles in the form of glass coupons were produced from the glass compositions of Tables 27A-27NN. The glass coupons had the indicated thicknesses. The CIELAB L*, a*, and b* coordinates of each colored glass article were determined. The average transmittance (%) for each sample over the wavelength range from 380 nm to 750 nm was also determined. The results are reported in Table 28.

TABLE 28 Average transmittance Thickness (380 nm- Example L* a* b* (mm) 750 nm) ORA-1 54.3 −2.25 −23.3 1.496 38.08 ORA-2 53.5 5.59 −47.3 1.504 45.89 ORA-3 73.5 −1.65 3.45 1.518 56.14 ORA-4 58.6 −2.44 −0.74 1.355 42.35 ORA-5 81.6 −6.19 26.71 1.503 48.95 ORA-6 80.9 −10.9 60.97 1.551 44.81 ORA-6 82.2 −11.5 61.28 1.52 46.21 ORA-7 84 2.38 24.44 1.51 67.97 ORA-8 86 −9.09 −0.48 1.499 56.39 ORA-8 85.7 −9.4 −0.84 1.502 55.96 ORA-8 85.7 −9.37 −0.86 1.5 55.85 ORA-9 60.3 2.68 −46.7 1.5 52.41 ORA-10 81.4 −12.9 44.23 1.496 45.38 ORA-11 96.2 −1.07 6.85 1.534 82.97 ORA-11 96.1 −1.08 7 1.53 82.78 ORA-12 96.6 −0.46 2.3 1.34 87.06 ORA-14 96.3 −0.49 0.14 1.516 89.66 ORA-15 85.6 −1.05 2.82 1.504 72.58 ORA-16 80 −7.58 −2.04 1.51 52.17 ORA-17 74.4 −1.63 2.16 1.509 58.32 ORA-18 88.8 −3.39 17.58 1.505 66.53 ORA-21 77.1 −17.9 8.2 1.453 39.68 ORA-22 87 −8.47 5.42 1.33 64.68 ORA-23 95.3 −0.43 0.29 1.34 88.58 ORA-23 95.3 −0.43 0.43 1.34 88.58 ORA-24 65.9 −2.01 −18.5 1.33 51.58 ORA-25 81.5 −5.99 −3.18 1.535 58.24 ORA-26 77.9 −9.15 −1.49 1.537 47.20 ORA-27 73.6 −11.9 1.72 1.526 37.11 ORA-28 68.3 −14.4 6.15 1.538 27.56 ORA-29 55.7 −17.4 17.39 1.554 13.76 ORA-30 41.5 −16.8 27.15 1.553 5.89 ORA-31 89.8 −0.72 16.26 1.4 72.68 ORA-32 26.9 −12 15.29 1.32 3.08 ORA-33 65.6 −2.29 −12.4 1.31 50.51 ORA-34 79.1 −13.5 10.74 1.31 46.61 ORA-35 95 −1.05 −1.88 1.32 87.51 ORA-36 46.4 −17.7 −13.5 1.3 13.49 ORA-37 42.9 −1.87 −22.3 1.34 33.01 ORA-38 43.4 −0.37 −42 1.33 28.23 ORA-39 60.9 −2.38 0.5 1.32 44.34 ORA-40 94.3 −0.51 8.43 1.34 84.53 ORA-41 87.1 −8.58 5.19 1.32 64.68 ORA-42 95.2 −0.73 −0.52 1.31 88.13 ORA-43 65.5 −2.16 −19.2 1.35 50.85 ORA-44 59.3 −2.83 −0.51 1.34 42.93 ORA-45 94.5 −0.38 9.12 1.31 85.15 ORA-46 86.6 −9.29 5.62 1.31 62.94 ORA-47 95.4 −0.61 −0.79 1.34 88.84 ORA-48 65.2 −2.41 −20.2 1.29 50.75 ORA-49 57.6 −3.12 −2.32 1.34 41.79 ORA-50 94.3 −0.35 9.09 1.33 84.83 ORA-51 66.3 −1.99 −18.3 1.32 51.94 ORA-52 90 −1.31 −2.91 1.31 79.81 ORA-52 89.2 −1.62 −3.62 1.29 78.10 ORA-53 66.3 −1.99 −19.6 1.33 51.11 ORA-53 66.6 −2.1 −19.5 1.33 51.36 ORA-54 88.8 −6.42 4.63 1.33 65.58 ORA-54 88.8 −6.54 4.6 1.35 65.42 ORA-56 68.8 −6.69 −18.2 1.32 43.78 ORA-56 69.6 −6.37 −17.8 1.29 45.12 ORA-57 83 −4 −7.77 1.29 65.47 ORA-57 83.6 −3.74 −7.38 1.29 66.76 ORA-58 64.6 −2.21 −20.4 1.29 49.14 ORA-58 64.1 −2.17 −20.6 1.29 48.62 ORA-59 89 −1.7 −3.4 1.3 77.55 ORA-60 67 −1.93 −18.2 1.29 51.74 ORA-61 93.4 −0.84 7.53 1.34 83.00 ORA-62 63.5 −11.9 −9.2 1.31 28.70 ORA-63 83.1 −3.99 −6.93 1.27 65.15 ORA-64 62.7 −2.12 −21.6 1.31 46.93 ORA-65 87.2 −8.3 5.82 1.33 65.10 ORA-66 93.7 −0.3 9.8 1.36 83.86 ORA-67 74.4 −2.49 32.99 1.14 46.62 ORA-68 90.5 −4.5 −5.85 1.34 74.29 ORA-69 68.8 −7.32 −15.8 1.33 42.51 ORA-70 68 −4.44 −20.9 1.35 47.23 ORA-71 57 −2.73 −5.3 1.37 41.30 ORA-72 63.6 −2.73 −18.7 1.42 46.95 ORA-73 96.1 −0.12 3.25 1.35 89.72 ORA-74 55.7 −2.73 0.04 1.36 39.84 ORA-75 62.8 −2.25 −5.79 1.36 47.14 ORA-76 96.8 −0.02 0.27 1.35 91.59 ORA-77 95.9 0.01 0.7 1.33 88.60 ORA-78 65.4 0.92 −37.5 1.36 53.47 ORA-79 76.6 −2.14 −16.2 0.621 63.69 ORA-79 76.6 −2.14 −16.2 0.621 63.69 ORA-79 76.6 −2.14 −16.2 0.621 63.69 ORA-80 96.7 −0.25 −0.13 0.62 91.23 ORA-80 96.7 −0.25 −0.13 0.62 91.23 ORA-80 96.7 −0.25 −0.13 0.62 91.23 ORA-81 71.2 −2.05 −7.46 0.643 56.43 ORA-81 71.2 −2.05 −7.46 0.643 56.43 ORA-81 71.2 −2.05 −7.46 0.643 56.43 ORA-82 86.6 −1.81 −6.31 1.33 74.45 ORA-83 96.9 −0.02 0.12 1.24 92.02 ORA-84 96.7 −0.11 0.25 1.3 91.05 ORA-85 96.8 −0.07 0.21 1.32 91.52 ORA-86 96.9 −0.03 0.21 1.28 91.43 ORA-87 96.7 −0.02 0.47 1.25 91.39 ORA-88 79.3 −4.44 −11.8 1.26 60.21 ORA-89 60.4 −8.61 −17.1 1.34 31.09 ORA-90 67.8 −6.25 −30.3 1.34 46.93 ORA-91 62.4 −6.04 −26.3 1.35 38.76 ORA-92 63 −10.3 −24.5 1.35 38.11 ORA-93 64.1 −8.04 −28.3 1.33 41.34 ORA-94 65.3 −6.48 −29.5 1.33 43.18 ORA-95 84.5 −12.4 12.15 1.29 52.71 ORA-96 83 −13.6 13.11 1.35 49.38 ORA-97 90.1 −8.32 29.93 1.3 61.02 ORA-98 91 −2.23 −8.98 1.23 85.94 ORA-99 87.2 −2.88 −14.4 1.26 81.26 ORA-100 82.2 −2.53 −20.6 1.27 74.80 ORA-101 79.7 −3.97 −10.2 1.29 68.13 ORA-102 78 −4.64 −0.58 1.3 62.62 ORA-103 76.4 −5.2 6.85 1.28 58.13 ORA-104 81.8 −2.5 −21.2 1.31 74.47 ORA-105 81.5 −2.5 −21.7 1.31 74.29 ORA-106 81.6 −2.62 −21.8 1.25 74.67 ORA-107 88.2 −6.98 0.45 1.2 69.06 ORA-108 88.5 −6.04 2.77 1.22 69.99 ORA-109 90.6 −5.74 6.05 1.2 71.88 ORA-110 90.6 −5.52 7.3 1.2 72.19 ORA-111 90.3 −5.35 9.22 1.28 70.83 ORA-112 90.5 −5.31 8.41 1.28 70.71 ORA-113 90.8 −4.31 9.47 1.28 72.44 ORA-114 96.8 −0.06 0.39 1.27 91.19 ORA-115 90 −5.24 7.76 1.29 70.45 ORA-116 95.8 3.04 −0.87 1.348 88.26 ORA-117 93.7 7.94 −1.71 1.349 81.56 ORA-118 91.7 3.05 10.6 1.35 79.00 ORA-119 93.9 3 4.49 1.35 83.88 ORA-120 93.4 5.72 3.16 1.336 81.16 ORA-121 87.6 2.01 −11.4 1.348 77.16 ORA-122 68.3 −2.07 −0.58 1.348 51.93 ORA-123 69.5 −8.73 −13 1.341 45.19 ORA-124 68.1 −1.99 −0.92 1.348 51.96 ORA-125 70.4 −8.27 −13.1 1.315 46.55 ORA-126 68 −9.3 −15.1 1.32 43.43 ORA-127 65.6 −2.31 −3.05 1.346 49.46 ORA-128 95.1 −0.8 8.89 1.307 79.31 ORA-129 95.2 −0.91 5.02 1.324 83.78 ORA-130 93.2 −1.14 3.86 1.327 81.89 ORA-131 78.2 4.27 62.38 1.258 45.39 ORA-132 96.1 −0.4 3.04 1.297 87.72 ORA-133 95 −1.08 5.27 1.299 79.59 ORA-134 92.2 −3.32 −5.34 1.252 79.12 ORA-135 88.4 −4.18 −9.77 1.345 72.86 ORA-136 91.1 −3.29 −7 1.282 78.05 ORA-137 91.9 −1.07 25.91 1.287 68.35 ORA-138 96.7 −0.26 1.46 1.336 88.98 ORA-139 88.5 −0.11 48.07 1.334 59.06 ORA-140 94.5 −1.1 11.46 1.279 79.19 ORA-141 96.1 −0.18 1.02 1.332 88.70 ORA-142 96.2 −0.17 1.49 1.337 88.52 ORA-143 96.7 −0.28 1.5 1.318 88.86 ORA-144 96.1 −0.73 5.28 1.307 83.38 ORA-145 96.6 −0.44 2.41 1.336 87.24 ORA-146 88.8 −7.87 4.43 1.413 67.88 ORA-147 87.6 −8.98 6.75 1.431 64.56 ORA-148 89 −7.38 6.6 1.403 67.49 ORA-149 88.9 −7.22 8.14 1.423 66.30 ORA-150 89.2 −6.44 8.75 1.407 67.20 ORA-151 89.4 −5.91 9.7 1.416 67.40 ORA-152 90.4 0.96 13.31 1.293 78.86 ORA-153 92.9 0.53 8.35 1.3 83.61 ORA-154 94.5 0.2 4.69 1.319 86.92 ORA-155 93.3 −0.72 −4.48 1.307 86.34 ORA-156 81.8 −1.41 −19 1.305 71.94 ORA-157 95.4 −1.73 −1.38 1.29 86.14 ORA-157 95.4 −1.74 −1.39 1.29 86.24 ORA-158 91.5 −5.47 −3.07 1.291 72.48 ORA-158 91.6 −5.45 −3.08 1.297 72.65 ORA-159 95.2 −2.99 9.81 1.297 79.31 ORA-160 93.6 −6.18 23.4 1.313 69.68 ORA-161 92.6 −4.67 −3.67 1.337 76.40 ORA-162 92.8 −4.35 −3.35 1.323 77.22 ORA-163 95.4 −0.71 6.06 1.373 84.14 ORA-164 95.2 −0.7 6.73 1.364 83.63 ORA-165 94.5 −1.61 −2.24 0.591 85.07 ORA-165 94.5 −1.61 −2.24 0.591 85.07 ORA-166 88.8 −6.46 1.89 1.379 70.52 ORA-167 88.7 −6.58 1.85 1.377 70.18 ORA-168 88.5 −6.82 1.68 1.372 69.73 ORA-169 93.2 −2.95 1.1 0.594 81.55 ORA-169 88.8 −6.58 2 1.346 70.28 ORA-169 93.2 −2.95 1.1 0.594 81.55 ORA-169 88.8 −6.58 2 1.346 70.28 ORA-170 89.1 −5.87 4.95 1.318 69.39 ORA-171 89 −6.19 3.17 1.31 70.18 ORA-172 87.1 −1.71 −5.56 1.351 75.02 ORA-173 86.9 −1.8 −5.68 1.336 74.68 ORA-174 91 −1.63 −7.21 1.333 81.25 ORA-175 90.9 −1.63 −7.29 1.334 81.23 ORA-176 90.8 −1.78 −7.35 1.334 80.73 ORA-177 90.8 −1.79 −7.47 1.341 80.64 ORA-178 95.4 −0.71 6 1.345 83.71 ORA-179 95.3 −0.71 6.32 1.305 83.46 ORA-180 87.5 −1.64 −5.58 1.297 75.73 ORA-181 87.2 −1.67 −5.61 1.344 75.35 ORA-182 87.3 −1.66 −5.44 1.319 75.35 ORA-183 95.3 −0.74 5.85 1.32 83.75 ORA-184 95 −3.11 9.96 1.329 78.73 ORA-185 92.2 −5.34 −0.33 1.316 76.11 ORA-186 92.9 −4.43 −0.54 1.314 78.05 ORA-187 91.3 −6.12 −2 1.322 72.83 ORA-188 95.8 −1.22 0.53 1.326 88.30 ORA-189 86.7 −3.8 −7.01 1.309 73.91 ORA-190 83.9 −7.84 0.86 1.293 60.45 ORA-191 90 −3.89 −1.84 1.313 76.65 ORA-192 88.2 −8.1 16.38 1.31 61.57 ORA-193 89.3 −7.44 4.68 1.354 69.18 ORA-194 89.9 −6.8 4.48 1.363 70.85 ORA-195 90.1 −6.59 4.83 1.362 71.57 ORA-196 90 −6.64 4.98 1.365 71.16 ORA-197 90 −6.81 4.19 1.382 71.46 ORA-198 90.5 −5.77 5.27 1.361 72.91 ORA-199 86.9 −1.7 −5.41 1.364 74.70 ORA-200 87 −1.74 −5.51 1.364 74.67 ORA-201 87.3 −1.89 −4.41 1.376 74.90 ORA-202 87.8 −1.81 −3.85 1.358 75.67 ORA-203 86.9 −1.61 −4.9 1.389 74.89 ORA-204 87.2 −1.62 −5.07 1.355 75.24 ORA-205 87.4 −1.7 −5.65 1.314 75.59 ORA-205 87.3 −1.67 −5.68 1.315 75.37 ORA-206 87.9 −1.23 −3.69 1.302 76.36 ORA-206 88 −1.25 −3.65 1.301 76.58 ORA-207 87.5 −1.37 −3.75 1.309 75.65 ORA-207 87.4 −1.36 −3.78 1.308 75.41 ORA-208 87.6 −1.45 −4.46 1.312 75.88 ORA-208 87.5 −1.43 −4.48 1.314 75.62 ORA-209 90.4 −4.83 6.02 1.3 72.97 ORA-209 90.5 −4.84 6.06 1.302 73.14 ORA-210 91 −3.76 5.05 1.315 77.53 ORA-210 90.9 −3.74 5.02 1.317 77.31 ORA-211 90.6 −4.15 5.26 1.346 75.81 ORA-211 90.5 −4.12 5.23 1.347 75.68 ORA-212 90.1 −4.9 4.65 1.308 74.40 ORA-212 90.2 −4.89 4.68 1.314 74.67 ORA-213 90.6 −5.49 13.08 1.323 68.09 ORA-213 90.7 −5.51 13.1 1.326 68.27 ORA-214 92.8 −3.85 3.17 0.845 79.23 ORA-215 92.7 −3.99 3.32 0.847 78.78 ORA-216 92.8 −3.83 3.41 0.845 79.16 ORA-217 90.4 −6 5.4 1.341 72.46 ORA-218 90.8 −5.49 5.48 1.323 73.73 ORA-219 90.7 −5.64 5.2 1.322 73.41 ORA-220 90.3 −6.17 4.9 1.368 71.92 ORA-221 90.3 −6.16 5.17 1.359 72.03 ORA-222 93.9 −2.73 2.55 0.59 82.65 ORA-222 90.3 −6.15 5.5 1.362 72.03 ORA-223 90.1 −6.28 5.36 1.383 71.59 ORA-224 90.5 −5.94 5.3 1.385 72.56 ORA-225 90.6 −5.8 5.38 1.384 72.92 ORA-226 90.7 −5.24 5.85 1.339 73.19 ORA-227 91 −5.02 5.84 1.342 74.24 ORA-228 90.8 −5.53 5.47 1.337 73.77 ORA-229 90.9 −5.58 5.08 1.332 73.87 ORA-230 94 −2.69 2.43 0.6 82.99 ORA-230 90.8 −5.65 5.25 1.337 73.64 ORA-231 89.7 −1.37 −2 1.329 78.60 ORA-232 96.8 −0.02 0.21 1.322 91.63 ORA-233 96.8 −0.03 0.23 1.318 91.77 ORA-234 93.8 −2.97 2.61 1.327 82.14 ORA-235 90.6 −5.94 5.03 1.321 72.83 ORA-236 96.6 −0.33 1.63 1.322 87.69 ORA-237 96.6 −0.32 1.56 1.332 87.82 ORA-238 93 −3.03 1.62 1.291 81.13 ORA-238 93 −3.03 1.62 1.291 81.13 ORA-239 85.7 −8.09 5.15 1.326 62.69 ORA-240 88.7 −4.59 5.53 1.332 72.22 ORA-241 89.1 −6.01 1.55 1.314 72.28 ORA-242 90.4 −6.46 0.69 1.321 72.03 ORA-243 89.2 −5.77 8.31 1.315 70.97 ORA-244 89 −6.09 3.66 1.292 70.53 ORA-245 88.8 −6.28 4.01 1.287 70.10 ORA-246 88.8 −6.35 3.73 1.29 70.14 ORA-247 96.6 −0.38 1.95 1.349 87.28 ORA-248 96.6 −0.38 2 1.333 87.22 ORA-249 96.7 −0.28 1.45 1.343 88.96 ORA-250 96.3 −0.83 4.74 1.349 82.83 ORA-251 96.6 −0.27 1.67 1.339 89.17 ORA-252 96.6 −0.31 1.88 1.371 88.85 ORA-253 96.6 −0.29 1.56 1.381 88.86 ORA-254 96.6 −0.41 2.15 1.369 86.92 ORA-255 96.6 −0.42 2.15 1.354 86.72 ORA-256 96.6 −0.41 2.11 1.375 86.92 ORA-257 96.6 −0.32 2.01 1.414 88.77 ORA-258 96.3 −0.87 4.96 1.411 82.51 ORA-259 96.6 −0.32 1.91 1.401 88.78 ORA-260 96.6 −0.31 1.83 1.404 88.95 ORA-261 96.7 −0.27 1.44 1.315 89.03 ORA-262 96.6 −0.41 2.11 1.332 86.94 ORA-263 96.7 −0.34 1.83 1.263 88.74 ORA-264 96.8 −0.36 1.89 1.324 88.80 ORA-265 96.8 −0.34 1.81 1.272 88.97 ORA-266 96.8 −0.33 1.75 1.261 88.99 ORA-267 96.8 −0.26 1.43 1.263 89.53 ORA-268 96.8 −0.28 1.51 1.304 89.42 ORA-269 96.8 −0.28 1.56 1.321 89.37 ORA-270 96.8 −0.23 1.4 1.327 89.74 ORA-271 96.8 −0.21 1.32 1.28 89.88 ORA-272 92.8 −3.11 −4.14 1.369 79.89 ORA-273 89.3 −1.59 −4.49 1.23 78.30 ORA-274 96.6 −0.2 1.2 1.289 88.42 ORA-275 96.6 −0.31 1.69 1.299 87.36 ORA-276 96.6 −0.26 1.45 1.315 87.84 ORA-277 96.7 −0.01 0.21 1.298 91.71 ORA-278 96.7 −0.19 1.11 1.303 88.71 ORA-279 96.7 −0.19 1.05 1.243 88.99 ORA-280 96.5 −0.19 1.08 1.367 88.79 ORA-281 96.6 −0.02 0.34 1.365 90.95 ORA-282 96.1 −0.91 5.37 1.335 82.02 ORA-283 96.2 −0.87 5.01 1.362 82.65 ORA-285 95.4 −0.54 −0.7 1.3 88.76 ORA-286 95.4 −0.53 −0.43 1.213 88.69 ORA-287 95.5 −0.46 −0.44 1.247 88.87 ORA-288 88.2 −1.61 −5.12 1.358 76.98 ORA-289 88.8 −6.53 3.4 1.303 69.77 ORA-290 88.6 −6.67 3.46 1.347 69.42 ORA-291 88.6 −6.64 3.63 1.337 69.49 ORA-292 88.9 −6.44 3.1 1.315 70.14 ORA-293 89.1 −6.33 3.54 1.317 70.63 ORA-294 90.1 −5.12 2.87 1.283 73.82 ORA-295 88.7 −6.52 3.65 1.295 69.94 ORA-296 89.1 −6.18 2.93 1.284 70.87 ORA-297 89.3 −5.84 2.18 1.276 71.76 ORA-298 85.5 −9.77 1.11 1.983 62.28 ORA-299 83.3 −11.3 −2.01 1.942 58.42 ORA-300 84.4 −10.1 1.39 1.985 59.90 ORA-301 83.9 −10.7 0.11 1.976 59.06 ORA-302 84.1 −10.3 −0.85 1.99 60.61 ORA-303 83.9 −10.9 −2.46 1.974 60.24 ORA-304 83.6 −11.1 −2.68 2.024 59.85 ORA-305 83.4 −11.3 −2.58 2.013 59.25 ORA-306 83.9 −11 −0.94 2.023 59.74 ORA-307 83.9 −10.6 −2.28 2.021 60.85 ORA-308 83.9 −10.8 −3.2 2.019 60.99 ORA-309 83.4 −11.3 −4.16 2.014 59.89 ORA-310 82.9 −11.9 −4.29 2.008 58.39 ORA-311 84.1 −10.8 −1.86 2.022 60.79 ORA-312 84.4 −10.5 −1.75 2.011 61.54 ORA-313 84.1 −10.8 −1.53 2.022 60.38 ORA-314 84.1 −10.6 −1.84 2.014 60.78 ORA-315 84 −10.5 −1.42 2.024 60.65 ORA-316 88.4 −6.82 3.86 1.36 68.96 ORA-317 88.5 −6.69 3.82 1.351 69.77 ORA-318 88.7 −6.56 4.04 1.338 69.78 ORA-319 88.8 −6.52 3.2 1.351 69.96 ORA-320 88.6 −6.59 3.6 1.35 69.49 ORA-321 90 −5.2 2.89 1.341 73.54 ORA-322 88.7 −6.57 3.72 1.342 69.95 ORA-323 88.7 −6.5 3.67 1.347 69.93 ORA-324 84.9 −9.6 5.11 2.025 61.02 ORA-325 84.7 −9.71 5.35 2.05 60.45 ORA-326 84.9 −9.54 5.42 2.044 60.89 ORA-327 84.9 −9.44 5.75 2.041 60.80 ORA-328 85.7 −9.03 4.42 2.067 62.94 ORA-329 85.1 −9.12 5.7 2.062 61.55 ORA-330 85.3 −9.36 4.7 2.068 61.81 ORA-331 85.1 −9.15 5.71 2.064 61.50 ORA-332 93.7 −2.75 0.62 0.552 82.99 ORA-333 94.5 −2.19 0.53 0.546 85.24 ORA-334 93.9 −3.05 0.33 0.534 82.84 ORA-335 93.7 −2.77 −0.43 0.53 83.12 ORA-336 94 −2.49 0.13 0.534 84.29 ORA-337 94.1 −2.33 1.16 0.545 84.11 ORA-338 93.4 −3.17 1.18 0.544 81.64 ORA-339 93.2 −2.76 0.74 0.54 81.94 ORA-340 93.3 −2.73 1.3 0.549 82.49 ORA-341 84.8 −9.28 1.57 2.083 62.39 ORA-341 96.8 −0.01 0.19 1.331 91.81 ORA-343 96.8 −0.02 0.2 1.332 91.81 ORA-344 96.9 −0.01 0.18 1.329 92.01 ORA-345 96.9 0 0.18 1.331 92.03 ORA-346 93.6 −2.4 0.58 0.515 83.13 ORA-347 93.3 −2.39 0.5 0.506 82.66 ORA-348 93.8 −2.11 0.77 0.477 83.67 ORA-349 93.8 −2.08 0.73 0.476 83.61 ORA-350 93.8 −2.14 0.72 0.471 83.22 ORA-351 93.6 −2.09 1.01 0.479 82.66 ORA-352 93.8 −2.19 0.91 0.499 83.75 ORA-353 94.3 −1.78 1.01 0.433 85.13 ORA-354 94.4 −1.79 0.92 0.444 85.42

It will be apparent to those skilled in the art that various modifications and variations may be made to the embodiments described herein without departing from the spirit and scope of the claimed subject matter. Thus, it is intended that the specification cover the modifications and variations of the various embodiments described herein provided such modification and variations come within the scope of the appended claims and their equivalents. 

The invention claimed is:
 1. A colored glass article comprising: greater than or equal to 50 mol % and less than or equal to 80 mol % SiO₂; greater than or equal to 7 mol % and less than or equal to 20 mol % Al₂O₃; greater than or equal to 1 mol % and less than or equal to 15 mol % B₂O₃; greater than or equal to 1 mol % and less than or equal to 20 mol % Li₂O; greater than 0 mol % and less than or equal to 15 mol % Na₂O; greater than or equal to 1 mol % and less than or equal to 35 mol % R₂O, wherein R₂O is the sum of Li₂O, Na₂O, and K₂O; greater than 1×10⁻⁶ mol % and less than or equal to 5 mol % of a colorant, wherein the colorant comprises at least one of Cr₂O₃, Au, Ag, CuO, NiO, Co₃O₄, TiO₂, CeO₂; and greater than or equal to 12 mol % and less than or equal to 24 mol % of Al₂O₃+MgO+CaO+ZnO, wherein the colored glass article comprises: a transmittance color coordinate in CIELAB color space comprising an L* value greater than or equal to 55 and less than or equal to 96.5 and an a* value and a b* value, wherein |a*| is ≥0.3 and |b*| is ≥0.5, as measured under F2 illumination and a 10° standard observer angle; a compressive stress profile with a surface compressive stress greater than or equal to 200 MPa and a central tension greater than or equal to 60 MPa; a dielectric constant from 5.6 to 6.4 over a frequency range from 10 GHz to 60 GHz; and the thickness t is greater than or equal to 0.4 mm and less than or equal to 5 mm.
 2. The colored glass article of claim 1, wherein the thickness t is greater than or equal to 0.5 mm and less than or equal to 5 mm.
 3. The colored glass article of claim 1, wherein a colored glass article having the same composition and microstructure as a center of the colored glass article has a fracture toughness K_(IC) greater than or equal to 0.7 MPa·m^(1/2).
 4. The colored glass article of claim 1, comprising an average transmittance of greater than or equal to 10% and less than or equal to 92% over a wavelength range of 380 nm to 750 nm.
 5. The colored glass article of claim 1, further comprising at least one crystalline phase.
 6. The colored glass article of claim 1, comprising a crystallinity of less than 10 wt %.
 7. The colored glass article of claim 1, wherein the depth of compression is less than or equal to 0.3t.
 8. The colored glass article of claim 1, wherein the surface compressive stress is greater than or equal to 400 MPa.
 9. The colored glass article of claim 1, wherein the central tension is greater than or equal to 70 MPa.
 10. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=0.2879·a*+27.818; b*=7.0833·a*−94.5; b*=0.45·a*+104.5; and b*=15.3·a*+253.
 11. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=7.0833·a*−94.5; b*=−0.9583·a*+146.75; b*=2.6957·a*−50.565; and b*=33.
 12. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=2.6957·a*−50.565; a*=54; b*=1.0769·a*−17.154; and b*=6.6667·a*−173.67.
 13. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=0.2879·a*+27.818; a*=0; b*=−1.375·a*+1; and b*=9.333·a*+86.667, exclusive of a* values greater than −0.3 and less than 0.3 and exclusive of b* values greater than −0.5 and less than 0.5.
 14. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* and b* values within a region of a plot of a* vs. b* bound by the intersection of lines: b*=0.0833·a*+20.833; b*=2.1182·a*−32.073; b*=−0.3; and b*=1.5929·a*−0.3, exclusive of a* values greater than −0.3 and less than 0.3 and exclusive of b* values greater than −0.5 and less than 0.5.
 15. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −18 and less than or equal to 0.3, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to 0.5 and less than or equal to
 82. 16. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −18 and less than or equal to 18, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to 0.5 and less than or equal to
 82. 17. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −20 and less than or equal to 60, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to −90 and less than or equal to 85, exclusive of b* values greater than −0.5 and less than 0.5.
 18. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to −0.3, and b* values greater than or equal to 0.5 and less than or equal to
 82. 19. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to 20, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to 0.5 and less than or equal to
 75. 20. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −15 and less than or equal to 65, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to −90 and less than or equal to 80, exclusive of b* values greater than −0.5 and less than 0.5.
 21. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −35 and less than or equal to 60, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to −90 and less than or equal to 80, exclusive of b* values greater than −0.5 and less than 0.5.
 22. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −15 and less than or equal to −0.3 and b* values greater than or equal to −10 and less than or equal to 10, exclusive of b* values greater than −0.5 and less than 0.5.
 23. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −5 and less than or equal to 25, exclusive of a* values greater than −0.3 and less than 0.3, and b* greater than or equal to −20 and less than or equal to 5, exclusive of b* values greater than −0.5 and less than 0.5.
 24. The colored glass article of claim 1, wherein the transmittance color coordinate in the CIELAB color space comprises a* values greater than or equal to −10 and less than or equal to 25, exclusive of a* values greater than −0.3 and less than 0.3, and b* values greater than or equal to −20 and less than or equal to 5, exclusive of b* values greater than −0.5 and less than 0.5.
 25. An electronic device comprising a housing, the housing comprising a colored glass article as recited in claim
 1. 26. The colored glass article of claim 1, wherein the colored glass article comprises greater than or equal to 1 mol % and less than or equal to 12 mol % B₂O₃.
 27. The colored glass article of claim 1, the colored glass article comprises greater than or equal to 1 mol % and less than or equal to 18 mol % Li₂O.
 28. The colored glass article of claim 1, the colored glass article comprises greater than or equal to 0.01 mol % and less than or equal to 12 mol % Na₂O. 